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"type": "thesis", "metadata_visibility": "show", "creators": { "items": [ { "id": "Felbeck-George-Theodore", "name": { "family": "Felbeck", "given": "George Theodore" }, "show_email": "NO" } ] }, "title": "The Rate of Thermal Diffusion in Mixtures of Carbon Dioxide and Hydrogen", "ispublished": "unpub", "full_text_status": "public", "keywords": "(Chemistry)", "abstract": "
An equation is derived for the time rate\r\nof change of composition of a binary gas mixture\r\nof initially uniform composition by thermal diffusion\r\nin an apparatus consisting of two chambers,\r\none above the other, connected by a straight tube.\r\nThe upper chamber is held at a given constant high\r\ntemperature and the lower chamber at a given constant\r\nlower temperature.
\r\n\r\nUsing the thermal conductivity method of\r\nanalysis the rate of change of composition in\r\nthe lower chamber has been measured for carbon\r\ndioxide-hydrogen mixtures for various compositions,\r\npressures and higher temperatures.
\r\n\r\nFrom the experimental results and the derived\r\nequation, values are determined for the\r\nthermal diffusion coefficient, the ordinary or\r\nconcentration diffusion coefficient and the\r\ntemperature exponent for these coefficients.
\r\n\r\n\r\n ", "date": "1943", "date_type": "degree", "id_number": "CaltechTHESIS:01242017-150443602", "refereed": "FALSE", "official_url": "https://resolver.caltech.edu/CaltechTHESIS:01242017-150443602", "rights": "No commercial reproduction, distribution, display or performance rights in this work are provided.", "collection": "CaltechTHESIS", "reviewer": "Kathy Johnson", "deposited_by": "Benjamin Perez", "deposited_on": "2017-01-25 15:43:09", "doi": "10.7907/1901-1751", "divisions": { "items": [ "div_chem" ] }, "institution": "California Institute of Technology", "thesis_type": "phd", "thesis_advisor": { "items": [ { "id": "Dickinson-R-G", "name": { "family": "Dickinson", "given": "Roscoe Gilkey" }, "role": "advisor" } ] }, "thesis_committee": { "items": [ { "name": { "family": "Unknown", "given": "Unknown" } } ] }, "thesis_degree": "PHD", "thesis_degree_grantor": "California Institute of Technology", "review_status": "approved", "option_major": { "items": [ "chemistry" ] }, "copyright_statement": "Author's Rights Authorization: I hereby certify that, if appropriate, I have obtained a written permission statement from the owner(s) of each third party copyrighted matter to be included in my thesis, dissertation, or project report, allowing distribution as specified below. I certify that the version I submitted here is the same as that approved by my advisory committee.\n\nI hereby grant to California Institute of Technology or its agents the non-exclusive license to archive and make accessible, under the conditions specified under \"Thesis Availability\" in this submission, my thesis, dissertation, or project report in whole or in part in all forms of media, now or hereafter known. I retain all other ownership rights to the copyright of the thesis, dissertation, or project report. I also retain the right to use in future works (such as articles or books) all or part of this thesis, dissertation, or project report.", "resource_type": "thesis", "pub_year": "1943", "author_list": "Felbeck, George Theodore", "advisor_list": "Dickinson, Roscoe Gilkey", "comittee_list": "Unknown, Unknown" }, { "id": "https://thesis.library.caltech.edu/id/eprint/10071", "eprint_id": 10071, "rev_number": 17, "documents": [ { "id": "/id/document/76429", "doc_id": 76429, "rev_number": 2, "files": [ { "id": "/id/file/216492", "fileid": 216492, "datasetid": "document", "objectid": 76429, "filename": "Lyons_EH_1933.pdf", "mime_type": "application/pdf", "hash": "3c64bfbf11b18613274e5cd68c30bb4c", "hash_type": "MD5", "filesize": 4550463, "mtime": "2017-02-28 17:05:39", "url": "/10071/1/Lyons_EH_1933.pdf" } ], "eprint_id": 10071, "pos": 1, "placement": 1, "mime_type": "application/pdf", "format": "application/pdf", "language": "en", "security": "public", "license": "other", "main": 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"media_sample_start": "0", "media_sample_stop": "0", "content": "final" }, { "id": "/id/document/133370", "doc_id": 133370, "rev_number": 1, "files": [ { "id": "/id/file/378815", "fileid": 378815, "datasetid": "document", "objectid": 133370, "filename": "indexcodes.txt", "mime_type": "text/plain", "hash": "7107d1e046e0bb27395a31dacb5691d8", "hash_type": "MD5", "filesize": 6806, "mtime": "2021-06-24 19:52:12", "url": "/10071/8/indexcodes.txt" } ], "eprint_id": 10071, "pos": 8, "placement": 8, "mime_type": "text/plain", "format": "other", "format_desc": "Generate index codes conversion from application/pdf to indexcodes", "language": "en", "security": "public", "license": "other", "main": "indexcodes.txt", "media_duration": "0", "media_aspect_ratio": "0", "media_sample_start": "0", "media_sample_stop": "0", "relation": { "items": [ { "type": "http://eprints.org/relation/isVersionOf", "uri": "/id/document/76429" }, { "type": "http://eprints.org/relation/isVolatileVersionOf", "uri": "/id/document/76429" }, { "type": "http://eprints.org/relation/isIndexCodesVersionOf", "uri": "/id/document/76429" } ] } } ], "eprint_status": "archive", "userid": 87, "dir": "disk0/00/01/00/71", "datestamp": "2017-02-28 18:12:52", "lastmod": "2023-08-16 23:09:00", "status_changed": "2017-02-28 18:12:52", "type": "thesis", "metadata_visibility": "show", "creators": { "items": [ { "id": "Lyons-Ernest-Herbert-Jr.", "name": { "family": "Lyons", "given": "Ernest Herbert, Jr." }, "show_email": "NO" } ] }, "title": "The Photo-Oxidation of Carbon Tetrachloride", "ispublished": "unpub", "full_text_status": "public", "keywords": "Chemistry", "abstract": "1. It has been shown that carbon tetrachloride\r\nis not decomposed by light of wavelength 2537\r\n\u00e5ngstroms.
\r\n\r\n2. It has been shown that light of wavelength\r\n2537 \u00e5ngstroms produces an oxidation of carbon\r\ntetrachloride according to the reaction
\r\n\r\nCCl4 + \u00bdO2 \u2192 COCl2 + Cl2\r\n\r\nIt has been shown that one molecule of carbon\r\ntetrachloride is decomposed per quantum of light\r\nabsorbed. A possible mechanism for this reaction\r\nhas been given.
\r\n\r\n3. The difficulty of purifying carbon\r\ntetrachloride for photochemical work has been\r\npointed out.
\r\n\r\n4. Evidence suggesting a photochemical \r\nhydrolysis of carbon tetrachloride has been\r\ngiven.
\r\n\r\n", "date": "1933", "date_type": "degree", "id_number": "CaltechTHESIS:02282017-090332720", "refereed": "FALSE", "official_url": "https://resolver.caltech.edu/CaltechTHESIS:02282017-090332720", "rights": "No commercial reproduction, distribution, display or performance rights in this work are provided.", "collection": "CaltechTHESIS", "reviewer": "Tony Diaz", "deposited_by": "Benjamin Perez", "deposited_on": "2017-02-28 18:12:52", "doi": "10.7907/ZC4V-5J32", "divisions": { "items": [ "div_chem" ] }, "institution": "California Institute of Technology", "thesis_type": "masters", "thesis_advisor": { "items": [ { "id": "Dickinson-R-G", "name": { "family": "Dickinson", "given": "Roscoe Gilkey" }, "role": "advisor" } ] }, "thesis_committee": { "items": [ { "name": { "family": "Unknown", "given": "Unknown" } } ] }, "thesis_degree": "MS", "thesis_degree_grantor": "California Institute of Technology", "thesis_defense_date": "1933-01-01", "review_status": "approved", "option_major": { "items": [ "chemistry" ] }, "copyright_statement": "Author's Rights Authorization: I hereby certify that, if appropriate, I have obtained a written permission statement from the owner(s) of each third party copyrighted matter to be included in my thesis, dissertation, or project report, allowing distribution as specified below. I certify that the version I submitted here is the same as that approved by my advisory committee.\n\nI hereby grant to California Institute of Technology or its agents the non-exclusive license to archive and make accessible, under the conditions specified under \"Thesis Availability\" in this submission, my thesis, dissertation, or project report in whole or in part in all forms of media, now or hereafter known. I retain all other ownership rights to the copyright of the thesis, dissertation, or project report. 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Tri-Iodide ; Cesium Didromo-Iodide", "note": "Thesis is a compilation of published articles on crystalline structures.\r\n\r\nThe Nobel Prize in Chemistry 1954 was awarded to Linus Carl Pauling \"for his research into the nature of the chemical bond and its application to the elucidation of the structure of complex substances.\"\r\n\r\nThe Nobel Peace Prize 1962 was awarded to Linus Carl Pauling.\"", "abstract": "No Abstract.", "date": "1925", "date_type": "degree", "id_number": "CaltechETD:etd-05142003-141307", "refereed": "FALSE", "official_url": "https://resolver.caltech.edu/CaltechETD:etd-05142003-141307", "related_url": { "items": [ { "description": "Article 1: The Crystal Structure of Molybdenite", "type": "doi", "url": "https://doi.org/10.1021/ja01659a020" }, { "description": "Article 2: The Crystal Structure of Magnesium Stannide", "type": "doi", "url": "https://doi.org/10.1021/ja01665a001" }, { "description": "Article 3: The Crystal Structure of Uranyl Nitrate Hexahydrate", 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The Nobel Peace Prize, 1962.", "review_status": "approved", "option_major": { "items": [ "chemistry" ] }, "copyright_statement": "I hereby certify that, if appropriate, I have obtained a written permission statement from the owner(s) of each third party copyrighted matter to be included in my thesis, dissertation, or project report, allowing distribution as specified below. I certify that the version I submitted is the same as that approved by my advisory committee.\n\nI hereby grant to California Institute of Technology or its agents the non-exclusive\nlicense to archive and make accessible, under the conditions specified below,\nmy thesis, dissertation, or project report in whole or in part in all forms of media, now or hereafter known. I retain all other ownership rights to the copyright of the thesis, dissertation or project report. 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