(orcid 0000-0002-9692-7614)
Xiong, Shuoyan; Shoshani, Manar M. et al. (2022) Mechanistic studies of P,O-chelated nickel complexes targeting functional polyolefin synthesis In: 258th ACS National Meeting & Exposition, March 20-24, 2022, San Diego, CA https://resolver.caltech.edu/CaltechAUTHORS:20220714-215129425
Agapie, Theodor (2020) Synthetic cluster models of protein active sites In: 260th ACS National Meeting & Exposition, 23-27 August 2020, San Francisco, CA https://resolver.caltech.edu/CaltechAUTHORS:20201221-082520162
Ribson, Ryan; Agapie, Theodor et al. (2020) Influencing singlet fission via coordination chemistry in 2,5-di(2-pyridyl)pyrrole-linked bipentacenes In: 259th ACS National Meeting & Exposition, 22-26 March 2020, Philadelphia, PA https://resolver.caltech.edu/CaltechAUTHORS:20200219-150326751
Agapie, Theodor (2020) Mechanisms of conversion of CO₂ and CO to multicarbon products with molybdenum complexes In: 259th ACS National Meeting & Exposition, 22-26 March 2020, Philadelphia, PA https://resolver.caltech.edu/CaltechAUTHORS:20200219-073615264
Agapie, Theodor (2020) Synthetic cluster models of the biological oxygen evolving complex: Insights regarding function and spectroscopy In: 259th ACS National Meeting & Exposition, 22-26 March 2020, Philadelphia, PA https://resolver.caltech.edu/CaltechAUTHORS:20200219-081913734
Buss, Joshua Alan; Agapie, Theodor (2019) Fundamental lessons in carbon fixation chemistry: Molybdenum-mediated reduction of C_1 oxygenates In: 258th ACS National Meeting & Exposition, 25-29 August 2019, San Diego, CA https://resolver.caltech.edu/CaltechAUTHORS:20190812-092302497
Thevenon, Arnaud; Rosas-Hernández, Alonso et al. (2019) In situ nanostructuring and stabilization of polycrystalline copper electrodes with organic salt additives promotes CO_2 reduction to ethylene In: 258th ACS National Meeting & Exposition, 25-29 August 2019, San Diego, CA https://resolver.caltech.edu/CaltechAUTHORS:20190812-090716368
Xiong, Shuoyan; Agapie, Theodor (2019) Nickel-based bimetallic catalysts for Olefin polymerization In: 258th ACS National Meeting & Exposition, 25-29 August 2019, San Diego, CA https://resolver.caltech.edu/CaltechAUTHORS:20190812-131301286
Bailey, Gwendolyn A.; Buss, Joshua Alan et al. (2019) Open-shell Mo(V) nitrides, phosphides, and carbides: Does radical character dictate coupling chemistry? In: 258th ACS National Meeting & Exposition, 25-29 August 2019, San Diego, CA https://resolver.caltech.edu/CaltechAUTHORS:20190812-095602968
Bruening, Meaghan; Low, Choon Heng et al. (2019) Synthesis and reactivity of group 4 complexes supported by redox noninnocent anthracene-bisphenoxide ligands In: 258th ACS National Meeting & Exposition, 25-29 August 2019, San Diego, CA https://resolver.caltech.edu/CaltechAUTHORS:20190812-091932708
Shiau, Angela; Lee, Heui Beom et al. (2019) Tetranuclear Mn_4O_4 complexes as models of the oxygen evolving complex of photosystem II In: 258th ACS National Meeting & Exposition, 25-29 August 2019, San Diego, CA https://resolver.caltech.edu/CaltechAUTHORS:20190812-100523477
Sampson, Jessica; Choi, Gyeongshin et al. (2018) Transition metal complexes supported by pyrrolide and imidazoline ligands with pyridine donors In: 256th American Chemical Society National Meeting & Exposition, 19-23 August 2018, Boston, MA https://resolver.caltech.edu/CaltechAUTHORS:20181109-153905545
Agapie, Theodor (2017) Biologically inspired clusters: Synthetic control of structure and effects on reactivity In: 253rd American Chemical Society National Meeting & Exposition, April 2-6, 2017, San Francisco, CA https://resolver.caltech.edu/CaltechAUTHORS:20170503-093714219
Agapie, Theodor (2017) Mechanistic insight into the cleavage and coupling of CO with molybdenum complexes: Toward upgrading oxygenated C1 precursors In: 253rd American Chemical Society National Meeting & Exposition, April 2-6, 2017, San Francisco, CA https://resolver.caltech.edu/CaltechAUTHORS:20170503-143024986
Agapie, Theodor (2017) Small molecule activation with molybdenum complexes supported by diphosphine-arene ligands In: 253rd American Chemical Society National Meeting & Exposition, April 2-6, 2017, San Francisco, CA https://resolver.caltech.edu/CaltechAUTHORS:20170503-124825735
Reed, Christopher; Agapie, Theodor (2017) Structure-function studies of tetranuclear iron clusters with a variable interstitial μ4-atom as models of biological active sites In: 253rd American Chemical Society National Meeting & Exposition, April 2-6, 2017, San Francisco, CA https://resolver.caltech.edu/CaltechAUTHORS:20170503-153753745
Radlauer, Madalyn; Agapie, Theodor et al. (2016) Proximal effects in bimetallic catalysts for olefin polymerization, in cross metathes and in multiblock polymers In: 252nd American Chemical Society National Meeting & Exposition, 21-25 August 2016, Philadelphia, PA https://resolver.caltech.edu/CaltechAUTHORS:20160914-121100086
Agapie, Theodor (2016) Reactivity of metal complexes supported by ligands with functionalized pendant ar In: 252nd American Chemical Society National Meeting & Exposition, 21-25 August 2016, Philadelphia, PA https://resolver.caltech.edu/CaltechAUTHORS:20160913-082846175
Agapie, Theodor (2016) Tuning reactivity of biologically inspired clusters via metal and bridging anion composition In: 252nd American Chemical Society National Meeting & Exposition, 21-25 August 2016, Philadelphia, PA https://resolver.caltech.edu/CaltechAUTHORS:20160913-123923807
Hirscher, Nathanael; Lifschitz, Alejo et al. (2016) Development of chromium compounds supported by chelating multi-aryl ligands for selective ethylene oligomerization In: 251st American Chemical Society National Meeting & Exposition, March 13-17, 2016, San Diego, CA https://resolver.caltech.edu/CaltechAUTHORS:20160404-131622641
Reed, Christopher; Agapie, Theodor (2016) Effects of the μ4-bridging atom in a tetranuclear iron cluster on the activation of nitric oxide In: 251st American Chemical Society National Meeting & Exposition, March 13-17, 2016, San Diego, CA https://resolver.caltech.edu/CaltechAUTHORS:20160414-095853543
Sampson, Jessica; Akhtar, Muhammad et al. (2016) Ethylene and α-olefin copolymerization by bimetallic zirconium catalysts In: 251st American Chemical Society National Meeting & Exposition, March 13-17, 2016, San Diego, CA https://resolver.caltech.edu/CaltechAUTHORS:20160406-143935867
Low, Choon Heng; Buss, Joshua A. et al. (2016) Extending the π-system: Modulation of arene and phosphine donor lability in polyarene diphosphine-supported molybdenum complexes and its application to small molecule reactivity In: 251st American Chemical Society National Meeting & Exposition, March 13-17, 2016, San Diego, CA https://resolver.caltech.edu/CaltechAUTHORS:20160413-133217924
Buss, Joshua A.; Agapie, Theodor (2016) Four-electron reductive coupling of carbon monoxide: Evidence for dicarbyne and terminal carbide reaction intermediates In: 251st American Chemical Society National Meeting & Exposition, March 13-17, 2016, San Diego, CA https://resolver.caltech.edu/CaltechAUTHORS:20160413-100054867
Carsch, Kurtis; De Ruiter, Graham et al. (2016) Intramolecular arene C-H and C-F activation by multimetallic tetramanganese clusters relevant to the oxygen-evolving complex of photosystem II In: 251st American Chemical Society National Meeting & Exposition, March 13-17, 2016, San Diego, CA https://resolver.caltech.edu/CaltechAUTHORS:20160413-101904614
Riduan, Siti Nurhanna; Buss, Joshua A. et al. (2016) Selective two-electron reduction of carbon monoxide mediated by molybdenum complexes supported on an asymmetric phenol phosphine ligand In: 251st American Chemical Society National Meeting & Exposition, March 13-17, 2016, San Diego, CA https://resolver.caltech.edu/CaltechAUTHORS:20160413-143959801
Agapie, Theodor (2016) Small molecule activation with metal complexes supported by ligands with pendant arene moieties In: 251st American Chemical Society National Meeting & Exposition, March 13-17, 2016, San Diego, CA https://resolver.caltech.edu/CaltechAUTHORS:20160413-135238397
Lee, Heui Beom; Tsui, Emily Y. et al. (2016) Tetranuclear complexes as precursors for the rational design of pentanuclear oxido clusters reminiscent of the oxygen evolving complex in photosystem II In: 251st American Chemical Society National Meeting & Exposition, 13-17 March 2016, San Diego, CA https://resolver.caltech.edu/CaltechAUTHORS:20160413-132314517
Han, Zhiji; Horak, Kyle et al. (2016) Toward the synthesis of tetrametallic terminal oxo complexes supported by aminopyrazole ligands In: 251st American Chemical Society National Meeting & Exposition, 13-17 March 2016, San Diego, CA https://resolver.caltech.edu/CaltechAUTHORS:20160413-103034272
De Ruiter, Graham; Thompson, Niklas B. et al. (2016) Towards terminal high-valent metal-oxo motifs on multimetallic scaffolds In: 251st American Chemical Society National Meeting & Exposition, March 13-17, 2016, San Diego, CA https://resolver.caltech.edu/CaltechAUTHORS:20160407-124624898
Lifschitz, Alejo; Hirscher, Nathanael et al. (2016) Tuning product selectivity in catalytic ethylene tetramerization systems In: 251st American Chemical Society National Meeting & Exposition, March 13-17, 2016, San Diego, CA https://resolver.caltech.edu/CaltechAUTHORS:20160401-130804536
Wan, Ruomeng; Horak, Kyle et al. (2016) Variable binding modes of pyridine in molybdenum complexes supported by novel P-pyridine-P ligands In: 251st American Chemical Society National Meeting & Exposition, March 13-17, 2016, San Diego, CA https://resolver.caltech.edu/CaltechAUTHORS:20160413-152856843
Lionetti, Davide; Agapie, Theodor (2015) Activation of dioxygen and nitric oxide by an yttrium-tricopper complex: Different modes of metal-metal cooperativity In: 50th Midwest Regional Meeting of the American Chemical Society, October 21-24, 2015, St. Joseph, MO https://resolver.caltech.edu/CaltechAUTHORS:20160302-074418434
Kanady, Jacob; Agapie, Theodor (2015) Models of the oxygen-evolving complex of photosystem II In: 250th American Chemical Society National Meeting & Exposition, August 16-20, 2015, Boston, MA https://resolver.caltech.edu/CaltechAUTHORS:20150922-124929223
De Ruiter, Graham; Thompson, Niklas B. et al. (2015) Redox-state effects on small molecule bin multimetallic iron complexes In: 250th American Chemical Society National Meeting & Exposition, August 16-20, 2015, Boston, MA https://resolver.caltech.edu/CaltechAUTHORS:20150923-082335334
Agapie, Theodor (2014) Aryl ether carbon-oxygen bond cleavage by group 9 and 10 metals: Studies of selectivity and mechanism In: 248th American Chemical Society National Meeting & Exposition, August 10-14, 2014, San Francisco, CA https://resolver.caltech.edu/CaltechAUTHORS:20140815-082851585
Sampson, Jessica; Radlauer, Madalyn et al. (2014) Bimetallic complexes for polymerization catalysis In: 248th American Chemical Society National Meeting & Exposition, August 10-14, 2014, San Francisco, CA https://resolver.caltech.edu/CaltechAUTHORS:20140814-130753437
Horak, Kyle T.; Agapie, Theodor (2014) Designing non-innocent ligands for multiproton-multielectron chemistry: Reactivity of Pd-hydroquinone complexes In: 248th American Chemical Society National Meeting & Exposition, August 10-14, 2014, San Francisco, CA https://resolver.caltech.edu/CaltechAUTHORS:20140812-142635226
Tsui, Emily Y.; Agapie, Theodor (2014) Effects of redox-inactive metals on heterometallic manganese-oxido complexes In: 248th American Chemical Society National Meeting & Exposition, August 10-14, 2014, San Francisco, CA https://resolver.caltech.edu/CaltechAUTHORS:20140814-094929636
Lionetti, Davide; Herbert, David E. et al. (2014) Heterometallic effects in tetrametallic triiron clusters In: 248th American Chemical Society National Meeting & Exposition, August 10-14, 2014, San Francisco, CA https://resolver.caltech.edu/CaltechAUTHORS:20140812-125655020
Edouard, Guy A.; Kelley, Paul et al. (2014) Mechanistic studies of intramolecular aryl ether carbon-oxygen bond activation by group 9 and 10 transition metal centers In: 248th American Chemical Society National Meeting & Exposition, August 10-14, 2014, San Francisco, CA https://resolver.caltech.edu/CaltechAUTHORS:20140814-094528402
Agapie, Theodor (2014) Metal complexes supported by P-arene-P pincers In: 248th American Chemical Society National Meeting & Exposition, August 10-14, 2014, San Francisco, CA https://resolver.caltech.edu/CaltechAUTHORS:20140812-130150570
Horak, Kyle T.; Agapie, Theodor (2014) Metal-ligand cooperativity in Pd-hydroquinone complexes for dioxygen reduction In: 248th American Chemical Society National Meeting & Exposition, August 10-14, 2014, San Francisco, CA https://resolver.caltech.edu/CaltechAUTHORS:20140812-110712960
Lionetti, Davide; Herbert, David E. et al. (2014) Modulation of redox potential of Fe-3 oxo/hydroxo clusters by Lewis acids In: 248th American Chemical Society National Meeting & Exposition, August 10-14, 2014, San Francisco, CA https://resolver.caltech.edu/CaltechAUTHORS:20140812-151959962
Buss, Joshua A.; Cheng, Christine et al. (2014) Molybdenum catalyzed ammonia borane dehydrgenation In: 248th American Chemical Society National Meeting & Exposition, August 10-14, 2014, San Francisco, CA https://resolver.caltech.edu/CaltechAUTHORS:20140811-152312322
De Ruiter, Graham; Agapie, Theodor (2014) Multimetallic complexes supported by ligands with Pyridine6-X3 donor sets In: 248th American Chemical Society National Meeting & Exposition, August 10-14, 2014, San Francisco, CA https://resolver.caltech.edu/CaltechAUTHORS:20140812-110442326
De Ruiter, Graham; Agapie, Theodor (2014) Novel ligand frameworks containing pyridine- and X-type donors (X = O, S or N) for multimetallic complexes In: 248th American Chemical Society National Meeting & Exposition, August 10-14, 2014, San Francisco, CA https://resolver.caltech.edu/CaltechAUTHORS:20140812-083716932
Buss, Joshua A.; Cheng, Christine et al. (2014) Para-terphenyl diphosphine molybdenum complexes: Synthesis and reactivity In: 248th American Chemical Society National Meeting & Exposition, August 10-14, 2014, San Francisco, CA https://resolver.caltech.edu/CaltechAUTHORS:20140812-160025589
Sampson, Jessica; Radlauer, Madalyn et al. (2014) Polymerization catalysis by bimetallic complexes In: 248th American Chemical Society National Meeting & Exposition, August 10-14, 2014, San Francisco, CA https://resolver.caltech.edu/CaltechAUTHORS:20140812-142845578
Lee, Heui Beom; Herbert, Dave E. et al. (2014) Redox properties of cobalt μ4-oxo complexes [MCo_3O]^n+ incorporating redox inactive metals (M = Li^+, Zn^2+, Co^2+) In: 248th American Chemical Society National Meeting & Exposition, 10-14 August 2014, San Francisco, CA https://resolver.caltech.edu/CaltechAUTHORS:20140813-084834355
Kanady, Jacob S.; Tsui, Emily Y. et al. (2014) Strategies for synthesizing Mn_4CaOn models relevant to biological water oxidation In: 248th American Chemical Society National Meeting & Exposition, August 10-14, 2014, San Francisco, CA https://resolver.caltech.edu/CaltechAUTHORS:20140813-084102380
Suseno, Sandy; Kaiser, Jens et al. (2014) Synthesis and characterization of a series of mixed transition metal oxido cubanes (MMnO_4) In: 248th American Chemical Society National Meeting & Exposition, August 10-14, 2014, San Francisco, CA https://resolver.caltech.edu/CaltechAUTHORS:20140812-111925530
Low, Choon Heng; Edouard, Guy A. et al. (2014) Synthesis and characterization of transition metal complexes supported by diphosphine phenolate frameworks In: 248th American Chemical Society National Meeting & Exposition, August 10-14, 2014, San Francisco, CA https://resolver.caltech.edu/CaltechAUTHORS:20140811-154055413
Lee, Heui Beom; Herbert, Dave E. et al. (2014) Synthesis and reactivity of heteromultimetallic cobalt-oxido cluster complexes relevant to water oxidation In: 248th American Chemical Society National Meeting & Exposition, 10-14 August 2014, San Francisco, CA https://resolver.caltech.edu/CaltechAUTHORS:20140812-125909417
Tsui, Emily Y.; Agapie, Theodor (2014) Synthesis and study of [MMn_3O_x] complexes: The effects of redox-inactive metals on cluster properties and reactivity In: 248th American Chemical Society National Meeting & Exposition, August 10-14, 2014, San Francisco, CA https://resolver.caltech.edu/CaltechAUTHORS:20140812-160312421
Suseno, Sandy; Kaiser, Jens et al. (2014) Synthesis of mixed-metal transition metal oxido cubanes (MMn_3O_4) and their potential as prescursors for water oxidation electrocatalysts In: 248th American Chemical Society National Meeting & Exposition, August 10-14, 2014, San Francisco, CA https://resolver.caltech.edu/CaltechAUTHORS:20140812-144111056
Henthorn, Justin T.; Agapie, Theodor (2014) Synthesis, characterization, and multi-proton/multi-electron chemistry of molybdenum-quinoid complexes supported by a non-innocent ligand In: 248th American Chemical Society National Meeting & Exposition, August 10-14, 2014, San Francisco, CA https://resolver.caltech.edu/CaltechAUTHORS:20140812-153114531
Henthorn, Justin T.; Agapie, Theodor (2014) Synthesis, characterization, and reactivity of molybdenum-quinoid complexes supported by a redox and acid/base non-innocent ligand In: 248th American Chemical Society National Meeting & Exposition, August 10-14, 2014, San Francisco, CA https://resolver.caltech.edu/CaltechAUTHORS:20140811-152108669
Agapie, Theodor (2014) Synthetic cluster models of biological and heterogeneous oxygen evolving catalysts In: 248th American Chemical Society National Meeting & Exposition, August 10-14, 2014, San Francisco, CA https://resolver.caltech.edu/CaltechAUTHORS:20140812-132530916
Kanady, Jacob S.; Lin, Po-Heng et al. (2014) Synthetic strategies towards a Mn_4CaO_n model complex of the oxygen-evolving complex of photosystem II In: 248th American Chemical Society National Meeting & Exposition, August 10-14, 2014, San Francisco, CA https://resolver.caltech.edu/CaltechAUTHORS:20140811-153741693
Edouard, Guy A.; Kelley, Paul et al. (2014) Transition metal mediated carbon-oxygen bond activation of aryl ethers bearing pendant phosphines In: 248th American Chemical Society National Meeting & Exposition, August 10-14, 2014, San Francisco, CA https://resolver.caltech.edu/CaltechAUTHORS:20140812-152526761
Low, Choon Heng; Edouard, Guy A. et al. (2014) m-Terphenyl diphosphines bearing a central phenolate ring as coordinatively flexible frameworks for supporting transition metals In: 248th American Chemical Society National Meeting & Exposition, August 10-14, 2014, San Francisco, CA https://resolver.caltech.edu/CaltechAUTHORS:20140812-143045742
Agapie, Theodor (2013) Award Address (ACS Award in Pure Chemistry sponsored by the Alpha Chi Sigma Fraternity and the Alpha Chi Sigma Educational Foundation). Heterometallic models of the oxygen evolving complex of photosystem II In: 245th ACS National Meeting & Exposition, Abstracts of Papers, April 7-11, 2013, New Orleans, LA https://resolver.caltech.edu/CaltechAUTHORS:20130723-085534028
Radlauer, Madalyn R.; Buckley, Aya K. et al. (2013) Copolymerization of amino olefins with ethylene by dinickel bisphenoxyiminato complexes In: 245th ACS National Meeting & Exposition, Abstracts of Papers, April 7-11, 2013, New Orleans, LA https://resolver.caltech.edu/CaltechAUTHORS:20130724-153502539
Tsui, Emily; Agapie, Theodor (2013) Synthetic and electrochemical studies of heterometallic manganese oxido complexes In: 245th ACS National Meeting & Exposition, Abstracts of Papers, April 7-11, 2013, New Orleans, LA https://resolver.caltech.edu/CaltechAUTHORS:20130508-151417953