Agapie, Theodor

Article from CaltechAUTHORS

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Horak, Kyle T. and VanderVelde, David G., el al. (2015) Tuning of Metal Complex Electronics and Reactivity by Remote Lewis Acid Binding to π-Coordinated Pyridine Diphosphine Ligands; Organometallics; Vol. 34; No. 19; 4753-4765; 10.1021/acs.organomet.5b00562
Horak, Kyle T. and Lin, Sibo, el al. (2015) Heterometallic Effects in Trinuclear Complexes Supported by p-Terphenyl Diphosphine Ligands; Organometallics; Vol. 34; No. 18; 4429-4432; 10.1021/acs.organomet.5b00579
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Agapie, Theodor (2015) Synthetic cluster models of the biological oxygen evolving catalyst from photosystem II; Abstracts of Papers of the American Chemical Society; Vol. 249; INOR-423
Henthorn, Justin T. and Lin, Sibo, el al. (2015) Combination of Redox-Active Ligand and Lewis Acid for Dioxygen Reduction with π-Bound Molybdenum−Quinonoid Complexes; Journal of the American Chemical Society; Vol. 137; No. 4; 1458-1464; 10.1021/ja5100405
Lin, Po-Heng and Takase, Michael K., el al. (2015) Investigations of the Effect of the Non-Manganese Metal in Heterometallic-Oxido Cluster Models of the Oxygen Evolving Complex of Photosystem II: Lanthanides as Substitutes for Calcium; Inorganic Chemistry; Vol. 54; No. 1; 59-64; PMCID PMC4286168; 10.1021/ic5015219
Tsui, Emily Y. and Agapie, Theodor (2014) Carbon dioxide cleavage by a Ni_2 complex supported by a binucleating bis(N-heterocyclic carbene) framework; Polyhedron; Vol. 84; 103-110; PMCID PMC6214461; 10.1016/j.poly.2014.06.041
Martin-Diaconescu, Vlad and Gennari, Marcello, el al. (2014) Ca K‑Edge XAS as a Probe of Calcium Centers in Complex Systems; Inorganic Chemistry; Vol. 54; No. 4; 1283-1292; PMCID PMC4331723; 10.1021/ic501991e
Henthorn, Justin T. and Agapie, Theodor (2014) Dioxygen Reactivity with a Ferrocene–Lewis Acid Pairing: Reduction to a Boron Peroxide in the Presence of Tris(pentafluorophenyl)borane; Angewandte Chemie International Edition; Vol. 53; No. 47; 12893-12896; 10.1002/anie.201408462
Kanady, Jacob S. and Lin, Po-Heng, el al. (2014) Toward Models for the Full Oxygen-Evolving Complex of Photosystem II by Ligand Coordination To Lower the Symmetry of the Mn_3CaO_4 Cubane: Demonstration That Electronic Effects Facilitate Binding of a Fifth Metal; Journal of the American Chemical Society; Vol. 136; No. 41; 14373-14376; PMCID PMC4210109; 10.1021/ja508160x
Lionetti, Davide and Agapie, Theodor (2014) How calcium affects oxygen formation; Nature; Vol. 513; No. 7519; 495-496; PMCID PMC4879831; 10.1038/nature13753
Buss, Joshua A. and Edouard, Guy A., el al. (2014) Molybdenum Catalyzed Ammonia Borane Dehydrogenation: Oxidation State Specific Mechanisms; Journal of the American Chemical Society; Vol. 136; No. 32; 11272-11275; PMCID PMC4140452; 10.1021/ja5059923
Kanady, Jacob S. and Lin, Po-Heng, el al. (2014) Synthetic strategies towards a Mn4CaOn model complex of the oxygen-evolving complex of photosystem II; Abstracts of Papers of the American Chemical Society; Vol. 248; 989-INOR
Radlauer, Madalyn R. and Agapie, Theodor (2014) Bimetallic Zirconium Amine Bis(phenolate) Polymerization Catalysts: Enhanced Activity and Tacticity Control for Polyolefin Synthesis; Organometallics; Vol. 33; No. 13; 3247-3250; PMCID PMC4216186; 10.1021/om500608j
Agapie, Theodor (2014) Synthesis and properties of heterometallic cluster models of biological and heterogeneous water oxidation catalysts; Abstracts of Papers of the American Chemical Society; Vol. 247; 519-INOR
Horak, Kyle T. and Velian, Alexandra, el al. (2014) Arene non-innocence in dinuclear complexes of Fe, Co, and Ni supported by a para-terphenyl diphosphine; Chemical Communications; Vol. 50; No. 34; 4427-4429; 10.1039/C4CC00838C
Martin-Diaconescu, V. and Serena, D., el al. (2014) Application of X-ray Absorption (XAS) and Emission (XES) Spectroscopies to the Calcium Centers of PSII Oxygen Evolving Complex Structural Analogs; Journal of Biological Inorganic Chemistry; Vol. 19; No. S1; S498; 10.1007/s00775-014-1095-8
Herbert, David E. and Lionetti, Davide, el al. (2013) Heterometallic Triiron-Oxo/Hydroxo Clusters: Effect of Redox-Inactive Metals; Journal of the American Chemical Society; Vol. 135; No. 51; 19075-19078; PMCID PMC3953215; 10.1021/ja4104974
Tsui, Emily Y. and Kanady, Jacob S., el al. (2013) Synthetic Cluster Models of Biological and Heterogeneous Manganese Catalysts for O_2 Evolution; Inorganic Chemistry; Vol. 52; No. 24; 13833-13848; PMCID PMC3917504; 10.1021/ic402236f
Suseno, Sandy and Horak, Kyle T., el al. (2013) Trinuclear Nickel Complexes with Metal–Arene Interactions Supported by Tris- and Bis(phosphinoaryl)benzene Frameworks; Organometallics; Vol. 32; No. 23; 6883-6886; PMCID PMC3920585; 10.1021/om400976x
Herbert, David E. and Lara, Nadia C., el al. (2013) Arene C-H Amination at Nickel in Terphenyl–Diphosphine Complexes with Labile Metal–Arene Interactions; Chemistry-A European Journal; Vol. 19; No. 48; 16453-16460; PMCID PMC3897266; 10.1002/chem.201302539
Lin, Sibo and Herbert, David E., el al. (2013) Dipalladium(I) Terphenyl Diphosphine Complexes as Models for Two-Site Adsorption and Activation of Organic Molecules; Journal of the American Chemical Society; Vol. 135; No. 42; 15830-15840; PMCID PMC3851319; 10.1021/ja406696k
Kanady, Jacob S. and Tran, Rosalie, el al. (2013) Role of oxido incorporation and ligand lability in expanding redox accessibility of structurally related Mn4 clusters; Chemical Science; Vol. 4; No. 10; 3986-3996; PMCID PMC3806640; 10.1039/C3SC51406D
Kelley, Paul and Day, Michael W., el al. (2013) Hydrogen Evolution Catalyzed by Aluminum-Bridged Cobalt Diglyoximate Complexes; European Journal of Inorganic Chemistry; Vol. 2013; No. 22-23; 3840-3845; 10.1002/ejic.201300309
Tsui, Emily Y. and Agapie, Theodor (2013) Reduction potentials of heterometallic manganese-oxido cubane complexes modulated by redox-inactive metals; Proceedings of the National Academy of Sciences of the United States of America; Vol. 110; No. 25; 10084-10088; PMCID PMC3690856; 10.1073/pnas.1302677110
Suseno, Sandy and Agapie, Theodor (2013) Intramolecular Arene C−H to C−P Functionalization Mediated by Nickel(II) and Palladium(II); Organometallics; Vol. 32; No. 11; 3161-3164; PMCID PMC3811949; 10.1021/om400424a
Tsui, Emily Y. and Tran, Rosalie, el al. (2013) Redox-inactive metals modulate the reduction potential in heterometallic manganese–oxido clusters; Nature Chemistry; Vol. 5; No. 4; 293-299; PMCID PMC3654670; 10.1038/NCHEM.1578
Radlauer, Madalyn R. and Buckley, Aya K., el al. (2013) Bimetallic Coordination Insertion Polymerization of Unprotected Polar Monomers: Copolymerization of Amino Olefins and Ethylene by Dinickel Bisphenoxyiminato Catalysts; Journal of the American Chemical Society; Vol. 135; No. 10; 3784-3787; 10.1021/ja4004816
Kanady, Jacob S. and Mendoza-Cortés, José L., el al. (2013) Oxygen Atom Transfer and Oxidative Water Incorporation in Cuboidal Mn_(3)MO_n Complexes Based on Synthetic, Isotopic Labeling, and Computational Studies; Journal of the American Chemical Society; Vol. 135; No. 3; 1073-1082; 10.1021/ja310022p
Lionetti, Davide and Day, Michael W., el al. (2013) Metal-templated ligand architectures for trinuclear chemistry: tricopper complexes and their O_2 reactivity; Chemical Science; Vol. 4; No. 2; 785-790; PMCID PMC3607385; 10.1039/c2sc21758a
Mindiola, Daniel J. and Arnold, John, el al. (2012) New talent: Americas; Dalton Transactions; Vol. 41; No. 26; 7781-7781; 10.1039/c2dt90087d
Kelley, Paul and Radlauer, Madalyn R., el al. (2012) Metallomacrocycles as ligands: synthesis and characterisation of aluminium-bridged bisglyoximato complexes of palladium and iron; Dalton Transactions; Vol. 41; No. 26; 8086-8092; 10.1039/c2dt30285c
Kelley, Paul and Lin, Sibo, el al. (2012) Nickel-Mediated Hydrogenolysis of C–O Bonds of Aryl Ethers: What Is the Source of the Hydrogen?; Journal of the American Chemical Society; Vol. 134; No. 12; 5480-5483; PMCID PMC3340012; 10.1021/ja300326t
Radlauer, Madalyn R. and Day, Michael W., el al. (2012) Dinickel Bisphenoxyiminato Complexes for the Polymerization of Ethylene and α-Olefins; Organometallics; Vol. 31; No. 6; 2231-2243; PMCID PMC3375993; 10.1021/om2011694
Tonks, Ian A. and Tofan, Daniel, el al. (2012) Zirconium and Titanium Propylene Polymerization Precatalysts Supported by a Fluxional C_2-Symmetric Bis(anilide)pyridine Ligand; Organometallics; Vol. 31; No. 5; 1965-1974; 10.1021/om201262h
Radlauer, Madalyn R. and Day, Michael W., el al. (2012) Bimetallic Effects on Ethylene Polymerization in the Presence of Amines: Inhibition of the Deactivation by Lewis Bases; Journal of the American Chemical Society; Vol. 134; No. 3; 1478-1481; PMCID PMC3307529; 10.1021/ja210990t
Whited, Charlotte A. and Warren, Jeffrey J., el al. (2012) Gating NO Release from Nitric Oxide Synthase; Journal of the American Chemical Society; Vol. 134; No. 1; 27-30; PMCID PMC3257399; 10.1021/ja2069533
Chao, Steven T. and Lara, Nadia C., el al. (2011) Reversible Halide-Modulated Nickel–Nickel Bond Cleavage: Metal–Metal Bonds as Design Elements for Molecular Devices; Angewandte Chemie International Edition; Vol. 50; No. 33; 7529-7532; PMCID PMC3805114; 10.1002/anie.201102797
Kanady, Jacob S. and Tsui, Emily Y., el al. (2011) A Synthetic Model of the Mn_3Ca Subsite of the Oxygen-Evolving Complex in Photosystem II; Science; Vol. 333; No. 6043; 733-736; 10.1126/science.1206036
Agapie, Theodor (2011) Selective ethylene oligomerization: Recent advances in chromium catalysis and mechanistic investigations; Coordination Chemistry Reviews; Vol. 255; No. 7-8; 861-880; 10.1016/j.ccr.2010.11.035
Lin, Sibo and Day, Michael W., el al. (2011) Nickel Hydrides Supported by a Non-Innocent Diphosphine Arene Pincer: Mechanistic Studies of Nickel−Arene H-Migration and Partial Arene Hydrogenation; Journal of the American Chemical Society; Vol. 133; No. 11; 3828-3831; PMCID PMC3060299; 10.1021/ja200368y
Tsui, Emily Y. and Day, Michael W., el al. (2011) Trinucleating Copper: Synthesis and Magnetostructural Characterization of Complexes Supported by a Hexapyridyl 1,3,5-Triarylbenzene Ligand; Angewandte Chemie International Edition; Vol. 50; No. 7; 1668-1672; 10.1002/anie.201005232
Lin, Sibo and Agapie, Theodor (2011) Cross-Coupling Chemistry at Mononuclear and Dinuclear Nickel Complexes; Synlett; Vol. 2011; No. 1; 1-5; 10.1055/s-0030-1259093
Tsui, Emily Y. and Kanady, Jacob S., el al. (2011) Trinuclear first row transition metal complexes of a hexapyridyl, trialkoxy 1,3,5-triarylbenzene ligand; Chemical Communications; Vol. 47; No. 14; 4189-4191; 10.1039/c0cc05608a
Velian, Alexandra and Lin, Sibo, el al. (2010) Synthesis and C−C Coupling Reactivity of a Dinuclear Ni^I−Ni^I Complex Supported by a Terphenyl Diphosphine; Journal of the American Chemical Society; Vol. 132; No. 18; 6296-6297; 10.1021/ja101699a
Agapie, Theodor and Day, Michael W., el al. (2008) Synthesis and reactivity of tantalum complexes supported by bidentate X2 and tridentate LX2 ligands with two phenolates linked to pyridine, thiophene, furan, and benzene connectors: mechanistic studies of the formation of a tantalum benzylidene and insertion chemistry for tantalum-carbon bonds; Organometallics; Vol. 27; No. 23; 6123-6142; 10.1021/om8002653
Agapie, Theodor and Henling, Lawrence M., el al. (2008) Zirconium and titanium complexes supported by tridentate LX2 ligands having two phenolates linked to furan, thiophene, and pyridine donors: precatalysts for propylene polymerization and oligomerization; Organometallics; Vol. 27; No. 23; 6245-6256; 10.1021/om800136y
Agapie, Theodor and Labinger, Jay A., el al. (2007) Mechanistic Studies of Olefin and Alkyne Trimerization with Chromium Catalysts: Deuterium Labeling and Studies of Regiochemistry Using a Model Chromacyclopentane Complex; Journal of the American Chemical Society; Vol. 129; No. 46; 14281-14295; 10.1021/ja073493h
Agapie, Theodor and Bercaw, John E. (2007) Cyclometalated Tantalum Diphenolate Pincer Complexes: Intramolecular C−H/M−CH_3σ-Bond Metathesis May Be Faster than O−H/M−CH_3 Protonolysis; Organometallics; Vol. 26; No. 12; 2957-2959; 10.1021/om700284c
Marinescu, Smaranda C. and Agapie, Theodor, el al. (2007) Group 3 Dialkyl Complexes with Tetradentate (L, L, N, O; L = N, O, S) Monoanionic Ligands: Synthesis and Reactivity; Organometallics; Vol. 26; No. 5; 1178-1190; 10.1021/om0608612
Agapie, Theodor and Day, Michael W., el al. (2006) A Chromium-Diphosphine System for Catalytic Ethylene Trimerization: Synthetic and Structural Studies of Chromium Complexes with a Nitrogen-Bridged Diphosphine Ligand with ortho-Methoxyaryl Substituents; Organometallics; Vol. 25; No. 11; 2733-2742; 10.1021/om050605+
Agapie, Theodor and Schofer, Susan J., el al. (2004) Mechanistic Studies of the Ethylene Trimerization Reaction with Chromium−Diphosphine Catalysts: Experimental Evidence for a Mechanism Involving Metallacyclic Intermediates; Journal of the American Chemical Society; Vol. 126; No. 5; 1304-1305; 10.1021/ja038968t
Agapie, Theodor and Diaconescu, Paula L., el al. (2002) Radical Scission of Symmetrical 1,4-Dicarbonyl Compounds: C−C Bond Cleavage with Titanium(IV) Enolate Formation and Related Reactions; Organometallics; Vol. 21; No. 7; 1329-1340; 10.1021/om0107284
Agapie, Theodor and Diaconescu, Paula L., el al. (2002) Methine (CH) Transfer via a Chlorine Atom Abstraction/Benzene-Elimination Strategy: Molybdenum Methylidyne Synthesis and Elaboration to a Phosphaisocyanide Complex; Journal of the American Chemical Society; Vol. 124; No. 11; 2412-2413; 10.1021/ja017278r
Diaconescu, Paula L. and Odom, Aaron L., el al. (2001) Uranium−Group 14 Element Single Bonds: Isolation and Characterization of a Uranium(IV) Silyl Species; Organometallics; Vol. 20; No. 24; 4993-4995; 10.1021/om010575k
Agapie, Theodor and Odom, Aaron L., el al. (2000) In Pursuit of the Molybdenum(III) Tris(thiolate) Fragment: Unusual Structure of a Dimolybdenum μ-Nitrido Complex; Inorganic Chemistry; Vol. 39; No. 2; 174-179; 10.1021/ic9904891