(orcid 0000-0002-0927-680X)
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Yang, Ze-Peng; Fu, Gregory C. (2020) Convergent Catalytic Asymmetric Synthesis of Esters of Chiral Dialkyl Carbinols Journal of the American Chemical Society; Vol. 142; No. 12; https://doi.org/10.1021/jacs.0c01324
Huo, Haohua; Gorsline, Bradley J. et al. (2020) Catalyst-controlled doubly enantioconvergent coupling of racemic alkyl nucleophiles and electrophiles Science; Vol. 367; No. 6477; https://doi.org/10.1126/science.aaz3855
Yin, Haolin; Fu, Gregory C. (2019) Mechanistic Investigation of Enantioconvergent Kumada Reactions of Racemic α-Bromoketones Catalyzed by a Nickel/Bis(oxazoline) Complex Journal of the American Chemical Society; Vol. 141; No. 38; https://doi.org/10.1021/jacs.9b08185
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Masuda, Yusuke; Fu, Gregory C. (2019) Synthesis of Chiral Diamine Ligands for Nickel-catalyzed Asymmetric Cross-couplings of Alkylchloroboronate Esters with Alkylzincs: (1R,2R)-N,N’-Dimethyl-1,2-bis(2-methylphenyl)-1,2-diaminoethane Organic Syntheses; Vol. 96; https://doi.org/10.15227/orgsyn.096.0245
Fu, Gregory C. (2019) Enantioconvergent Cross−Couplings of Alkyl Electrophiles: The Catalytic Asymmetric Synthesis of Organosilanes Angewandte Chemie International Edition; Vol. 58; No. 11; https://doi.org/10.1002/anie.201814208
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Ahn, Jun Myun; Peters, Jonas C. et al. (2017) Design of a Photoredox Catalyst that Enables the Direct Synthesis of Carbamate-Protected Primary Amines via Photoinduced, Copper-Catalyzed N-Alkylation Reactions of Unactivated Secondary Halides Journal of the American Chemical Society; Vol. 139; No. 49; https://doi.org/10.1021/jacs.7b10907
Ahn, Jun Myun; Ratani, Tanvi S. et al. (2017) Photoinduced, Copper-Catalyzed Alkylation of Amines: A Mechanistic Study of the Cross-Coupling of Carbazole with Alkyl Bromides Journal of the American Chemical Society; Vol. 139; No. 36; https://doi.org/10.1021/jacs.7b07052
Zhao, Wei; Wurz, Ryan P. et al. (2017) Photoinduced, Copper-Catalyzed Decarboxylative C–N Coupling to Generate Protected Amines: An Alternative to the Curtius Rearrangement Journal of the American Chemical Society; Vol. 139; No. 35; https://doi.org/10.1021/jacs.7b07546
Fu, Gregory C. (2017) Transition-Metal Catalysis of Nucleophilic Substitution Reactions: A Radical Alternative to S_N1 and S_N2 Processes ACS Central Science; Vol. 3; No. 7; https://doi.org/10.1021/acscentsci.7b00212
Mu, Xin; Shibata, Yu et al. (2017) Control of Vicinal Stereocenters through Nickel-Catalyzed Alkyl-Alkyl Cross-Coupling Angewandte Chemie International Edition; Vol. 56; No. 21; https://doi.org/10.1002/anie.201702402
Choi, Junwon; Fu, Gregory C. (2017) Transition metal–catalyzed alkyl-alkyl bond formation: Another dimension in cross-coupling chemistry Science; Vol. 356; No. 6334; https://doi.org/10.1126/science.aaf7230
Kalek, Marcin; Fu, Gregory C. (2017) Caution in the Use of Nonlinear Effects as a Mechanistic Tool for Catalytic Enantioconvergent Reactions: Intrinsic Negative Nonlinear Effects in the Absence of Higher-Order Species Journal of the American Chemical Society; Vol. 139; No. 11; https://doi.org/10.1021/jacs.7b01826
Schmidt, Jens; Choi, Junwon et al. (2016) A general, modular method for the catalytic asymmetric synthesis of alkylboronate esters Science; Vol. 354; No. 6317; https://doi.org/10.1126/science.aai8611
Ziegler, Daniel T.; Fu, Gregory C. (2016) Catalytic Enantioselective Carbon–Oxygen Bond Formation: Phosphine-Catalyzed Synthesis of Benzylic Ethers via the Oxidation of Benzylic C–H Bonds Journal of the American Chemical Society; Vol. 138; No. 37; https://doi.org/10.1021/jacs.6b08486
Chu, Crystal K.; Liang, Yufan et al. (2016) Silicon-Carbon Bond Formation via Nickel-Catalyzed Cross-Coupling of Silicon Nucleophiles with Unactivated Secondary and Tertiary Alkyl Electrophiles Journal of the American Chemical Society; Vol. 138; No. 20; https://doi.org/10.1021/jacs.6b03465
Johnson, Miles W.; Hannoun, Kareem I. et al. (2016) A mechanistic investigation of the photoinduced, copper-mediated cross-coupling of an aryl thiol with an aryl halide Chemical Science; Vol. 7; https://doi.org/10.1039/c5sc04709a
Kainz, Quirin M.; Matier, Carson D. et al. (2016) Asymmetric copper-catalyzed C-N cross-couplings induced by visible light Science; Vol. 351; No. 6274; https://doi.org/10.1126/science.aad8313
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Ratani, Tanvi S.; Bachman, Shoshana et al. (2015) Photoinduced, Copper-Catalyzed Carbon–Carbon Bond Formation with Alkyl Electrophiles: Cyanation of Unactivated Secondary Alkyl Chlorides at Room Temperature Journal of the American Chemical Society; Vol. 137; No. 43; https://doi.org/10.1021/jacs.5b08452
Liang, Yufan; Fu, Gregory C. (2015) Stereoconvergent Negishi Arylations of Racemic Secondary Alkyl Electrophiles: Differentiating between a CF_3 and an Alkyl Group Journal of the American Chemical Society; Vol. 137; No. 30; https://doi.org/10.1021/jacs.5b04725
Kalek, Marcin; Fu, Gregory C. (2015) Phosphine-Catalyzed Doubly Stereoconvergent γ-Additions of Racemic Heterocycles to Racemic Allenoates: The Catalytic Enantioselective Synthesis of Protected α,α-Disubstituted α-Amino Acid Derivatives Journal of the American Chemical Society; Vol. 137; No. 29; https://doi.org/10.1021/jacs.5b05528
Liang, Yufan; Fu, Gregory C. (2015) Nickel-Catalyzed Alkyl–Alkyl Cross-Couplings of Fluorinated Secondary Electrophiles: A General Approach to the Synthesis of Compounds having a Perfluoroalkyl Substituent Angewandte Chemie International Edition; Vol. 54; No. 31; https://doi.org/10.1002/anie.201503297
Lee, Sarah Yunmi; Fujiwara, Yuji et al. (2015) Phosphine-Catalyzed Enantioselective Intramolecular [3+2] Annulations To Generate Fused Ring Systems Journal of the American Chemical Society; Vol. 137; No. 13; https://doi.org/10.1021/jacs.5b01985
Kramer, Søren; Fu, Gregory C. (2015) Use of a New Spirophosphine To Achieve Catalytic Enantioselective [4 + 1] Annulations of Amines with Allenes To Generate Dihydropyrroles Journal of the American Chemical Society; Vol. 137; No. 11; https://doi.org/10.1021/jacs.5b01944
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Schley, Nathan D.; Fu, Gregory C. (2014) Nickel-Catalyzed Negishi Arylations of Propargylic Bromides: A Mechanistic Investigation Journal of the American Chemical Society; Vol. 136; No. 47; https://doi.org/10.1021/ja508718m
Ziegler, Daniel T.; Riesgo, Lorena et al. (2014) Biphenyl-Derived Phosphepines as Chiral Nucleophilic Catalysts: Enantioselective [4+1] Annulations To Form Functionalized Cyclopentenes Angewandte Chemie International Edition; Vol. 53; No. 48; https://doi.org/10.1002/anie.201405854
Choi, Junwon; Martín-Gago, Pablo et al. (2014) Stereoconvergent Arylations and Alkenylations of Unactivated Alkyl Electrophiles: Catalytic Enantioselective Synthesis of Secondary Sulfonamides and Sulfones Journal of the American Chemical Society; Vol. 136; No. 34; https://doi.org/10.1021/ja506885s
Tan, Yichen; Muñoz-Molina, José María et al. (2014) Oxygen nucleophiles as reaction partners in photoinduced, copper-catalyzed cross-couplings: O-arylations of phenols at room temperature Chemical Science; Vol. 5; No. 7; https://doi.org/10.1039/c4sc00368c
Lee, Sarah Yunmi; Neufeind, Stefan et al. (2014) Enantioselective Nucleophile-Catalyzed Synthesis of Tertiary Alkyl Fluorides via the α‑Fluorination of Ketenes: Synthetic and Mechanistic Studies Journal of the American Chemical Society; https://doi.org/10.1021/ja5044209
Liang, Yufan; Fu, Gregory C. (2014) Catalytic Asymmetric Synthesis of Tertiary Alkyl Fluorides: Negishi Cross-Couplings of Racemic α,α-Dihaloketones Journal of the American Chemical Society; Vol. 136; No. 14; https://doi.org/10.1021/ja501815p
Cong, Huan; Fu, Gregory C. (2014) Catalytic Enantioselective Cyclization/Cross-Coupling with Alkyl Electrophiles Journal of the American Chemical Society; Vol. 136; No. 10; https://doi.org/10.1021/ja500706v
Do, Hien-Quang; Bachman, Shoshana et al. (2014) Photoinduced, Copper-Catalyzed Alkylation of Amides with Unactivated Secondary Alkyl Halides at Room Temperature Journal of the American Chemical Society; Vol. 136; No. 5; https://doi.org/10.1021/ja4126609
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Ziegler, Daniel T.; Choi, Junwon et al. (2013) A Versatile Approach to Ullmann C−N Couplings at Room Temperature: New Families of Nucleophiles and Electrophiles for Photoinduced, Copper-Catalyzed Processes Journal of the American Chemical Society; Vol. 135; No. 35; https://doi.org/10.1021/ja4060806
Cordier, Christopher J.; Lundgren, Ryan J. et al. (2013) Enantioconvergent Cross-Couplings of Racemic Alkylmetal Reagents with Unactivated Secondary Alkyl Electrophiles: Catalytic Asymmetric Negishi α-Alkylations of N-Boc-pyrrolidine Journal of the American Chemical Society; Vol. 135; No. 30; https://doi.org/10.1021/ja4054114
Uyeda, Christopher; Tan, Yichen et al. (2013) A New Family of Nucleophiles for Photoinduced, Copper-Catalyzed Cross-Couplings via Single-Electron Transfer: Reactions of Thiols with Aryl Halides Under Mild Conditions (0 °C) Journal of the American Chemical Society; Vol. 135; No. 25; https://doi.org/10.1021/ja404050f
Bissember, Alex C.; Lundgren, Rylan J. et al. (2013) Transition-Metal-Catalyzed Alkylations of Amines with Alkyl Halides: Photoinduced, Copper-Catalyzed Couplings of Carbazoles Angewandte Chemie International Edition; Vol. 52; No. 19; https://doi.org/10.1002/anie.201301202
Lundgren, Rylan J.; Wilsily, Ashraf et al. (2013) Catalytic Asymmetric C-N Bond Formation: Phosphine-Catalyzed Intra- and Intermolecular γ-Addition of Nitrogen Nucleophiles to Allenoates and Alkynoates Angewandte Chemie International Edition; Vol. 52; No. 9; https://doi.org/10.1002/anie.201208957
Zultanski, Susan L.; Fu, Gregory C. (2013) Nickel-Catalyzed Carbon−Carbon Bond-Forming Reactions of Unactivated Tertiary Alkyl Halides: Suzuki Arylations Journal of the American Chemical Society; Vol. 135; No. 2; https://doi.org/10.1021/ja311669p
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Binder, Jörg T.; Cordier, Christopher J. et al. (2012) Catalytic Enantioselective Cross-Couplings of Secondary Alkyl Electrophiles with Secondary Alkylmetal Nucleophiles: Negishi Reactions of Racemic Benzylic Bromides with Achiral Alkylzinc Reagents Journal of the American Chemical Society; Vol. 134; No. 41; https://doi.org/10.1021/ja308460z
Lee, Sarah Yunmi; Murphy, Jaclyn M. et al. (2012) Nonenzymatic Dynamic Kinetic Resolution of Secondary Alcohols via Enantioselective Acylation: Synthetic and Mechanistic Studies Journal of the American Chemical Society; Vol. 134; No. 36; https://doi.org/10.1021/ja307425g
Bissember, Alex C.; Levina, Anna et al. (2012) A Mild, Palladium-Catalyzed Method for the Dehydrohalogenation of Alkyl Bromides: Synthetic and Mechanistic Studies Journal of the American Chemical Society; Vol. 134; No. 34; https://doi.org/10.1021/ja306323x
Dudnik, Alexander S.; Fu, Gregory C. (2012) Nickel-Catalyzed Coupling Reactions of Alkyl Electrophiles, Including Unactivated Tertiary Halides, To Generate Carbon–Boron Bonds Journal of the American Chemical Society; Vol. 134; No. 25; https://doi.org/10.1021/ja304068t
Choi, Junwon; Fu, Gregory C. (2012) Catalytic asymmetric synthesis of secondary nitriles via stereoconvergent Negishi arylations and alkenylations of racemic α-bromonitriles Journal of the American Chemical Society; Vol. 134; No. 22; https://doi.org/10.1021/ja303442q
Wilsily, Ashraf; Tramutola, Francesco et al. (2012) New Directing Groups for Metal-Catalyzed Asymmetric Carbon–Carbon Bond-Forming Processes: Stereoconvergent Alkyl–Alkyl Suzuki Cross-Couplings of Unactivated Electrophiles Journal of the American Chemical Society; Vol. 134; No. 13; https://doi.org/10.1021/ja301612y
Zuhl, Andrea M.; Mohr, Justin T. et al. (2012) Competitive Activity-Based Protein Profiling Identifies Aza-β-Lactams as a Versatile Chemotype for Serine Hydrolase Inhibition Journal of the American Chemical Society; Vol. 134; No. 11; https://doi.org/10.1021/ja300799t
Oelke, Alexander J.; Sun, Jianwei et al. (2012) Nickel-Catalyzed Enantioselective Cross-Couplings of Racemic Secondary Electrophiles That Bear an Oxygen Leaving Group Journal of the American Chemical Society; Vol. 134; No. 6; https://doi.org/10.1021/ja300031w
Fujiwara, Yuji; Sun, Jianwei et al. (2011) Enantioselective carbon–sulfur bond formation: γ additions of aryl thiols to allenoates catalyzed by a chiral phosphepine Chemical Science; Vol. 2; No. 11; https://doi.org/10.1039/c1sc00414j
Zultanski, Susan L.; Fu, Gregory C. (2011) Catalytic Asymmetric γ-Alkylation of Carbonyl Compounds via Stereoconvergent Suzuki Cross-Couplings Journal of the American Chemical Society; Vol. 133; No. 39; https://doi.org/10.1021/ja2079515
Fujiwara, Yuji; Fu, Gregory C. (2011) Application of a New Chiral Phosphepine to the Catalytic Asymmetric Synthesis of Highly Functionalized Cyclopentenes That Bear an Array of Heteroatom-Substituted Quaternary Stereocenters Journal of the American Chemical Society; Vol. 133; No. 31; https://doi.org/10.1021/ja2049012
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Bachovchin, Daniel A.; Mohr, Justin T. et al. (2011) Academic cross-fertilization by public screening yields a remarkable class of protein phosphatase methylesterase-1 inhibitors Proceedings of the National Academy of Sciences of the United States of America; Vol. 108; No. 17; https://doi.org/10.1073/pnas.1015248108
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Lou, Sha; Fu, Gregory C. (2010) Palladium/Tris(tert-butyl)phosphine‐Catalyzed Suzuki Cross‐ Couplings in the Presence of Water Advanced Synthesis and Catalysis; Vol. 352; No. 11‐12; https://doi.org/10.1002/adsc.201000267
Lu, Zhe; Fu, Gregory C. (2010) Alkyl-Alkyl Suzuki Cross-Coupling of Unactivated Secondary Alkyl Chlorides Angewandte Chemie International Edition; Vol. 49; No. 37; https://doi.org/10.1002/anie.201003272
Owston, Nathan A.; Fu, Gregory C. (2010) Asymmetric Alkyl−Alkyl Cross-Couplings of Unactivated Secondary Alkyl Electrophiles: Stereoconvergent Suzuki Reactions of Racemic Acylated Halohydrins Journal of the American Chemical Society; Vol. 132; No. 34; https://doi.org/10.1021/ja105924f
Lundin, Pamela M.; Fu, Gregory C. (2010) Asymmetric Suzuki Cross-Couplings of Activated Secondary Alkyl Electrophiles: Arylations of Racemic α-Chloroamides Journal of the American Chemical Society; Vol. 132; No. 32; https://doi.org/10.1021/ja105148g
Lou, Sha; Fu, Gregory C. (2010) Enantioselective Alkenylation via Nickel-Catalyzed Cross-Coupling with Organozirconium Reagents Journal of the American Chemical Society; Vol. 132; No. 14; https://doi.org/10.1021/ja1017046
Sun, Jianwei; Fu, Gregory C. (2010) Phosphine-Catalyzed Formation of Carbon−Sulfur Bonds: Catalytic Asymmetric Synthesis of γ-Thioesters Journal of the American Chemical Society; Vol. 132; No. 13; https://doi.org/10.1021/ja101251d
Lou, Sha; Fu, Gregory C. (2010) Nickel/Bis(oxazoline)-Catalyzed Asymmetric Kumada Reactions of Alkyl Electrophiles: Cross-Couplings of Racemic α-Bromoketones Journal of the American Chemical Society; Vol. 132; No. 4; https://doi.org/10.1021/ja909689t
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Lou, Sha; Fu, Gregory C. (2010) Nickel-catalyzed asymmetric Negishi cross-couplings of racemic secondary allylic chlorides with alkylzincs: (S,E)-ethyl 6-(1,3-dioxolan-2-yl)-4-methylhex-2-enoate Organic Syntheses; Vol. 87; https://doi.org/10.15227/orgsyn.087.0317
Lou, Sha; Fu, Gregory C. (2010) Nickel-catalyzed enantioselective Negishi cross-couplings of racemic secondary α-bromo amides with alkylzinc reagents: (s)-N-benzyl-7-cyano-2-ethyl-N-phenylheptanamide Organic Syntheses; Vol. 87; https://doi.org/10.15227/orgsyn.087.0330
Lou, Sha; Fu, Gregory C. (2010) Palladium-catalyzed alkyl-alkyl Suzuki cross-coupling of primary alkyl bromides at room temperature: (13-cholorotridecyloxy)triethylsilane Organic Syntheses; Vol. 87; https://doi.org/10.15227/orgsyn.087.0299
Lou, Sha; Fu, Gregory C. (2010) [Synthesis of chiral pyridine bis(oxazoline) ligands for nickel-catalyzed asymmetric Negishi cross-couplings of secondary allylic chlorides with alkylzincs: 2,6-bis[(4R)-4,5-dihydro-4-(2-phenylethyl)-2-oxazolyl]-pyridine](https://resolver.caltech.edu/CaltechAUTHORS:20200428-095146731 "Title links to perma link") Organic Syntheses; Vol. 87; https://doi.org/10.15227/orgsyn.087.0310
Smith, Sean W.; Fu, Gregory C. (2009) Asymmetric Carbon−Carbon Bond Formation γ to a Carbonyl Group: Phosphine-Catalyzed Addition of Nitromethane to Allenes Journal of the American Chemical Society; Vol. 131; No. 40; https://doi.org/10.1021/ja9061823
Dochnahl, Maximilian; Fu, Gregory C. (2009) Catalytic Asymmetric Cycloaddition of Ketenes and Nitroso Compounds: Enantioselective Synthesis of α-Hydroxycarboxylic Acid Derivatives Angewandte Chemie International Edition; Vol. 48; No. 13; https://doi.org/10.1002/anie.200805805
Chung, Ying Kit; Fu, Gregory C. (2009) Phosphine-Catalyzed Enantioselective Synthesis of Oxygen Heterocycles Angewandte Chemie International Edition; Vol. 48; No. 12; https://doi.org/10.1002/anie.200805377
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Fu, Gregory C. (2008) The Development of Versatile Methods for Palladium-Catalyzed Coupling Reactions of Aryl Electrophiles through the Use of P(t-Bu)₃ and PCy₃ as Ligands Accounts of Chemical Research; Vol. 41; No. 11; https://doi.org/10.1021/ar800148f
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