Stoltz, Brian M.

Nishiura, Yuji; Gonzalez, Kevin J.; et el. (2023) Enantioselective 1,3-Dipolar Cycloadditions of α-Methylene Lactams to Construct Spirocycles; Organic Letters; Vol. 25; No. 35; 6469-6473; PMCID PMC10496134; 10.1021/acs.orglett.3c01978
Zhang, Tianyi; Nishiura, Yuji; et el. (2023) Palladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to α,β-Unsaturated Lactams: Enantioselective Construction of All-Carbon Quaternary Stereocenters in Saturated Nitrogen-Containing Heterocycles; Organic Letters; Vol. 25; No. 35; 6479-6484; PMCID PMC10496148; 10.1021/acs.orglett.3c02064
Kim, Alexia N.; Ngamnithiporn, Aurapat; et el. (2023) Recent Advances in the Total Synthesis of the Tetrahydroisoquinoline Alkaloids (2002–2020); Chemical Reviews; Vol. 123; No. 15; 9447-9496; PMCID PMC10416225; 10.1021/acs.chemrev.3c00054
Barbor, Jay P.; Nair, Vaishnavi N.; et el. (2023) Development of a Nickel-Catalyzed N–N Coupling for the Synthesis of Hydrazides; Journal of the American Chemical Society; Vol. 145; No. 28; 15071-15077; PMCID PMC10360072; 10.1021/jacs.3c04834
Greßies, Steffen; Süße, Lars; et el. (2023) Tandem Dearomatization/Enantioselective Allylic Alkylation of Pyridines; Journal of the American Chemical Society; Vol. 145; No. 22; 11907-11913; PMCID PMC10251512; 10.1021/jacs.3c02470
Flesch, Kaylin N.; Cusumano, Alexander Q.; et el. (2023) Divergent Catalysis: Catalytic Asymmetric [4+2] Cycloaddition of Palladium Enolates; Journal of the American Chemical Society; Vol. 145; No. 20; 11301-11310; 10.1021/jacs.3c02104
Hafeman, Nicholas J.; Loskot, Steven A.; et el. (2023) Total synthesis of (−)-scabrolide A and (−)-yonarolide; Chemical Science; Vol. 14; No. 18; 4745-4758; PMCID PMC10173254; 10.1039/d3sc00651d
Murphy, Sara E.; Crounse, John D.; et el. (2023) Accretion product formation in the self-reaction of ethene-derived hydroxy peroxy radicals; Environmental Science: Atmospheres; 10.1039/d3ea00020f
Gross, Benjamin M.; Han, Seojung; et el. (2023) A Convergent Total Synthesis of (+)-Ineleganolide; Journal of the American Chemical Society; Vol. 145; No. 14; 7763-7767; 10.1021/jacs.3c02142
Rand, Alexander W.; Gonzalez, Kevin J.; et el. (2023) Total Synthesis of Strempeliopidine and Non-Natural Stereoisomers through a Convergent Petasis Borono-Mannich Reaction; Journal of the American Chemical Society; Vol. 145; No. 13; 7278-7287; PMCID PMC10281614; 10.1021/jacs.2c13146
Gross, Benjamin M.; Han, Seojung; et el. (2023) A Convergent Total Synthesis of (+)-Ineleganolide; 10.26434/chemrxiv-2023-lt9vb
Gonzalez, Kevin J.; Rand, Alexander W.; et el. (2023) Development of a Non‐Directed Petasis‐Type Reaction by an Aromaticity‐Disrupting Strategy; Angewandte Chemie International Edition; Vol. 62; No. 14; Art. No. e202218921; PMCID PMC10033435; 10.1002/anie.202218921
Reimann, Christopher E.; Kim, Kelly E.; et el. (2023) What is a cross-coupling? An argument for a universal definition; Tetrahedron; Vol. 130; Art. No. 133176; PMCID PMC9878734; 10.1016/j.tet.2022.133176
Hafeman, Nicholas J.; Chan, Melinda; et el. (2022) Asymmetric Total Synthesis of Havellockate; Journal of the American Chemical Society; Vol. 144; No. 44; 20232-20236; PMCID PMC9997676; 10.1021/jacs.2c09583
Hafeman, Nicholas J.; Chan, Melinda; et el. (2022) Asymmetric Total Synthesis of Havellockate; Journal of the American Chemical Society; Vol. 144; No. 44; 20232-20236; PMCID PMC9997676; 10.1021/jacs.2c09583
Zhang, Tianyi; Cusumano, Alexander Q.; et el. (2022) Investigations of an Unexpected [2+2] Photocycloaddition in the Synthesis of (−)-Scabrolide A from Quantum Mechanics Calculations; Journal of Organic Chemistry; Vol. 87; No. 21; 14115-14124; 10.1021/acs.joc.2c01693
Goldstein, Elizabeth L.; Takada, Hirokazu; et el. (2022) Synthesis of enantioenriched 2,2-disubstituted pyrrolidines via sequential asymmetric allylic alkylation and ring contraction; Tetrahedron; Vol. 123; Art. No. 132940; 10.1016/j.tet.2022.132940
Fulton, Tyler J.; Du, Yun E.; et el. (2022) Asymmetric allylic alkylation, allylation, and related reactions; ISBN 9781119736424; 661-704; 10.1002/9781119736424.ch17
Moghadam, Farbod A.; Hicks, Elliot F.; et el. (2022) Ir-Catalyzed Asymmetric Allylic Alkylation of Dialkyl Malonates Enabling the Construction of Enantioenriched All-Carbon Quaternary Centers; Journal of the American Chemical Society; Vol. 144; No. 18; 7983-7987; 10.1021/jacs.2c02960
Li, Cheng; Lohrey, Trevor D.; et el. (2022) Part-per-trillion trace selective gas detection using frequency locked whispering gallery mode microtoroids; 10.26434/chemrxiv-2022-606xv
Kim, Alexia N.; Ngamnithiporn, Aurapat; et el. (2022) Iridium-catalyzed asymmetric trans-selective hydrogenation of 1,3-disubstituted isoquinolines; Chemical Science; Vol. 13; No. 11; 3227-3232; PMCID PMC8926345; 10.1039/d1sc06729j
Moghadam, Farbod A.; Hicks, Elliot F.; et el. (2022) Ir-Catalyzed Asymmetric Allylic Alkylation of Dialkyl Malo-nates Enabling the Construction of Enantioenriched All-Carbon Quaternary Centers; 10.26434/chemrxiv-2022-n4bsw
Chimiak, L.; Eiler, J.; et el. (2022) Isotope effects at the origin of life: Fingerprints of the Strecker synthesis; Geochimica et Cosmochimica Acta; Vol. 321; 78-98; 10.1016/j.gca.2022.01.015
Samkian, Adrian E.; Sercel, Zachary P.; et el. (2022) Some unusual transformations of a highly reactive α-bromocaranone; Tetrahedron Letters; Vol. 89; Art. No. 153496; 10.1016/j.tetlet.2021.153496
Kim, Kelly E.; Kim, Alexia N.; et el. (2021) Late-Stage Diversification: A Motivating Force in Organic Synthesis; Journal of the American Chemical Society; Vol. 143; No. 41; 16890-16901; PMCID PMC9285880; 10.1021/jacs.1c08920
Lohrey, Trevor D.; Cusumano, Alexander Q.; et el. (2021) Identifying the Imperative Role of Metal–Olefin Interactions in Catalytic C–O Reductive Elimination from Nickel(II); ACS Catalysis; Vol. 11; No. 16; 10208-10222; PMCID PMC8849544; 10.1021/acscatal.1c02790
Sercel, Zachary P.; Sun, Alexander W.; et el. (2021) Synthesis of Enantioenriched gem-Disubstituted 4-Imidazolidinones by Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation; Organic Letters; Vol. 23; No. 16; 6348-6351; PMCID PMC8534816; 10.1021/acs.orglett.1c02134
Reimann, Christopher E.; Ngamnithiporn, Aurapat; et el. (2021) The Enantioselective Synthesis of Eburnamonine, Eucophylline, and 16′-epi-Leucophyllidine; Angewandte Chemie International Edition; Vol. 60; No. 33; 17957-17962; PMCID PMC8338904; 10.1002/anie.202106184
Cusumano, Alexander; Goddard, William Andrew; et el. (2021) Reductive elimination from palladium(II) via a [π2s + π2s + σ2s + σ2s] pericyclic reaction
Cusumano, Alexander Q.; Houk, K. N.; et el. (2021) Synthetic strategy toward ineleganolide: A cautionary tale; Tetrahedron; Vol. 93; Art. No. 132289; PMCID PMC8294177; 10.1016/j.tet.2021.132289
Yu, Donna D.; Van Citters, Gregg; et el. (2021) Discovery of novel modulators for the PPARα (peroxisome proliferator activated receptor α): Potential therapies for nonalcoholic fatty liver disease; Bioorganic and Medicinal Chemistry; Vol. 41; Art. No. 116193; 10.1016/j.bmc.2021.116193
Han, Seo-Jung; Cavitt, Marchello A.; et el. (2021) A Synthetic Strategy toward Eight-Membered Cyclic Amines by Cycloetherification and Claisen Rearrangement; Organic Letters; Vol. 23; No. 9; 3300-3303; PMCID PMC8846577; 10.1021/acs.orglett.1c00763
Süsse, Lars and Stoltz, Brian M. (2021) Enantioselective Formation of Quaternary Centers by Allylic Alkylation with First-Row Transition-Metal Catalysts; Chemical Reviews; Vol. 121; No. 7; 4084-4099; PMCID PMC8846597; 10.1021/acs.chemrev.0c01115
Zhang, Gang; Li, Shan; et el. (2021) A covalent p97/VCP ATPase inhibitor can overcome resistance to CB-5083 and NMS-873 in colorectal cancer cells; European Journal of Medicinal Chemistry; Vol. 213; Art. No. 113148; PMCID PMC7954469; 10.1016/j.ejmech.2020.113148
Li, Cheng; Lohrey, Trevor; et el. (2021) Part-per-trillion trace gas detection using frequency-locked whispering gallery mode microtoroids; ISBN 9781510642133; Art. No. 116890B; 10.1117/12.2578032
Sardini, Stephen R. and Stoltz, Brian M. (2021) Discussion Addendum for: Preparation of (S)-tert-ButylPyOx and Palladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids; Organic Syntheses; Vol. 98; 117-130; PMCID PMC9558615; 10.15227/orgsyn.098.0117
Fulton, Tyler J.; Cusumano, Alexander Q.; et el. (2020) Global Diastereoconvergence in the Ireland–Claisen Rearrangement of Isomeric Enolates: Synthesis of Tetrasubstituted α-Amino Acids; Journal of the American Chemical Society; Vol. 142; No. 52; 21938-21947; PMCID PMC8552564; 10.1021/jacs.0c11480
Kim, Kelly E.; Sakazaki, Yuka; et el. (2020) Synthesis of non-natural cyanthiwigin–gagunin hybrids through late-stage diversification of the cyanthiwigin natural product core; Tetrahedron; Vol. 76; No. 51; Art. No. 130755; 10.1016/j.tet.2019.130755
Kim, Alexia N. and Stoltz, Brian M. (2020) Recent Advances in Homogeneous Catalysts for the Asymmetric Hydrogenation of Heteroarenes; ACS Catalysis; Vol. 10; No. 23; 13834-13851; PMCID PMC8460131; 10.1021/acscatal.0c03958
Cusumano, Alexander Q.; Goddard, William A., III; et el. (2020) Transition Metal Catalyzed [π2s + π2s + σ2s + σ2s] Pericyclic Reaction: Woodward–Hoffmann Rules, Aromaticity, and Electron Flow; Journal of the American Chemical Society; Vol. 142; No. 45; 19033-19039; PMCID PMC8549492; 10.1021/jacs.0c09575
Ngamnithiporn, Aurapat; Iwayama, Toshihiko; et el. (2020) Enantioselective synthesis of highly oxygenated acyclic quaternary center-containing building blocks via palladium-catalyzed decarboxylative allylic alkylation of cyclic siloxyketones; Chemical Science; Vol. 11; No. 40; 11068-11071; PMCID PMC8162308; 10.1039/d0sc04383d
Fulton, Tyler J.; Chen, Anthony Y.; et el. (2020) Enantioselective Total Synthesis of (–)-Myrifabral A and B; Chemical Science; Vol. 11; No. 39; 10802-10806; PMCID PMC8162428; 10.1039/d0sc01141j
Kenseth, Christopher M.; Hafeman, Nicholas J.; et el. (2020) Synthesis of Carboxylic Acid and Dimer Ester Surrogates to Constrain the Abundance and Distribution of Molecular Products in α-Pinene and β-Pinene Secondary Organic Aerosol; Environmental Science and Technology; Vol. 54; No. 20; 12829-12839; 10.1021/acs.est.0c01566
Wolf, William J.; Li, Jiaming; et el. (2020) Efficient Synthesis of Geminal-Dialkyl Dienes for Olefin Metathesis Polymerization; Macromolecules; Vol. 53; No. 18; 7803-7809; PMCID PMC8297823; 10.1021/acs.macromol.0c01606
Cusumano, Alexander Q.; Stoltz, Brian M.; et el. (2020) Reaction Mechanism, Origins of Enantioselectivity, and Reactivity Trends in Asymmetric Allylic Alkylation: A Comprehensive Quantum Mechanics Investigation of a C(sp³)–C(sp³) Cross-Coupling; Journal of the American Chemical Society; Vol. 142; No. 32; 13917-13933; PMCID PMC7802888; 10.1021/jacs.0c06243
Kenseth, Christopher M.; Hafeman, Nicholas J.; et el. (2020) Synthesis of carboxylic acid and dimer ester surrogates to constrain the abundance and distribution of molecular products in α-pinene and β-pinene secondary organic aerosol
Inanaga, Kazato; Wollenburg, Marco; et el. (2020) Catalytic enantioselective synthesis of carbocyclic and heterocyclic spiranes via a decarboxylative aldol cyclization; Chemical Science; Vol. 11; No. 28; 7390-7395; PMCID PMC7574022; 10.1039/d0sc02366c
Duquette, Douglas C.; Cusumano, Alexander Q.; et el. (2020) Probing Trends in Enantioinduction via Substrate Design: Palladium-Catalyzed Decarboxylative Allylic Alkylation of α-Enaminones; Organic Letters; Vol. 22; No. 13; 4966-4969; PMCID PMC7608880; 10.1021/acs.orglett.0c01441
Lavernhe, Rémi; Alexy, Eric J.; et el. (2020) Palladium-Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Acyclic α-N-Pyrrolyl/Indolyl Ketones; Organic Letters; Vol. 22; No. 11; 4272-4275; PMCID PMC7608871; 10.1021/acs.orglett.0c01303
Baek, Doohyun; Ryu, Huijeong; et el. (2020) Catalytic enantioselective synthesis of tetrasubstituted chromanones via palladium-catalyzed asymmetric conjugate arylation using chiral pyridine-dihydroisoquinoline ligands; Chemical Science; Vol. 11; No. 18; 4602-4607; PMCID PMC7574023; 10.1039/d0sc00412j
Hafeman, Nicholas J.; Loskot, Steven A.; et el. (2020) The Total Synthesis of (–)-Scabrolide A; Journal of the American Chemical Society; Vol. 142; No. 19; 8585-8590; 10.1021/jacs.0c02513
Kim, Alexia N.; Ngamnithiporn, Aurapat; et el. (2020) Iridium-Catalyzed Enantioselective and Diastereoselective Hydrogenation of 1,3-Disubstituted Isoquinolines; ACS Catalysis; Vol. 10; No. 5; 3241-3248; PMCID PMC8152574; 10.1021/acscatal.0c00211
Jette, Carina I.; Tong, Z. Jaron; et el. (2020) Copper-Catalyzed Enantioselective Allylic Alkylation with a γ-Butyrolactone-Derived Silyl Ketene Acetal; Angewandte Chemie International Edition; Vol. 59; No. 5; 2033-2038; PMCID PMC7051182; 10.1002/anie.201912618
Lavernhe, Rémi; Alexy, Eric J.; et el. (2020) Palladium-Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Protected Benzoin-Derived Enol Carbonates; Advanced Synthesis and Catalysis; Vol. 362; No. 2; 344-347; PMCID PMC7942817; 10.1002/adsc.201901281
Park, Dongseong; Jette, Carina I.; et el. (2020) Enantioselective Alkynylation of Trifluoromethyl Ketones Catalyzed by Cation-Binding Salen Nickel Complexes; Angewandte Chemie International Edition; Vol. 59; No. 2; 775-779; 10.1002/anie.201913057
Li, Jiaming; Stoltz, Brian M.; et el. (2019) Enantioselective Synthesis of 15-Deoxy-Δ¹²,¹⁴-Prostaglandin J₂; Organic Letters; Vol. 21; No. 24; 10139-10142; 10.1021/acs.orglett.9b04198
Wright, Austin C. and Stoltz, Brian M. (2019) Enantioselective construction of the tricyclic core of curcusones A–D via a cross-electrophile coupling approach; Chemical Science; Vol. 10; No. 45; 10562-10565; PMCID PMC6988747; 10.1039/c9sc04127c
Wright, Austin C.; Lee, Chung Whan; et el. (2019) Progress toward the Enantioselective Synthesis of Curcusones A–D via a Divinylcyclopropane Rearrangement Strategy; Organic Letters; Vol. 21; No. 23; 9658-9662; 10.1021/acs.orglett.9b03829
Sercel, Zachary P.; Sun, Alexander W.; et el. (2019) Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation of 1,4-Diazepan-5-ones; Organic Letters; Vol. 21; No. 22; 9158-9161; PMCID PMC8579948; 10.1021/acs.orglett.9b03530
Velasco-Rubio, Álvaro; Alexy, Eric J.; et el. (2019) Stereospecific Overman Rearrangement of Substituted Cyclic Vinyl Bromides: Access to Fully Substituted α-Amino Ketones; Organic Letters; Vol. 21; No. 22; 8962-8965; 10.1021/acs.orglett.9b03347
Schuman, David P.; Liu, Wen‐Bo; et el. (2019) Transition‐Metal‐Free Catalytic C─H Bond Silylation; ISBN 9783527344536; 213-240; 10.1002/9783527814787.ch7
Sun, Alexander W.; Lackner, Sebastian; et el. (2019) Modularity: Adding New Dimensions to Total Synthesis; Trends in Chemistry; Vol. 1; No. 7; 630-643; 10.1016/j.trechm.2019.05.008
Jones, Christopher G.; Asay, Matthew; et el. (2019) Characterization of Reactive Organometallic Species via MicroED; ACS Central Science; Vol. 5; No. 9; 1507-1513; PMCID PMC6764211; 10.1021/acscentsci.9b00403
Sun, Alexander W.; Bulterys, Philip L.; et el. (2019) Incorporation of a chiral gem-disubstituted nitrogen heterocycle yields an oxazolidinone antibiotic with reduced mitochondrial toxicity; Bioorganic and Medicinal Chemistry Letters; Vol. 29; No. 18; 2686-2689; PMCID PMC6711789; 10.1016/j.bmcl.2019.07.024
Wright, Austin C.; Du, Yun Emily; et el. (2019) A Small-scale Procedure for Acid-catalyzed Ketal Formation; Journal of Organic Chemistry; Vol. 84; No. 17; 11258-11260; 10.1021/acs.joc.9b01541
Fulton, Tyler J.; Wu, Brenda; et el. (2019) Palladium-catalyzed α,β-dehydrogenation of acyclic ester equivalents promoted by a novel electron deficient phosphinooxazoline ligand; Tetrahedron; Vol. 75; No. 31; 4104-4109; PMCID PMC7119178; 10.1016/j.tet.2019.05.065
Alexy, Eric J.; Fulton, Tyler J.; et el. (2019) Palladium-catalyzed enantioselective decarboxylative allylic alkylation of fully substituted N-acyl indole-derived enol carbonates; Chemical Science; Vol. 10; No. 23; 5996-6000; PMCID PMC6566452; 10.1039/c9sc01726g
Craig, Robert A., II; Smith, Russell C.; et el. (2019) Unified Enantioselective, Convergent Synthetic Approach Toward the Furanobutenolide-Derived Polycyclic Norcembranoid Diterpenes: Synthesis of a Series of Ineleganoloids by Oxidation State Manipulation of the Carbocyclic Core; Journal of Organic Chemistry; Vol. 84; No. 12; 7722-7746; 10.1021/acs.joc.9b00635
Harned, Andrew M. and Stoltz, Brian M. (2019) Development of a catalytic enantioselective synthesis of the guanacastepene and heptemerone tricyclic core; Tetrahedron; Vol. 75; No. 24; 3166-3177; PMCID PMC6959853; 10.1016/j.tet.2019.02.053
Lee, Chung Whan; Taylor, Buck L. H.; et el. (2019) An unexpected Ireland–Claisen rearrangement cascade during the synthesis of the tricyclic core of Curcusone C: Mechanistic elucidation by trial-and-error and automatic artificial force-induced reaction (AFIR) computations; Journal of the American Chemical Society; Vol. 141; No. 17; 6995-7004; 10.1021/jacs.9b01146
Wright, Austin C. and Stoltz, Brian M. (2019) Discussion Addendum for: The Direct Acyl-Alkylation of Arynes. Preparation of Methyl 2-(2-acetylphenyl)acetate; Organic Syntheses; Vol. 96; 80-97
Yamano, Michael M.; Knapp, Rachel R.; et el. (2019) Cycloadditions of Oxacyclic Allenes and a Catalytic Asymmetric Entryway to Enantioenriched Cyclic Allenes; Angewandte Chemie International Edition; Vol. 58; No. 17; 5653-5657; PMCID PMC6456397; 10.1002/anie.201900503
Sun, Alexander W. and Stoltz, Brian M. (2019) Discussion Addendum for: Preparation of (S)-tert-ButylPHOX and (S)-2-Allyl-2-Methylcyclohexanone; ISBN 9780471264224; 10.1002/0471264229.os095.29
Sun, Alexander and Stoltz, Brian Mark (2019) Enantioselective synthesis of gem-disubstituted N-Boc diazaheterocycles via decarboxylative asymmetric allylic alkylation
Jette, Carina I.; Geibel, Irina; et el. (2019) Palladium-Catalyzed Construction of Quaternary Stereocenters by Enantioselective Arylation of γ-Lactams with Aryl Chlorides and Bromides; Angewandte Chemie International Edition; Vol. 58; No. 13; 4297-4301; 10.1002/anie.201814475
Han, Seo-Jung; Bhat, Vikram; et el. (2019) Atroposelective Synthesis of PINAP via Dynamic Kinetic Asymmetric Transformation; Advanced Synthesis and Catalysis; Vol. 361; No. 3; 441-444; 10.1002/adsc.201801248
Sun, Alexander W.; Hess, Stephan N.; et el. (2019) Enantioselective synthesis of gem-disubstituted N-Boc diazaheterocycles via decarboxylative asymmetric allylic alkylation; Chemical Science; Vol. 10; No. 3; 788-792; PMCID PMC6345351; 10.1039/c8sc03967d
Welin, Eric R.; Ngamnithiporn, Aurapat; et el. (2019) Concise total syntheses of (–)-jorunnamycin A and (–)-jorumycin enabled by asymmetric catalysis; Science; Vol. 363; No. 6424; 270-275; PMCID PMC7017906; 10.1126/science.aav3421
Praske, Eric; Otkjær, Rasmus V.; et el. (2019) Intramolecular Hydrogen Shift Chemistry of Hydroperoxy-Substituted Peroxy Radicals; Journal of Physical Chemistry A; Vol. 123; No. 2; 590-600; 10.1021/acs.jpca.8b09745
Li, Jiaming; Ahmed, Tonia S.; et el. (2019) Concise Syntheses of Δ^(12)-Prostaglandin J Natural Products via Stereoretentive Metathesis; Journal of the American Chemical Society; Vol. 141; No. 1; 154-158; 10.1021/jacs.8b12816
Shockley, Samantha E.; Hethcox, J. Caleb; et el. (2018) Intermolecular Stereoselective Iridium-Catalyzed Allylic Alkylation: An Evolutionary Account; Synlett; Vol. 29; No. 19; 2481-2492; PMCID PMC6870865; 10.1055/s-0037-1610217
Jones, Christopher G.; Martynowycz, Michael W.; et el. (2018) The CryoEM Method MicroED as a Powerful Tool for Small Molecule Structure Determination; ACS Central Science; Vol. 4; No. 11; 1587-1592; PMCID PMC6276044; 10.1021/acscentsci.8b00760
Davies, Huw M. L.; Itami, Kenichiro; et el. (2018) New directions in natural product synthesis; Chemical Society Reviews; Vol. 47; No. 21; 7828-7829; 10.1039/c8cs90115e
Liu, Wenbin; Ren, Zhi; et el. (2018) Catalyst-Controlled Selective Functionalization of Unactivated C–H Bonds in the Presence of Electronically Activated C–H Bonds; Journal of the American Chemical Society; Vol. 140; No. 38; 12247-12255; 10.1021/jacs.8b07534
Lu, Yanhui; Goldstein, Elizabeth L.; et el. (2018) Palladium-Catalyzed Enantioselective C_(sp)^3–C_(sp)3 Cross-Coupling for the Synthesis of (Poly)fluorinated Chiral Building Blocks; Organic Letters; Vol. 20; No. 18; 5657-5660; PMCID PMC6192028; 10.1021/acs.orglett.8b02369
Wang, Xin; Zhu, Ming-Hui; et el. (2018) General and Practical Potassium Methoxide/Disilane-Mediated Dehalogenative Deuteration of (Hetero)Arylhalides; Journal of the American Chemical Society; Vol. 140; No. 35; 10970-10974; 10.1021/jacs.8b07597
Alexy, Eric J.; Zhang, Haiming; et el. (2018) Catalytic Enantioselective Synthesis of Acyclic Quaternary Centers: Palladium-Catalyzed Decarboxylative Allylic Alkylation of Fully Substituted Acyclic Enol Carbonates; Journal of the American Chemical Society; Vol. 140; No. 32; 10109-10112; PMCID PMC6103296; 10.1021/jacs.8b05560
Kenseth, Christopher M.; Huang, Yuanlong; et el. (2018) Synergistic O₃ + OH oxidation pathway to extremely low-volatility dimers revealed in β-pinene secondary organic aerosol; Proceedings of the National Academy of Sciences of the United States of America; Vol. 115; No. 33; 8301-8306; PMCID PMC6099901; 10.1073/pnas.1804671115
Al Saihati, Zainab; Haibach, Michael C.; et el. (2018) Cyclic alkanes transfer dehydrogenation using homogeneous iridium pincer catalysts
Defieber, Christian; Mohr, Justin T.; et el. (2018) Short Enantioselective Formal Synthesis of (–)-Platencin; Synthesis-Stuttgart; Vol. 50; No. 22; 4359-4368; PMCID PMC6498846; 10.1055/s-0037-1610437
Hartrampf, Nina; Winter, Nils; et el. (2018) Total Synthesis of the Norhasubanan Alkaloid Stephadiamine; Journal of the American Chemical Society; Vol. 140; No. 28; 8675-8680; PMCID PMC6130314; 10.1021/jacs.8b01918
Hethcox, J. Caleb; Shockley, Samantha E.; et el. (2018) Enantioselective Synthesis of Vicinal All-Carbon Quaternary Centers via Iridium-Catalyzed Allylic Alkylation; Angewandte Chemie International Edition; Vol. 57; No. 28; 8664-8667; PMCID PMC6033654; 10.1002/anie.201804820
Krout, Michael R.; Henry, Christopher E.; et el. (2018) Wolff/Cope Approach to the AB Ring of the Sesterterpenoid Variecolin; Journal of Organic Chemistry; Vol. 83; No. 13; 6995-7009; PMCID PMC6035096; 10.1021/acs.joc.7b02972
Pritchett, Beau P. and Stoltz, Brian M. (2018) Enantioselective palladium-catalyzed allylic alkylation reactions in the synthesis of Aspidosperma and structurally related monoterpene indole alkaloids; Natural Product Reports; Vol. 35; No. 6; 559-574; PMCID PMC6013405; 10.1039/c7np00069c
Craig, Robert A., II; Smith, Russell C.; et el. (2018) Development of a Unified Enantioselective, Convergent Synthetic Approach Toward the Furanobutenolide-Derived Polycyclic Norcembranoid Diterpenes: Asymmetric Formation of the Polycyclic Norditerpenoid Carbocyclic Core by Tandem Annulation Cascade; Journal of Organic Chemistry; Vol. 83; No. 7; 3467-3485; PMCID PMC5889334; 10.1021/acs.joc.7b02825
Kim, Kelly E.; Adams, Ashley M.; et el. (2018) The Cyanthiwigin Natural Product Core as a Complex Molecular Scaffold for Comparative Late-Stage C–H Functionalization Studies; Journal of Organic Chemistry; Vol. 83; No. 6; 3023-3033; 10.1021/acs.joc.7b03291
Ngamnithiporn, Aurapat; Jette, Carina I.; et el. (2018) Nickel-catalyzed enantioselective allylic alkylation of lactones and lactams with unactivated allylic alcohols; Chemical Science; Vol. 2018; No. 9; 2547-2551; PMCID PMC5912103; 10.1039/c7sc05216b
Stoltz, Brian (2018) Award Address (ACS Award for Creative Work in Synthetic Organic Chemistry sponsored by MilliporeSigma). Complex natural products as a driving force for discovery in organic chemistry
Leung, Joyce; Bederman, Aaron; et el. (2018) Total synthesis of (±)-phomoidride D: A 22 year odyssey
Leung, Joyce C.; Bedermann, Aaron A.; et el. (2018) Total Synthesis of (±)-Phomoidride D; Angewandte Chemie International Edition; Vol. 57; No. 7; 1991-1994; 10.1002/anie.201712369
Duquette, Douglas Charles; Jensen, Thomas; et el. (2018) Progress towards the total synthesis of hamigerans C and D: a direct approach to an elaborated 6-7-5 carbocyclic core; Journal of Antibiotics; Vol. 71; No. 2; 263-267; PMCID PMC5788718; 10.1038/ja.2017.96
Chen, Anthony Y.; Lu, Qianqian; et el. (2018) Isocanthine Synthesis via Rh(III)-Catalyzed Intramolecular C-H Functionalization; Journal of Organic Chemistry; Vol. 83; No. 1; 330-337; 10.1021/acs.joc.7b02731
Praske, Eric; Otkjær, Rasmus V.; et el. (2018) Atmospheric autoxidation is increasingly important in urban and suburban North America; Proceedings of the National Academy of Sciences of the United States of America; Vol. 115; No. 1; 64-69; PMCID PMC5776813; 10.1073/pnas.1715540115
Roizen, Jennifer L.; Jones, Amanda C.; et el. (2017) Model Studies to Access the [6,7,5,5]-Core of Ineleganolide Using Tandem Translactonization-Cope or Cyclopropanation-Cope Rearrangements as Key Steps; Journal of Organic Chemistry; Vol. 82; No. 24; 13051-13067; PMCID PMC5732049; 10.1021/acs.joc.7b02030
Haibach, Michael C.; Stoltz, Brian M.; et el. (2017) Catalytic Reduction of Alkyl and Aryl Bromides Using Propan-2-ol; Angewandte Chemie International Edition; Vol. 56; No. 47; 15123-15126; 10.1002/anie.201708800
Alexy, Eric J.; Virgil, Scott C.; et el. (2017) Enantioselective Pd-Catalyzed Decarboxylative Allylic Alkylation of Thiopyranones. Access to Acyclic, Stereogenic α-Quaternary Ketones; Organic Letters; Vol. 19; No. 19; 5007-5009; PMCID PMC5632216; 10.1021/acs.orglett.7b02354
Liniger, Marc; Liu, Yiyang; et el. (2017) Sequential Ruthenium Catalysis for Olefin Isomerization and Oxidation: Application to the Synthesis of Unusual Amino Acids; Journal of the American Chemical Society; Vol. 139; No. 39; 13944-13949; PMCID PMC5628162; 10.1021/jacs.7b08496
Pritchett, Beau P.; Donckele, Etienne J.; et el. (2017) Enantioselective Catalysis Coupled with Stereodivergent Cyclization Strategies Enables Rapid Syntheses of (+)-Limaspermidine and (+)-Kopsihainanine A; Angewandte Chemie International Edition; Vol. 56; No. 41; 12624-12627; PMCID PMC5896324; 10.1002/anie.201707304
Shockley, Samantha E.; Hethcox, J. Caleb; et el. (2017) Enantioselective Synthesis of Acyclic α-Quaternary Carboxylic Acid Derivatives through Iridium-Catalyzed Allylic Alkylation; Angewandte Chemie International Edition; Vol. 56; No. 38; 11545-11548; PMCID PMC5674796; 10.1002/anie.201707015
Shockley, Samantha E.; Hethcox, J. Caleb; et el. (2017) Asymmetric Synthesis of All-Carbon Quaternary Spirocycles via a Catalytic Enantioselective Allylic Alkylation Strategy; Tetrahedron Letters; Vol. 58; No. 34; 3341-3343; PMCID PMC5578629; 10.1016/j.tetlet.2017.07.022
Loskot, Steven A.; Romney, David K.; et el. (2017) Enantioselective Total Synthesis of Nigelladine A via Late-Stage C–H Oxidation Enabled by an Engineered P450 Enzyme; Journal of the American Chemical Society; Vol. 139; No. 30; 10196-10199; PMCID PMC5679227; 10.1021/jacs.7b05196
Shockley, Samantha; Hethcox, Caleb; et el. (2017) Recent developments in stereoselective iridium-catalyzed allylic alkylation methodologies
Stoltz, Brian M. (2017) Twists and turns of lactam research
Starkov, Pavel; Moore, Jared T.; et el. (2017) Enantioselective Construction of Acyclic Quaternary Carbon Stereocenters: Palladium-Catalyzed Decarboxylative Allylic Alkylation of Fully-Substituted Amide Enolates; Journal of the American Chemical Society; Vol. 139; No. 28; 9615-9620; PMCID PMC5555155; 10.1021/jacs.7b04086
Craig, Robert A., II and Stoltz, Brian M. (2017) Polycyclic Furanobutenolide-Derived Cembranoid and Norcembranoid Natural Products: Biosynthetic Connections and Synthetic Efforts; Chemical Reviews; Vol. 117; No. 12; 7878-7909; PMCID PMC5497599; 10.1021/acs.chemrev.7b00083
Banerjee, Shibdas; Yang, Yun-Fang; et el. (2017) Ionic and Neutral Mechanisms for C–H Bond Silylation of Aromatic Heterocycles Catalyzed by Potassium t-Butoxide; Journal of the American Chemical Society; Vol. 139; No. 20; 6880-6887; 10.1021/jacs.6b13032
Liu, Wen-Bo; Schuman, David P.; et el. (2017) Potassium tert-Butoxide-Catalyzed Dehydrogenative C–H Silylation of Heteroaromatics: A Combined Experimental and Computational Mechanistic Study; Journal of the American Chemical Society; Vol. 139; No. 20; 6867-6879; 10.1021/jacs.6b13031
Hethcox, J. Caleb; Shockley, Samantha E.; et el. (2017) Enantioselective Iridium-Catalyzed Allylic Alkylation Reactions of Masked Acyl Cyanide Equivalents; Organic Letters; Vol. 19; No. 7; 1527-1529; PMCID PMC5470644; 10.1021/acs.orglett.7b00449
Stoltz, Brian M. (2017) Complex natural products as a driving force for discovery in organic chemistry
Bhat, Vikram; Welin, Eric R.; et el. (2017) Advances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations; Chemical Reviews; Vol. 117; No. 5; 4528-4561; PMCID PMC5516946; 10.1021/acs.chemrev.6b00731
Klare, Hendrik F. T.; Goldberg, Alexander F. G.; et el. (2017) Oxidative Fragmentations and Skeletal Rearrangements of Oxindole Derivatives; Organic Letters; Vol. 19; No. 5; 988-991; 10.1021/acs.orglett.6b03789
Pritchett, Beau P.; Kikuchi, Jun; et el. (2017) A Fischer Indolization Strategy toward the Total Synthesis of (–)-Goniomitine; Heterocycles; Vol. 95; No. 2; 1245-1253; PMCID PMC5502790; 10.3987/COM-16-S(S)80
Toutov, Anton A.; Betz, Kerry N.; et el. (2017) Alkali metal hydroxide–catalyzed C(sp)–H bond silylation; Journal of the American Chemical Society; Vol. 139; No. 4; 1668-1674; 10.1021/jacs.6b12114
Craig, Robert A., II; Roizen, Jennifer L.; et el. (2017) Enantioselective, convergent synthesis of the ineleganolide core by a tandem annulation cascade; Chemical Science; Vol. 8; No. 1; 507-514; PMCID PMC5321630; 10.1039/c6sc03347d
Hethcox, J. Caleb; Shockley, Samantha E.; et el. (2016) Iridium-Catalyzed Stereoselective Allylic Alkylation Reactions with Crotyl Chloride; Angewandte Chemie International Edition; Vol. 55; No. 52; 16092-16095; PMCID PMC5207348; 10.1002/anie.201609960
Pushkarskaya, Eugenia; Wong, Brian; et el. (2016) Single-step synthesis of 3-hydroxycarbazoles by annulation of electron-rich anilines and quinones; Tetrahedron Letters; Vol. 57; No. 50; 5653-5657; 10.1016/j.tetlet.2016.11.009
Pushkarskaya, Eugenia; Wong, Brian; et el. (2016) Single-step synthesis of 3-hydroxycarbazoles by annulation of electron-rich anilines and quinones; Tetrahedron Letters; Vol. 57; No. 50; 5653-5657; 10.1016/j.tetlet.2016.11.009
Kim, Kelly E. and Stoltz, Brian M. (2016) A Second-Generation Synthesis of the Cyanthiwigin Natural Product Core; Organic Letters; Vol. 18; No. 21; 5720-5723; 10.1021/acs.orglett.6b02962
Li, Jiaming; Grubbs, Robert H.; et el. (2016) Palladium-Catalyzed Aerobic Intramolecular Aminoacetoxylation of Alkenes Enabled by Catalytic Nitrate; Organic Letters; Vol. 18; No. 21; 5449-5451; PMCID PMC5512709; 10.1021/acs.orglett.6b02722
Pritchett, Beau P.; Kikuchi, Jun; et el. (2016) Enantioselective Pd-Catalyzed Allylic Alkylation Reactions of Dihydropyrido[1,2-a]indolone Substrates: Efficient Syntheses of (−)-Goniomitine, (+)-Aspidospermidine, and (−)-Quebrachamine; Angewandte Chemie International Edition; Vol. 55; No. 43; 13529-13532; PMCID PMC5207349; 10.1002/anie.201608138
Kim, Kelly E.; Li, Jiaming; et el. (2016) Catalytic Anti-Markovnikov Transformations of Hindered Terminal Alkenes Enabled by Aldehyde-Selective Wacker-Type Oxidation; Journal of the American Chemical Society; Vol. 138; No. 40; 13179-13182; 10.1021/jacs.6b08788
Krishnan, Subramanian; Chang, Alexander C.; et el. (2016) Escherichia coli K1 Modulates Peroxisome Proliferator–Activated Receptor γ and Glucose Transporter 1 at the Blood-Brain Barrier in Neonatal Meningitis; Journal of Infectious Diseases; Vol. 214; No. 7; 1092-1104; PMCID PMC5021232; 10.1093/infdis/jiw306
Mohr, Justin T.; Moore, Jared T.; et el. (2016) Enantioconvergent catalysis; Beilstein Journal of Organic Chemistry; Vol. 12; 2038-2045; PMCID PMC5082454; 10.3762/bjoc.12.192
Hethcox, J. Caleb; Shockley, Samantha E.; et el. (2016) Iridium-Catalyzed Diastereo-, Enantio-, and Regioselective Allylic Alkylation with Prochiral Enolates; ACS Catalysis; Vol. 6; No. 9; 6207-6213; PMCID PMC5481154; 10.1021/acscatal.6b01886
Toutov, Anton A.; Liu, Wen-Bo; et el. (2016) Potassium tert-Butoxide-Catalyzed Dehydrogenative Cross-Coupling of Heteroarenes with Hydrosilanes; Organic Syntheses; Vol. 93; 263-271; 10.15227/orgsyn.093.0263
Hayashi, Masaki; Bachman, Shoshana; et el. (2016) Ni-Catalyzed Enantioselective C-Acylation of α-Substituted Lactams; Journal of the American Chemical Society; Vol. 138; No. 29; 8997-9000; PMCID PMC4963289; 10.1021/jacs.6b02120
Craig, Robert A., II; Smith, Russell C.; et el. (2016) Preparation of 1,5-Dioxaspiro[5.5]undecan-3-one; Organic Syntheses; Vol. 93; 210-227; PMCID PMC5514842; 10.15227/orgsyn.093.0210
Estipona, Benzi I.; Pritchett, Beau P.; et el. (2016) Catalytic enantioselective total synthesis of (+)-eucomic acid; Tetrahedron; Vol. 72; No. 26; 3707-3712; PMCID PMC4986999; 10.1016/j.tet.2016.02.059
Stoltz, Brian M. and Martin, Stephen (2016) Tetrahedron Young Investigator Award ~ 2016; Tetrahedron; Vol. 72; No. 26; iii; 10.1016/j.tet.2016.04.026
Stoltz, Brian M. and Martin, Stephen (2016) Tetrahedron Young Investigator Award ~ 2016; Tetrahedron; Vol. 72; No. 26; iii; 10.1016/j.tet.2016.04.026
Wright, Austin C.; Haley, Christopher K.; et el. (2016) Synthesis of Aryl Ketoamides via Aryne Insertion into Imides; Organic Letters; Vol. 18; No. 12; 2793-2795; 10.1021/acs.orglett.6b00994
Wright, Austin C.; Haley, Christopher K.; et el. (2016) Synthesis of Aryl Ketoamides via Aryne Insertion into Imides; Organic Letters; Vol. 18; No. 12; 2793-2795; 10.1021/acs.orglett.6b00994
Han, Seo-Jung; Doi, Ryohei; et el. (2016) Nickel-Catalyzed Intramolecular C−O Bond Formation: Synthesis of Cyclic Enol Ethers; Angewandte Chemie International Edition; Vol. 55; No. 26; 7437-7440; PMCID PMC4985346; 10.1002/anie.201601991
O’Connor, Nicholas R.; Wood, John L.; et el. (2016) Synthetic Applications and Methodological Developments of Donor-Acceptor Cyclopropanes and Related Compounds; Israel Journal of Chemistry; Vol. 56; No. 6-7; 431-444; PMCID PMC6527366; 10.1002/ijch.201500089
Han, Seo-Jung and Stoltz, Brian M. (2016) A mild and efficient approach to enantioenriched α-hydroxyethyl α,β-unsaturated δ-lactams; Tetrahedron Letters; Vol. 57; No. 21; 2233-2235; PMCID PMC4864989; 10.1016/j.tetlet.2016.04.022
Liu, Wen-Bo; Okamoto, Noriko; et el. (2016) Enantioselective γ-Alkylation of α,β-Unsaturated Malonates and Ketoesters by a Sequential Ir-Catalyzed Asymmetric Allylic Alkylation/Cope Rearrangement; Journal of the American Chemical Society; Vol. 138; No. 16; 5234-5237; PMCID PMC5497580; 10.1021/jacs.6b02153
Bagdanoff, Jeffrey T.; Behenna, Douglas C.; et el. (2016) Enantioselective Synthesis of Caprolactam and Enone Precursors to the Heterocyclic DEFG Ring System of Zoanthenol; European Journal of Organic Chemistry; Vol. 2016; No. 12; 2101-2104; PMCID PMC5225988; 10.1002/ejoc.201600223
O’Connor, Nicholas R.; Bolgar, Peter; et el. (2016) Development of a simple system for the oxidation of electron-rich diazo compounds to ketones; Tetrahedron Letters; Vol. 57; No. 8; 849-851; 10.1016/j.tetlet.2016.01.020
Liniger, Marc; VanderVelde, David G.; et el. (2016) Total Synthesis and Characterization of 7-Hypoquinuclidonium Tetrafluoroborate and 7-Hypoquinuclidone BF_3 Complex; Journal of the American Chemical Society; Vol. 138; No. 3; 969-974; PMCID PMC4878439; 10.1021/jacs.5b11750
Bates, Kelvin H.; Nguyen, Tran B.; et el. (2016) Production and Fate of C_4 Dihydroxycarbonyl Compounds from Isoprene Oxidation; Journal of Physical Chemistry A; Vol. 120; No. 1; 106-117; 10.1021/acs.jpca.5b10335
Su, Judith; Goldberg, Alexander F. G.; et el. (2016) Label-free detection of single nanoparticles and biological molecules using microtoroid optical resonators; Light: Science and Applications; Vol. 5; No. 1; Art. No. e16001; PMCID PMC6059845; 10.1038/lsa.2016.1
Korch, Katerina M.; Loskot, Steven A.; et el. (2016) Asymmetric Synthesis of Quaternary Stereocenters via Metal Enolates; ISBN 9780470682531; 1-85; 10.1002/9780470682531.pat0858
Toutov, Anton A.; Liu, Wen-Bo; et el. (2015) Catalytic C–H bond silylation of aromatic heterocycles; Nature Protocols; Vol. 10; No. 12; 1897-1903; 10.1038/nprot.2015.118
Craig, Robert A., II; Loskot, Steven A.; et el. (2015) Palladium-Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Cyclopentanones; Organic Letters; Vol. 17; No. 21; 5160-5163; PMCID PMC4640231; 10.1021/acs.orglett.5b02376
Liu, Yiyang; Virgil, Scott C.; et el. (2015) Palladium-Catalyzed Decarbonylative Dehydration for the Synthesis of α-Vinyl Carbonyl Compounds and Total Synthesis of (−)-Aspewentins A, B, and C; Angewandte Chemie International Edition; Vol. 54; No. 40; 11800-11803; PMCID PMC4686263; 10.1002/anie.201505161
Kita, Yusuke; Numajiri, Yoshitaka; et el. (2015) Construction of Tertiary Chiral Centers by Pd-catalyzed Asymmetric Allylic Alkylation of Prochiral Enolate Equivalents; Tetrahedron; Vol. 71; No. 37; 6349-6353; PMCID PMC4528676; 10.1016/j.tet.2015.05.092
Xing, Xiangyou; O’Connor, Nicholas R.; et el. (2015) Palladium(II)-Catalyzed Allylic C-H Oxidation of Hindered Substrates Featuring Tunable Selectivity Over Extent of Oxidation; Angewandte Chemie International Edition; Vol. 54; No. 38; 11186-11190; 10.1002/anie.201504007
Holder, Jeffrey C.; Goodman, Emmett D.; et el. (2015) Synthesis of Diverse β-Quaternary Ketones via Palladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to Cyclic Enones; Tetrahedron; Vol. 71; No. 35; 5781-5792; PMCID PMC4598955; 10.1016/j.tet.2014.11.048
Shockley, Samantha E.; Holder, Jeffrey C.; et el. (2015) Palladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to α,β-Unsaturated Cyclic Electrophiles; Organic Process Research & Development; Vol. 19; No. 8; 974-981; PMCID PMC4896742; 10.1021/acs.oprd.5b00169
Holder, Jeffrey C.; Shockley, Samantha E.; et el. (2015) Preparation of (S)-tert-ButylPyOx and Palladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids; Organic Syntheses; Vol. 92; 247-266; PMCID PMC6499391; 10.15227/orgsyn.092.0247
Craig, Robert A., II and Stoltz, Brian M. (2015) Synthesis and exploration of electronically modified (R)-5,5-dimethyl-(p-CF₃)₃-i-PrPHOX in palladium-catalyzed enantio- and diastereoselective allylic alkylation: a practical alternative to (R)-(p-CF₃)₃-t-BuPHOX; Tetrahedron Letters; Vol. 56; No. 32; 4670-4673; PMCID PMC4524747; 10.1016/j.tetlet.2015.06.039
Marziale, Alexander N.; Duquette, Douglas C.; et el. (2015) An Efficient Protocol for the Palladium-Catalyzed Asymmetric Decarboxylative Allylic Alkylation Using Low Palladium Concentrations and a Palladium(II) Precatalyst; Advanced Synthesis and Catalysis; Vol. 357; No. 10; 2238-2245; PMCID PMC4811629; 10.1002/adsc.201500253
Bergner, Magnus; Duquette, Douglas C.; et el. (2015) Exceedingly Efficient Synthesis of (±)-Grandifloracin and Acylated Analogues; Organic Letters; Vol. 17; No. 12; 3008-3010; 10.1021/acs.orglett.5b01292
Goldberg, Alexander F. G.; Craig, Robert A., II; et el. (2015) Highly functionalized donor–acceptor cyclopropanes applied toward the synthesis of the Melodinus alkaloids; Tetrahedron Letters; Vol. 56; No. 23; 2983-2990; PMCID PMC4479304; 10.1016/j.tetlet.2014.09.016
Lee, Chung Whan; Han, Seo-Jung; et el. (2015) Stereochemical evaluation of bis(phosphine) copper catalysts for the asymmetric alkylation of 3-bromooxindoles with α-arylated malonate esters; Tetrahedron; Vol. 71; No. 22; 3666-3670; PMCID PMC4429905; 10.1016/j.tet.2014.10.065
Numajiri, Yoshitaka; Jiménez-Osés, Gonzalo; et el. (2015) Enantioselective Synthesis of Dialkylated N-Heterocycles by Palladium-Catalyzed Allylic Alkylation; Organic Letters; Vol. 17; No. 5; 1082-1085; PMCID PMC6410707; 10.1021/ol503425t
Boeser, Cornelia L.; Holder, Jeffrey C.; et el. (2015) Mechanistic analysis of an asymmetric palladium-catalyzed conjugate addition of arylboronic acids to β-substituted cyclic enones; Chemical Science; Vol. 6; No. 3; 1917-1922; PMCID PMC4338963; 10.1039/c4sc03337j
Li, Zining; Geng, Qian; et el. (2015) Selective syntheses of leuconolam, leuconoxine, and mersicarpine alkaloids from a common intermediate through regiocontrolled cyclizations by Staudinger reactions; Organic Chemistry Frontiers; Vol. 2; No. 3; 236-240; PMCID PMC4333676; 10.1039/C4QO00312H
Liu, Yiyang; Han, Seo-Jung; et el. (2015) Catalytic Enantioselective Construction of Quaternary Stereocenters: Assembly of Key Building Blocks for the Synthesis of Biologically Active Molecules; Accounts of Chemical Research; Vol. 48; No. 3; 740-751; PMCID PMC6410712; 10.1021/ar5004658
Toutov, Anton A.; Liu, Wen-Bo; et el. (2015) Silylation of C–H bonds in aromatic heterocycles by an Earth-abundant metal catalyst; Nature; Vol. 518; No. 7537; 80-84; 10.1038/nature14126
Numajiri, Yoshitaka; Pritchett, Beau P.; et el. (2015) Enantioselective Synthesis of α‑Quaternary Mannich Adducts by Palladium-Catalyzed Allylic Alkylation: Total Synthesis of (+)-Sibirinine; Journal of the American Chemical Society; Vol. 137; No. 3; 1040-1043; PMCID PMC4311947; 10.1021/ja512124c
Korch, Katerina M.; Eidamshaus, Christian; et el. (2015) Enantioselective Synthesis of α-Secondary and α-Tertiary Piperazin-2-ones and Piperazines by Catalytic Asymmetric Allylic Alkylation; Angewandte Chemie International Edition; Vol. 54; No. 1; 179-183; PMCID PMC4285707; 10.1002/anie.201408609
Han, Seo-Jung; Vogt, Florian; et el. (2015) Evolution of a Unified, Stereodivergent Approach to the Synthesis of Communesin F and Perophoramidine; Journal of Organic Chemistry; Vol. 80; No. 1; 528-547; PMCID PMC4285143; 10.1021/jo502534g
Shockley, Samantha E.; Holder, Jeffrey C.; et el. (2014) A Catalytic, Enantioselective Formal Synthesis of (+)-Dichroanone and (+)-Taiwaniaquinone H; Organic Letters; Vol. 16; No. 24; 6362-6365; PMCID PMC4275150; 10.1021/ol5031537
Han, Seo-Jung; de Melo, Gabriel Fernando; et el. (2014) A new method for the cleavage of nitrobenzyl amides and ethers; Tetrahedron Letters; Vol. 55; No. 47; 6467-6469; PMCID PMC4228375; 10.1016/j.tetlet.2014.10.006
Liu, Yiyang; Liniger, Marc; et el. (2014) Formal total syntheses of classic natural product target molecules via palladium-catalyzed enantioselective alkylation; Beilstein Journal of Organic Chemistry; Vol. 10; 2501-2512; PMCID PMC4222294; 10.3762/bjoc.10.261
Gordon, Jonny R.; Nelson, Hosea M.; et el. (2014) The Total Syntheses of Basiliolide C, epi-Basiliolide C, and Protecting-Group-Free Total Syntheses of Transtaganolides C and D; Journal of Organic Chemistry; Vol. 79; No. 20; 9740-9747; 10.1021/jo501924u
Bhat, Vikram; Virgil, Scott C.; et el. (2014) Asymmetric synthesis of QUINAP via dynamic kinetic resolution
Holder, Jeffrey C.; Shockley, Samantha E.; et el. (2014) Development and application of a palladium-catalyzed enantioselective conjugate addition
Ma, Sandy; Reeves, Corey M.; et el. (2014) Palladium-catalyzed decarboxylative allylic alkylation of diastereomeric β-ketoesters; Tetrahedron; Vol. 70; No. 27-28; 4208-4212; PMCID PMC4078409; 10.1016/j.tet.2014.03.042
Han, Seo-Jung; Vogt, Florian; et el. (2014) A Diastereodivergent Synthetic Strategy for the Syntheses of Communesin F and Perophoramidine; Organic Letters; Vol. 16; No. 12; 3316-3319; PMCID PMC4068777; 10.1021/ol5013263
Hong, Allen Y. and Stoltz, Brian M. (2014) Biosynthesis and Chemical Synthesis of Presilphiperfolanol Natural Products; Angewandte Chemie International Edition; Vol. 53; No. 21; 5248-5260; PMCID PMC4334158; 10.1002/anie.201309494
Reeves, Corey M.; Behenna, Douglas C.; et el. (2014) Development of (Trimethylsilyl)ethyl Ester Protected Enolates and Applications in Palladium-Catalyzed Enantioselective Allylic Alkylation: Intermolecular Cross-Coupling of Functionalized Electrophiles; Organic Letters; Vol. 16; No. 9; 2314-2317; PMCID PMC4011571; 10.1021/ol500355z
Craig, Robert A., II; O’Connor, Nicholas R.; et el. (2014) Stereoselective Lewis Acid Mediated (3+2) Cycloadditions of N-H- and N-Sulfonylaziridines with Heterocumulenes; Chemistry: a European Journal; Vol. 20; No. 16; 4806-4813; PMCID PMC4104980; 10.1002/chem.201303699
Jones, Amanda C.; May, Jeremy A.; et el. (2014) Toward a Symphony of Reactivity: Cascades Involving Catalysis and Sigmatropic Rearrangements; Angewandte Chemie International Edition; Vol. 53; No. 10; 2556-2591; PMCID PMC4030764; 10.1002/anie.201302572
Bates, Kelvin H.; Crounse, John D.; et el. (2014) Gas Phase Production and Loss of Isoprene Epoxydiols; Journal of Physical Chemistry A; Vol. 118; No. 7; 1237-1246; 10.1021/jp4107958
Krishnan, Subramanian; Shanmuganathan, Muthusamy V.; et el. (2014) Angiotensin II Receptor Type 1—A Novel Target for Preventing Neonatal Meningitis in Mice by Escherichia coli K1; Journal of Infectious Diseases; Vol. 209; No. 3; 409-419; PMCID PMC3883175; 10.1093/infdis/jit499
Liu, Yiyang; Kim, Kelly E.; et el. (2014) Palladium-Catalyzed Decarbonylative Dehydration of Fatty Acids for the Production of Linear Alpha Olefins; Advanced Synthesis and Catalysis; Vol. 356; No. 1; 130-136; PMCID PMC3998208
Stoltz, B. M.; Bennett, N. B.; et el. (2014) Alkylations of Enols and Enolates; ISBN 978-0-08-097743-0; 1-55; 10.1016/B978-0-08-097742-3.00301-3
Bennett, Nathan B. and Stoltz, Brian M. (2013) A Unified Approach to the Daucane and Sphenolobane Bicyclo[5.3.0]decane Core: Enantioselective Total Syntheses of Daucene, Daucenal, Epoxydaucenal B, and 14-para-Anisoyloxydauc-4,8-diene; Chemistry: a European Journal; Vol. 19; No. 52; 17745-17750; PMCID PMC3927641; 10.1002/chem.201302353
Liu, Wen-Bo; Reeves, Corey M.; et el. (2013) Enantio-, Diastereo-, and Regioselective Iridium-Catalyzed Asymmetric Allylic Alkylation of Acyclic β-Ketoesters; Journal of the American Chemical Society; Vol. 135; No. 46; 17298-17301; PMCID PMC3881553; 10.1021/ja4097829
Bhat, Vikram; Wang, Su; et el. (2013) Asymmetric Synthesis of QUINAP via Dynamic Kinetic Resolution; Journal of the American Chemical Society; Vol. 135; No. 45; 16829-16832; 10.1021/ja409383f
Holder, Jeffrey C.; Zou, Lufeng; et el. (2013) Mechanism and Enantioselectivity in Palladium-Catalyzed Conjugate Addition of Arylboronic Acids to β‑Substituted Cyclic Enones: Insights from Computation and Experiment; Journal of the American Chemical Society; Vol. 135; No. 40; 14996-15007; PMCID PMC3846424; 10.1021/ja401713g
Meyer, Michael E.; Phillips, John H.; et el. (2013) Use of a palladium(II)-catalyzed oxidative kinetic resolution in synthetic efforts toward bielschowskysin; Tetrahedron; Vol. 69; No. 36; 7627-7635; PMCID PMC3728638; 10.1016/j.tet.2013.02.034
Shimizu, Hideki; Holder, Jeffrey C.; et el. (2013) A scalable synthesis of the (S)-4-(tert-butyl)-2-(pyridin-2-yl)-4,5-dihydrooxazole ((S)-t-BuPyOx) ligand; Beilstein Journal of Organic Chemistry; Vol. 9; 1637-1642; PMCID PMC3778391; 10.3762/bjoc.9.187
Liu, Wen-Bo; Reeves, Corey M.; et el. (2013) Construction of Vicinal Tertiary and All-Carbon Quaternary Stereocenters via Ir-Catalyzed Regio-, Diastereo-, and Enantioselective Allylic Alkylation and Applications in Sequential Pd Catalysis; Journal of the American Chemical Society; Vol. 135; No. 29; 10626-10629; PMCID PMC3756902; 10.1021/ja4052075
Haley, Christopher K.; Gilmore, Christopher D.; et el. (2013) Development of a palladium-catalyzed decarboxylative cross-coupling of (2-azaaryl)carboxylates with aryl halides; Tetrahedron; Vol. 69; No. 27-28; 5732-5736; PMCID PMC3686134; 10.1016/j.tet.2013.03.085
Shibuya, Grant M.; Enquist, John A., Jr.; et el. (2013) Enantioselective Synthesis of the 5–6–7 Carbocyclic Core of the Gagunin Diterpenoids; Organic Letters; Vol. 15; No. 13; 3480-3483; PMCID PMC3743267; 10.1021/ol401514s
Vieregg, Jeffrey R.; Nelson, Hosea M.; et el. (2013) Selective Nucleic Acid Capture with Shielded Covalent Probes; Journal of the American Chemical Society; Vol. 135; No. 26; 9691-9699; PMCID PMC3703666; 10.1021/ja4009216
Reeves, Corey M.; Eidamshaus, Christian; et el. (2013) Enantioselective Construction of α-Quaternary Cyclobutanones by Catalytic Asymmetric Allylic Alkylation; Angewandte Chemie International Edition; Vol. 52; No. 26; 6718-6721; PMCID PMC3817853; 10.1002/anie.201301815
Nelson, Hosea M.; Gordon, Jonny R.; et el. (2013) Total Syntheses of (-)-Transtaganolide A, (+)-Transtaganolide B, (+)-Transtaganolide C, and (-)-Transtaganolide D and Biosynthetic Implications; Angewandte Chemie International Edition; Vol. 52; No. 26; 6699-6703; PMCID PMC3825171; 10.1002/anie.201301212
Hong, Allen Y. and Stoltz, Brian M. (2013) The Construction of All-Carbon Quaternary Stereocenters by Use of Pd-Catalyzed Asymmetric Allylic Alkylation Reactions in Total Synthesis; European Journal of Organic Chemistry; Vol. 2013; No. 14; 2745-2759; PMCID PMC4059687; 10.1002/ejoc.201201761
Holder, Jeffrey C.; Kikushima, Kotaro; et el. (2013) Development of a palladium-catalyzed enantioselective conjugate addition of arylboronic acids to cyclic conjugate acceptors
Bennett, Nathan B.; Duquette, Douglas C.; et el. (2013) Expanding Insight into Asymmetric Palladium-Catalyzed Allylic Alkylation of N-Heterocyclic Molecules and Cyclic Ketones; Chemistry: a European Journal; Vol. 19; No. 14; 4414-4418; PMCID PMC3815597; 10.1002/chem.201300030
Su, Judith; Goldberg, Alex; et el. (2013) Frequency Locked Microtoroid Optical Resonators as a Non-Invasive Tumor Biopsy Alternative; Biophysical Journal; Vol. 104; No. 2; 528A; 10.1016/j.bpj.2012.11.2924
Holder, Jeffrey C.; Marziale, Alexander N.; et el. (2013) Palladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to Heterocyclic Acceptors; Chemistry: a European Journal; Vol. 19; No. 1; 74-77; PMCID PMC3753812; 10.1002/chem.201203643
Caspi, Daniel D.; Zhang, Haiming; et el. (2012) Rapid and Convergent Synthesis of a 2,4’-Linked Tri-oxazole in an Approach to Poly-oxazoles; Heterocycles; Vol. 86; No. 2; 1003-1008; 10.3987/COM-12-S(N)118
Caspi, Daniel D.; Zhang, Haiming; et el. (2012) Rapid and Convergent Synthesis of a 2,4’-Linked Tri-oxazole in an Approach to Poly-oxazoles; Heterocycles; Vol. 86; No. 2; 1003-1008; 10.3987/COM-12-S(N)118
Keith, John A.; Behenna, Douglas C.; et el. (2012) The Reaction Mechanism of the Enantioselective Tsuji Allylation: Inner-Sphere and Outer-Sphere Pathways, Internal Rearrangements, and Asymmetric C–C Bond Formation; Journal of the American Chemical Society; Vol. 134; No. 46; 19050-19060; PMCID PMC3537505; 10.1021/ja306860n
Craig, Robert A., II; Roizen, Jennifer L.; et el. (2012) Enantioselective Synthesis of a Hydroxymethyl-cis-1,3-cyclopentenediol Building Block; Organic Letters; Vol. 14; No. 22; 5716-5719; PMCID PMC3506031; 10.1021/ol3027297
Reeves, Corey M. and Stoltz, Brian M. (2012) Catalytic Enantioselective Alkylation of Prochiral Ketone Enolates; ISBN 9783527329212; 1-10; 10.1002/9783527652235.ch1
Goldberg, Alexander F. G.; O’Connor, Nicholas R.; et el. (2012) Lewis Acid Mediated (3 + 2) Cycloadditions of Donor–Acceptor Cyclopropanes with Heterocumulenes; Organic Letters; Vol. 14; No. 20; 5314-5317; PMCID PMC3490221; 10.1021/ol302494n
Hong, Allen Y. and Stoltz, Brian M. (2012) Enantioselective Total Synthesis of the Reported Structures of (−)-9-epi-Presilphiperfolan-1-ol and (−)-Presilphiperfolan-1-ol: Structural Confirmation and Reassignment and Biosynthetic Insights; Angewandte Chemie International Edition; Vol. 51; No. 38; 9674-9678; PMCID PMC3517068; 10.1002/anie.201205276
Kim, Jimin and Stoltz, Brian M. (2012) A C–N insertion of β-lactam to benzyne: unusual formation of acridone; Tetrahedron Letters; Vol. 53; No. 37; 4994-4996; 10.1016/j.tetlet.2012.07.026
Kim, Jimin and Stoltz, Brian M. (2012) A C–N insertion of β-lactam to benzyne: unusual formation of acridone; Tetrahedron Letters; Vol. 53; No. 37; 4994-4996; 10.1016/j.tetlet.2012.07.026
Behenna, Douglas C. and Stoltz, Brian M. (2012) Natural Products as Inspiration for Reaction Development: Catalytic Enantioselective Decarboxylative Reactions of Prochiral Enolate Equivalents; ISBN 978-3-642-34285-1; 281-314; 10.1007/3418_2012_49
Stoltz, Brian M. (2012) Novel approach to antitumor antibiotics: Using the power of benzyne in synthesis
Vieregg, Jeffrey R.; Nelson, Hosea M.; et el. (2012) Sensitive and selective nucleic acid capture with shielded covalent probes
Tadross, Pamela M. and Stoltz, Brian M. (2012) A Comprehensive History of Arynes in Natural Product Total Synthesis; Chemical Reviews; Vol. 112; No. 6; 3550-3577; 10.1021/cr200478h
Behenna, Douglas C.; Liu, Yiyang; et el. (2012) Enantioselective construction of quaternary N-heterocycles by palladium-catalysed decarboxylative allylic alkylation of lactams; Nature Chemistry; Vol. 4; No. 2; 130-133; PMCID PMC3266627; 10.1038/nchem.1222
Bennett, Nathan B.; Hong, Allen Y.; et el. (2012) Synthesis of enantioenriched γ-quaternary cycloheptenones using a combined allylic alkylation/Stork–Danheiser approach: preparation of mono-, bi-, and tricyclic systems; Organic and Biomolecular Chemistry; Vol. 10; No. 1; 56-59; PMCID PMC3365663; 10.1039/C1OB06189E
Hong, Allen Y.; Bennett, Nathan B.; et el. (2011) Palladium-catalyzed asymmetric alkylation in the synthesis of cyclopentanoid and cycloheptanoid core structures bearing all-carbon quaternary stereocenters; Tetrahedron; Vol. 67; No. 52; 10234-10248; PMCID PMC3279929; 10.1016/j.tet.2011.10.031
Behenna, Douglas C.; Mohr, Justin T.; et el. (2011) Enantioselective Decarboxylative Alkylation Reactions: Catalyst Development, Substrate Scope, and Mechanistic Studies; Chemistry: a European Journal; Vol. 17; No. 50; 14199-14223; PMCID PMC3365686; 10.1002/chem.201003383
Enquist, John A., Jr.; Virgil, Scot C.; et el. (2011) Total Syntheses of Cyanthiwigins B, F, and G; Chemistry: a European Journal; Vol. 17; No. 36; 9957-9969; PMCID PMC3365662; 10.1002/chem.201100425
Goldberg, Alexander F. G. and Stoltz, Brian M. (2011) A Palladium-Catalyzed Vinylcyclopropane (3 + 2) Cycloaddition Approach to the Melodinus Alkaloids; Organic Letters; Vol. 13; No. 16; 4474-4476; PMCID PMC3155617; 10.1021/ol2017615
Goldberg, Alexander F. G. and Stoltz, Brian M. (2011) A Palladium-Catalyzed Vinylcyclopropane (3 + 2) Cycloaddition Approach to the Melodinus Alkaloids; Organic Letters; Vol. 13; No. 16; 4474-4476; PMCID PMC3155617; 10.1021/ol2017615
Tadross, Pamela M.; Bugga, Pradeep; et el. (2011) A rapid and convergent synthesis of the integrastatin core; Organic and Biomolecular Chemistry; Vol. 9; No. 15; 5354-5357; 10.1039/c1ob05725a
Day, Joshua J.; McFadden, Ryan M.; et el. (2011) The Catalytic Enantioselective Total Synthesis of (+)-Liphagal; Angewandte Chemie International Edition; Vol. 50; No. 30; 6814-6818; PMCID PMC3361906; 10.1002/anie.201101842
Petersen, Kimberly S. and Stoltz, Brian

1. Palladium-catalyzed, asymmetric Baeyer–Villiger oxidation of prochiral cyclobutanones with PHOX ligands; Tetrahedron; Vol. 67; No. 24; 4352-4357; 10.1016/j.tet.2011.04.046

Kikushima, Kotaro; Holder, Jeffrey C.; et el. (2011) Palladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to Five-, Six-, and Seven-Membered β-Substituted Cyclic Enones: Enantioselective Construction of All-Carbon Quaternary Stereocenters; Journal of the American Chemical Society; Vol. 133; No. 18; 6902-6905; PMCID PMC3087848; 10.1021/ja200664x
Allan, Kevin M.; Gilmore, Christopher D.; et el. (2011) Benzannulated Bicycles by Three-Component Aryne Reactions; Angewandte Chemie International Edition; Vol. 50; No. 19; 4488-4491; 10.1002/anie.201100911
Behenna, Douglas C.; Krishnan, Shyam; et el. (2011) Confirmation of the absolute configuration of (-)-aurantioclavine; Tetrahedron Letters; Vol. 52; No. 17; 2152-2154; 10.1016/j.tetlet.2010.11.074
Nelson, Hosea M.; Murakami, Kei; et el. (2011) A General Approach to the Basiliolide/Transtaganolide Natural Products: Total Syntheses of Basiliolide B, epi-8-Basiliolide B, Transtaganolide C, and Transtaganolide D; Angewandte Chemie International Edition; Vol. 50; No. 16; 3688-3691; 10.1002/anie.201008003
Chou, Tsui-Fen; Brown, Steve J.; et el. (2011) Reversible inhibitor of p97, DBeQ, impairs both ubiquitin-dependent and autophagic protein clearance pathways; Proceedings of the National Academy of Sciences of the United States of America; Vol. 108; No. 12; 4834-4839; PMCID PMC3064330; 10.1073/pnas.1015312108
Hong, Allen Y.; Krout, Michael R.; et el. (2011) Ring-Contraction Strategy for the Practical, Scalable, Catalytic Asymmetric Synthesis of Versatile γ-Quaternary Acylcyclopentenes; Angewandte Chemie International Edition; Vol. 50; No. 12; 2756-2760; PMCID PMC3365661; 10.1002/anie.201007814
Mukherjee, Herschel; McDougal, Nolan T.; et el. (2011) A Catalytic, Asymmetric Formal Synthesis of (+)-Hamigeran B; Organic Letters; Vol. 13; No. 5; 825-827; PMCID PMC3045637; 10.1021/ol102669z
Stoltz, B. M. (2010) Complex natural products as a driving force for discovery in organic chemistry
Stoltz, B. M. (2010) Intertwined nature of chemical synthesis and the discovery process
McDougal, Nolan T.; Streuff, Jan; et el. (2010) Rapid synthesis of an electron-deficient t-BuPHOX ligand: cross-coupling of aryl bromides with secondary phosphine oxides; Tetrahedron Letters; Vol. 51; No. 42; 5550-5554; PMCID PMC2976555; 10.1016/j.tetlet.2010.08.039
Freeman, David B.; Holubec, Alexandra A.; et el. (2010) Welwitindolinone C synthetic studies. Construction of the welwitindolinone carbon skeleton via a transannular nitrone cycloaddition; Tetrahedron; Vol. 66; No. 33; 6647-6655; PMCID PMC2924776; 10.1016/j.tet.2010.04.131
McDougal, Nolan T.; Virgil, Scott C.; et el. (2010) High-Throughput Screening of the Asymmetric Decarboxylative Alkylation Reaction of Enolate-Stabilized Enol Carbonates; Synlett; Vol. 2010; No. 11; 1712-1716; PMCID PMC2976558; 10.1055/s-0030-1258094
Baumgartner, Corinne; Ma, Sandy; et el. (2010) Efforts toward rapid construction of the cortistatin A carbocyclic core via enyne-ene metathesis; Organic and Biomolecular Chemistry; Vol. 8; No. 13; 2915-2917; 10.1039/c004275g
White, David E.; Stewart, Ian C.; et el. (2010) A general enantioselective route to the chamigrene natural product family; Tetrahedron; Vol. 66; No. 26; 4668-4686; PMCID PMC2925317; 10.1016/j.tet.2010.04.128
Fulmer, Gregory R.; Miller, Alexander J. M.; et el. (2010) NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist; Organometallics; Vol. 29; No. 9; 2176-2179; 10.1021/om100106e
Tadross, Pamela M.; Virgil, Scott C.; et el. (2010) Aryne Acyl-Alkylation in the General and Convergent Synthesis of Benzannulated Macrolactone Natural Products: An Enantioselective Synthesis of (−)-Curvularin; Organic Letters; Vol. 12; No. 7; 1612-1614; 10.1021/ol100335y
Tadross, Pamela M.; Gilmore, Christopher D.; et el. (2010) Regioselective Reactions of Highly Substituted Arynes; Organic Letters; Vol. 12; No. 6; 1224-1227; 10.1021/ol1000796
Streuff, Jan; White, David E.; et el. (2010) A palladium-catalysed enolate alkylation cascade for the formation of adjacent quaternary and tertiary stereocentres; Nature Chemistry; Vol. 2; No. 3; 192-196; PMCID PMC2917108; 10.1038/nchem.518
Allan, Kevin M.; Hong, Boram D.; et el. (2009) Expedient synthesis of 3-hydroxyisoquinolines and 2-hydroxy-1,4-naphthoquinones via one-pot aryne acyl-alkylation/condensation; Organic and Biomolecular Chemistry; Vol. 7; No. 23; 4960-4964; 10.1039/b913336d
Ebner, David C.; Bagdanoff, Jeffrey T.; et el. (2009) The Palladium-Catalyzed Aerobic Kinetic Resolution of Secondary Alcohols: Reaction Development, Scope, and Applications; Chemistry: a European Journal; Vol. 15; No. 47; 12978-12992; PMCID PMC2862982; 10.1002/chem.200902172
Ma, Sandy; Han, Xiaoqing; et el. (2009) Catalytic Enantioselective Stereoablative Alkylation of 3-Halooxindoles: Facile Access to Oxindoles with C3 All-Carbon Quaternary Stereocenters; Angewandte Chemie International Edition; Vol. 48; No. 1; 1-6; 10.1002/anie.200902943
Sherden, Nathaniel H.; Behenna, Douglas C.; et el. (2009) Unusual Allylpalladium Carboxylate Complexes: Identification of the Resting State of Catalytic Enantioselective Decarboxylative Allylic Alkylation Reactions of Ketones; Angewandte Chemie International Edition; Vol. 48; No. 37; 6840-6843; PMCID PMC2880474; 10.1002/anie.200902575
Stockdill, Jennifer L.; Behenna, Douglas C.; et el. (2009) An efficient synthesis of the carbocyclic core of zoanthenol; Tetrahedron; Vol. 65; No. 33; 6571-6575; 10.1016/j.tet.2009.05.023
Mohr, Justin T.; Hong, Allen Y.; et el. (2009) Enantioselective protonation; Nature Chemistry; Vol. 1; No. 5; 359-369; PMCID PMC2860147; 10.1038/nchem.297
Stockdill, Jennifer L.; Behenna, Douglas C.; et el. (2009) Unexpected decarbonylation during an acid-mediated cyclization to access the carbocyclic core of zoanthenol; Tetrahedron Letters; Vol. 50; No. 26; 3182-3184; 10.1016/j.tetlet.2009.01.121
Enquist, John A. and Stoltz, Brian M. (2009) Synthetic efforts toward cyathane diterpenoid natural products; Natural Product Reports; Vol. 26; No. 5; 661-680; PMCID PMC2683363; 10.1039/b811227b
Nelson, Hosea M. and Stoltz, Brian M. (2009) Progress toward the synthesis of the transtaganolide/basiliolide natural products: an Ireland–Claisen approach; Tetrahedron Letters; Vol. 50; No. 15; 1699-1701; 10.1016/j.tetlet.2009.01.108
Sun, Qingyu; Nelson, Hosea; et el. (2009) Side chain chemistry mediates backbone fragmentation in hydrogen deficient peptide radicals; Journal of Proteome Research; Vol. 8; No. 2; 958-966; 10.1021/pr800592t
Ebner, David C.; Tambar, Uttam K.; et el. (2009) The direct acyl-alkylation of arynes. Preparation of methyl 2-(2-acetylphenyl)acetate; Organic Syntheses; Vol. 86; 161-171; 10.15227/orgsyn.086.0161
Levine, Samantha R.; Krout, Michael R.; et el. (2009) Catalytic enantioselective approach to the eudesmane sesquiterpenoids: total synthesis of (+)-carissone; Organic Letters; Vol. 11; No. 2; 289-292; PMCID PMC2724392; 10.1021/ol802409h
Petrova, Krastina V.; Mohr, Justin T.; et el. (2009) Enantioselective Total Synthesis of (+)-Cassiol; Organic Letters; Vol. 11; No. 2; 293-295; PMCID PMC2707596; 10.1021/ol802410t
Mohr, Justin T.; Krout, Michael R.; et el. (2009) Preparation of (S)-2-Allyl-2-methylcyclohexanone (Cyclohexanone, 2-methyl-2-(2-propen-1-yl)-, (2S)-); Organic Syntheses; Vol. 86; 194-211; PMCID PMC3011275; 10.15227/orgsyn.086.0194
Stoltz, Brian M.; Krout, Michael R.; et el. (2009) Preparation of (S)-tert-ButylPHOX (Oxazole, 4-(1,1-dimethylethyl)-2-[2-(diphenylphosphino)phenyl]-4,5-dihydro- (4S)-); Organic Syntheses; Vol. 86; 181-193; PMCID PMC2805096; 10.15227/orgsyn.086.0181
Allan, Kevin M. and Stoltz, Brian M. (2008) A concise total synthesis of (−)-quinocarcin via aryne annulation; Journal of the American Chemical Society; Vol. 130; No. 51; 17270-17271; 10.1021/ja808112y
Trend, Raissa M. and Stoltz, Brian M. (2008) Structural features and reactivity of (sparteine)PdCl_2: a model for selectivity in the oxidative kinetic resolution of secondary alcohols; Journal of the American Chemical Society; Vol. 130; No. 47; 15957-15966; PMCID PMC2649720; 10.1021/ja804955e
Krishnan, Shyam; Bagdanoff, Jeffrey T.; et el. (2008) Pd-catalyzed enantioselective aerobic oxidation of secondary alcohols: Applications to the total synthesis of alkaloids; Journal of the American Chemical Society; Vol. 130; No. 41; 13745-13754; PMCID PMC2574996; 10.1021/ja804738b
Mohr, Justin T.; Krout, Michael R.; et el. (2008) Natural products as inspiration for the development of asymmetric catalysis; Nature; Vol. 455; No. 7211; 323-332; PMCID PMC2562237; 10.1038/nature07370
Seto, Masaki; Roizen, Jennifer L.; et el. (2008) Catalytic Enantioselective Alkylation of Substituted Dioxanone Enol Ethers: Ready Access to C(α)-Tetrasubstituted Hydroxyketones, Acids, and Esters; Angewandte Chemie International Edition; Vol. 47; No. 36; 6873-6876; PMCID PMC2762748; 10.1002/anie.200801424
Ebner, David C.; Trend, Raissa M.; et el. (2008) Palladium-Catalyzed Enantioselective Oxidation of Chiral Secondary Alcohols: Access to Both Enantiomeric Series; Angewandte Chemie International Edition; Vol. 47; No. 34; 6367-6370; PMCID PMC2790069; 10.1002/anie.200801865
Enquist, John A., Jr. and Stoltz, Brian M. (2008) The total synthesis of (-)-cyanthiwigin F by means of double catalytic enantioselective alkylation; Nature; Vol. 453; No. 7199; 1228-1231; PMCID PMC2474750; 10.1038/nature07046
Ferreira, Eric M.; Zhang, Haiming; et el. (2008) C–H bond functionalizations with palladium(II): intramolecular oxidative annulations of arenes; Tetrahedron; Vol. 64; No. 26; 5987-6001; PMCID PMC2441596; 10.1016/j.tet.2008.01.052
Marinescu, Smaranda C.; Nishimata, Toyoki; et el. (2008) Homogeneous Pd-Catalyzed Enantioselective Decarboxylative Protonation; Organic Letters; Vol. 10; No. 6; 1039-1042; PMCID PMC2966305; 10.1021/ol702821j
Behenna, Douglas C.; Stockdill, Jennifer L.; et el. (2008) The Biology and Chemistry of the Zoanthamine Alkaloids; Angewandte Chemie International Edition; Vol. 47; No. 13; 2365-2386; 10.1002/anie.200703172
Gilmore, Christopher D.; Allan, Kevin M.; et el. (2008) Orthogonal Synthesis of Indolines and Isoquinolines via Aryne Annulation; Journal of the American Chemical Society; Vol. 130; No. 5; 1558-1559; 10.1021/ja0780582
White, David E.; Stewart, Ian C.; et el. (2008) The Catalytic Asymmetric Total Synthesis of Elatol; Journal of the American Chemical Society; Vol. 130; No. 3; 810-811; PMCID PMC2533138; 10.1021/ja710294k
Nelson, Hosea M. and Stoltz, Brian M. (2008) Progress toward the Synthesis of the Basiliolides and Transtaganolides: An Intramolecular Pyrone Diels−Alder Entry into a Novel Class of Natural Products; Organic Letters; Vol. 10; No. 1; 25-28; 10.1021/ol702501s
Mohr, Justin T. and Stoltz, Brian M. (2007) Enantioselective Tsuji Allylations; Chemistry – An Asian Journal; Vol. 2; No. 12; 1476-1491; PMCID PMC2967289; 10.1002/asia.200700183
Mohr, Justin T.; Ebner, David C.; et el. (2007) Catalytic enantioselective stereoablative reactions: an unexploited approach to enantioselective catalysis; Organic and Biomolecular Chemistry; Vol. 5; No. 22; 3571-3576; PMCID PMC2963431; 10.1039/B711159M
Keith, John A.; Behenna, Douglas C.; et el. (2007) The Inner-Sphere Process in the Enantioselective Tsuji Allylation Reaction with (S)-t-Bu-phosphinooxazoline Ligands; Journal of the American Chemical Society; Vol. 129; No. 39; 11876-11877; 10.1021/ja070516j
Liu, Qi; Ferreira, Eric M.; et el. (2007) Convergency and Divergency as Strategic Elements in Total Synthesis: The Total Synthesis of (−)-Drupacine and the Formal Total Synthesis of (±)-Cephalotaxine, (−)-Cephalotaxine, and (+)-Cephalotaxine; Journal of Organic Chemistry; Vol. 72; No. 19; 7352-7358; 10.1021/jo0710883
Tani, Kousuke; Behenna, Douglas C.; et el. (2007) A Facile and Modular Synthesis of Phosphinooxazoline Ligands; Organic Letters; Vol. 9; No. 13; 2529-2531; 10.1021/ol070884s
Behenna, Douglas C.; Stockdill, Jennifer L.; et el. (2007) Synthesis of the Carbocyclic Core of Zoanthenol: Implementation of an Unusual Acid-Catalyzed Cyclization; Angewandte Chemie International Edition; Vol. 46; No. 22; 4077-4080; 10.1002/anie.200700430
Ly, Tony; Krout, Michael; et el. (2007) Synthesis of 2-Quinuclidonium by Eliminating Water: Experimental Quantification of the High Basicity of Extremely Twisted Amides; Journal of the American Chemical Society; Vol. 129; No. 7; 1864-1865; 10.1021/ja067703m
Ferreira, Eric M. and Stoltz, Brian M. (2006) The synthesis of C-3β functionalized indoles via a hydroboration/Suzuki–Miyaura coupling sequence; Tetrahedron Letters; Vol. 47; No. 48; 8579-8582; PMCID PMC1832155; 10.1016/j.tetlet.2006.09.112
Tambar, Uttam K.; Kano, Taichi; et el. (2006) Convergent and Diastereoselective Synthesis of the Polycyclic Pyran Core of Saudin; Journal of Organic Chemistry; Vol. 71; No. 22; 8357-8364; 10.1021/jo061236+
Garg, Neil K. and Stoltz, Brian M. (2006) A unified synthetic approach to the pyrazinone dragmacidins; Chemical Communications; Vol. 2006; No. 36; 3769-3779; 10.1039/b605929e
Tambar, Uttam K.; Ebner, David C.; et el. (2006) A Convergent and Enantioselective Synthesis of (+)-Amurensinine via Selective C−H and C−C Bond Insertion Reactions; Journal of the American Chemical Society; Vol. 128; No. 36; 11752-11753; PMCID PMC2529249; 10.1021/ja0651815
Mohr, Justin T.; Nishimata, Toyoki; et el. (2006) Catalytic Enantioselective Decarboxylative Protonation; Journal of the American Chemical Society; Vol. 128; No. 35; 11348-11349; 10.1021/ja063335a
McFadden, Ryan M. and Stoltz, Brian M. (2006) The Catalytic Enantioselective, Protecting Group-Free Total Synthesis of (+)-Dichroanone; Journal of the American Chemical Society; Vol. 128; No. 24; 7738-7739; 10.1021/ja061853f
Tani, Kousuke and Stoltz, Brian M. (2006) Synthesis and structural analysis of 2-quinuclidonium tetrafluoroborate; Nature; Vol. 441; No. 7094; 731-734; 10.1038/nature04842
Meyer, Michael E.; Ferreira, Eric M.; et el. (2006) 2-Diazoacetoacetic acid, an efficient and convenient reagent for the synthesis of alpha-diazo-beta-ketoesters; Chemical Communications; Vol. 2006; No. 12; 1316-1318; 10.1039/b517719g
Lacenere, Christopher J.; Garg, Neil K.; et el. (2006) Effects of a Modified Dye-Labeled Nucleotide Spacer Arm on Incorporation by Thermophilic DNA Polymerases; Nucleosides, Nucleotides and Nucleic Acids; Vol. 25; No. 1; 9-15; 10.1080/15257770500377714
Trend, Raissa M.; Ramtohul, Yeeman K.; et el. (2005) Oxidative Cyclizations in a Nonpolar Solvent Using Molecular Oxygen and Studies on the Stereochemistry of Oxypalladation; Journal of the American Chemical Society; Vol. 127; No. 50; 17778-17788; PMCID PMC2585987; 10.1021/ja055534k
Mohr, Justin T.; Behenna, Douglas C.; et el. (2005) Deracemization of Quaternary Stereocenters by Pd-Catalyzed Enantioconvergent Decarboxylative Allylation of Racemic β-Ketoesters; Angewandte Chemie International Edition; Vol. 44; No. 42; 6924-6927; 10.1002/anie.200502018
Caspi, Daniel D.; Garg, Neil K.; et el. (2005) Heterogeneous Reductive Isomerization Reaction Using Catalytic Pd/C and H_2; Organic Letters; Vol. 7; No. 12; 2513-2516; 10.1021/ol050952f
Tambar, Uttam K.; Kano, Taichi; et el. (2005) Progress toward the Total Synthesis of Saudin: Development of a Tandem Stille-Oxa-Electrocyclization Reaction; Organic Letters; Vol. 7; No. 12; 2413-2416; 10.1021/ol050705b
Garg, Neil K.; Caspi, Daniel D.; et el. (2005) Development of an Enantiodivergent Strategy for the Total Synthesis of (+)- and (−)-Dragmacidin F from a Single Enantiomer of Quinic Acid; Journal of the American Chemical Society; Vol. 127; No. 16; 5970-5978; 10.1021/ja050586v
Tambar, Uttam K. and Stoltz, Brian M. (2005) The Direct Acyl-Alkylation of Arynes; Journal of the American Chemical Society; Vol. 127; No. 15; 5340-5341; 10.1021/ja050859m
Garg, Neil K.; Woodroofe, Carolyn C.; et el. (2005) A ligand-free solid-supported system for Sonogashira couplings: applications in nucleoside chemistry; Chemical Communications; Vol. 2005; No. 36; 4551-4553; 10.1039/b505737j
Behenna, Douglas C. and Stoltz, Brian M. (2004) The Enantioselective Tsuji Allylation; Journal of the American Chemical Society; Vol. 126; No. 46; 15044-15045; 10.1021/ja044812x
Behenna, Douglas C. and Stoltz, Brian M. (2004) The Enantioselective Tsuji Allylation; Journal of the American Chemical Society; Vol. 126; No. 46; 15044-15045; 10.1021/ja044812x
Zhang, Haiming; Ferreira, Eric M.; et el. (2004) Direct Oxidative Heck Cyclizations: Intramolecular Fujiwara-Moritani Arylations for the Synthesis of Functionalized Benzofurans and Dihydrobenzofurans; Angewandte Chemie International Edition; Vol. 43; No. 45; 6144-6148; 10.1002/anie.200461294
Garg, Neil K.; Caspi, Daniel D.; et el. (2004) The Total Synthesis of (+)-Dragmacidin F; Journal of the American Chemical Society; Vol. 126; No. 31; 9552-9553; 10.1021/ja046695b
Nielsen, Robert J.; Keith, Jason M.; et el. (2004) A Computational Model Relating Structure and Reactivity in Enantioselective Oxidations of Secondary Alcohols by (−)-Sparteine−Pd^(II) Complexes; Journal of the American Chemical Society; Vol. 126; No. 25; 7967-7974; 10.1021/ja031911m
Trend, Raissa M. and Stoltz, Brian M. (2004) An Experimentally Derived Model for Stereoselectivity in the Aerobic Oxidative Kinetic Resolution of Secondary Alcohols by (Sparteine)PdCl_2; Journal of the American Chemical Society; Vol. 126; No. 14; 4482-4483; 10.1021/ja039551q
Su, Julius T.; Sarpong, Richmond; et el. (2004) Substituent Effects and Nearly Degenerate Transition States: Rational Design of Substrates for the Tandem Wolff−Cope Reaction; Journal of the American Chemical Society; Vol. 126; No. 1; 24-25; 10.1021/ja037716p
Bagdanoff, Jeffrey T. and Stoltz, Brian

1. Palladium-Catalyzed Oxidative Kinetic Resolution with Ambient Air as the Stoichiometric Oxidation Gas; Angewandte Chemie International Edition; Vol. 43; No. 3; 353-357; 10.1002/anie.200352444

Ashley, Eric R.; Cruz, Ernest G.; et el. (2003) The Total Synthesis of (−)-Lemonomycin; Journal of the American Chemical Society; Vol. 125; No. 49; 15000-15001; 10.1021/ja039223q
Sarpong, Richmond; Su, Julius T.; et el. (2003) The Development of a Facile Tandem Wolff/Cope Rearrangement for the Synthesis of Fused Carbocyclic Skeletons; Journal of the American Chemical Society; Vol. 125; No. 45; 13624-13625; 10.1021/ja037587c
Ferreira, Eric M. and Stoltz, Brian M. (2003) Catalytic C−H Bond Functionalization with Palladium(II): Aerobic Oxidative Annulations of Indoles; Journal of the American Chemical Society; Vol. 125; No. 32; 9578-9579; 10.1021/ja035054y
Trend, Raissa M.; Ramtohul, Yeeman K.; et el. (2003) Palladium-Catalyzed Oxidative Wacker Cyclizations in Nonpolar Organic Solvents with Molecular Oxygen: A Stepping Stone to Asymmetric Aerobic Cyclizations; Angewandte Chemie International Edition; Vol. 42; No. 25; 2892-2895; 10.1002/anie.200351196
Julian, Ryan R.; May, Jeremy A.; et el. (2003) Gas-Phase Synthesis of Charged Copper and Silver Fischer Carbenes from Diazomalonates: Mechanistic and Conformational Considerations in Metal-Mediated Wolff Rearrangements; Journal of the American Chemical Society; Vol. 125; No. 15; 4478-4486; 10.1021/ja028337j
Bagdanoff, Jeffrey T.; Ferreira, Eric M.; et el. (2003) Palladium-Catalyzed Enantioselective Oxidation of Alcohols: A Dramatic Rate Acceleration by Cs_2CO_3/t-BuOH; Organic Letters; Vol. 5; No. 6; 835-837; 10.1021/ol027463p
Julian, Ryan R.; May, Jeremy A.; et el. (2003) Molecular Mousetraps: Gas-Phase Studies of the Covalent Coupling of Noncovalent Complexes Initiated by Reactive Carbenes Formed by Controlled Activation of Diazo Precursors; Angewandte Chemie International Edition; Vol. 42; No. 9; 1012-1015; 10.1002/anie.200390258
Garg, Neil K.; Sarpong, Richmond; et el. (2002) The First Total Synthesis of Dragmacidin D; Journal of the American Chemical Society; Vol. 124; No. 44; 13179-13184; 10.1021/ja027822b
May, Jeremy A. and Stoltz, Brian M. (2002) Non-Carbonyl-Stabilized Metallocarbenoids in Synthesis: The Development of a Tandem Rhodium-Catalyzed Bamford−Stevens/Thermal Aliphatic Claisen Rearrangement Sequence; Journal of the American Chemical Society; Vol. 124; No. 42; 12426-12427; 10.1021/ja028020j
Spessard, Sarah J. and Stoltz, Brian M. (2002) Progress toward the Synthesis of Garsubellin A and Related Phloroglucins: The Direct Diastereoselective Synthesis of the Bicyclo[3.3.1]nonane Core; Organic Letters; Vol. 4; No. 11; 1943-1946; 10.1021/ol025968+
Ferreira, Eric M. and Stoltz, Brian M. (2001) The Palladium-Catalyzed Oxidative Kinetic Resolution of Secondary Alcohols with Molecular Oxygen; Journal of the American Chemical Society; Vol. 123; No. 31; 7725-7726; 10.1021/ja015791z
Fuerst, Douglas E.; Stoltz, Brian M.; et el. (2000) Synthesis of C(3) Benzofuran-Derived Bisaryl Quaternary Centers: Approaches to Diazonamide A; Organic Letters; Vol. 2; No. 22; 3521-3523; 10.1021/ol006578v
Ge, Min; Stoltz, Brian M.; et el. (2000) Mechanistic Insights into the Factors Determining Exo−EndoSelectivity in the Lewis Acid-Catalyzed Diels−Alder Reaction of 1,3-Dienes with 2-Cycloalkenones; Organic Letters; Vol. 2; No. 13; 1927-1929; 10.1021/ol0060026