[ { "id": "https://authors.library.caltech.eduhttps://authors.library.caltech.edu/records/r8snw-2t308", "eprint_id": 32127, "eprint_status": "archive", "datestamp": "2023-08-19 19:38:39", "lastmod": "2023-10-17 22:59:14", "type": "article", "metadata_visibility": "show", "creators": { "items": [ { "id": "Collins-T-J", "name": { "family": "Collins", "given": "Terrence J." } }, { "id": "Shigeko-O", "name": { "family": "Ozaki", "given": "Shigeko" } }, { "id": "Richmond-T-G", "name": { "family": "Richmond", "given": "Thomas G." } } ] }, "title": "Catalytic Oxidation of Styrene in the Presence of Square Planar Cobalt(iii) Complexes of Polyanionic Chelating Ligands", "ispublished": "pub", "full_text_status": "public", "note": "\u00a9 1987 Royal Society of Chemistry.\nReceived 13th January 1987; Com. 040.\nWe thank the Rohm and Haas Co., the Atlantic Richfield\nCorporation of America, and the National Science Foundation\n(Grant CHE-84-06198) for support of this work. S.O.\nthanks the Japanese Government for support for sabbatical\nleave from the University of Osaka. T.J.C. is a Dreyfus\nJ. CHEM. SOC., CHEM. COMMUN., 1987\nTeacher-Scholar (1986-1990) and an Alfred P. Sloan\nResearch Fellow (19861988).\nThe Chemical Laboratories, California Institute of Technology, Pasadena, CA 91 125, U.S.A. Contribution No. 7354.\n\n
Published - COLjcscc87.pdf
", "abstract": "Styrene has been catalytically oxidised in the presence of iodosoarenes and square planar cobalt(iii) complexes of\npolyanionic chelating (PAC) ligands; possible intermediates in these oxygen atom transfer reactions include cobalt(v)-oxo complexes.", "date": "1987-06-01", "date_type": "published", "publication": "Journal of the Chemical Society. Chemical Communications", "number": "11", "publisher": "Royal Society of Chemistry", "pagerange": "803-804", "id_number": "CaltechAUTHORS:20120627-090401083", "issn": "0022-4936", "official_url": "https://resolver.caltech.edu/CaltechAUTHORS:20120627-090401083", "rights": "No commercial reproduction, distribution, display or performance rights in this work are provided.", "funders": { "items": [ { "agency": "Rohm and Haas Company" }, { "agency": "Atlantic Richfield Corporation of America" }, { "agency": "NSF", "grant_number": "CHE-84-06198" } ] }, "other_numbering_system": { "items": [ { "id": "7354", "name": "Caltech Chemical Laboratories" } ] }, "doi": "10.1039/C39870000803", "primary_object": { "basename": "COLjcscc87.pdf", "url": "https://authors.library.caltech.edu/records/r8snw-2t308/files/COLjcscc87.pdf" }, "resource_type": "article", "pub_year": "1987", "author_list": "Collins, Terrence J.; Ozaki, Shigeko; et el." }, { "id": "https://authors.library.caltech.eduhttps://authors.library.caltech.edu/records/96v1f-wr608", "eprint_id": 32387, "eprint_status": "archive", "datestamp": "2023-08-19 15:32:45", "lastmod": "2023-10-17 23:23:04", "type": "article", "metadata_visibility": "show", "creators": { "items": [ { "id": "Collins-T-J", "name": { "family": "Collins", "given": "Terrence J." } }, { "id": "Santarsiero-B-D", "name": { "family": "Santarsiero", "given": "Bernard D." } }, { "id": "Spies-G-H", "name": { "family": "Spies", "given": "George H." } } ] }, "title": "Complexation of Secondary Amides to Chromium(III): the X-Ray\n Structure of a Molecule with Two Modes of Monodentate Organic Amide Co-ordination", "ispublished": "pub", "full_text_status": "public", "note": "\u00a9 1983 Royal Society of Chemistry.\n\nReceived, 23rd February 1983; Com. 252.\n\nWe thank the Donors of the Petroleum Research Fund,\nadministered by the American Chemical Society, the Research\nCorporation, and the National Science Foundation for\nsupport of this work. B.D.S. acknowledges support from the\nCalifornia Institute of Technology as a Myron A. Bantrell\nFellow in Chemistry, 1981-1983.\n\nPublished - COLjcscc83.pdf
", "abstract": "The X-ray crystal structure of the dimer [Cr{H(chba-Et)}(py)_2]_(2)\u00b72py [H_(4)(chba-Et)= 1,2-bis(3,5-dichloro-2-hydroxybenzamido) ethane, py = pyridine] establishes, for the first time, the existence of N-co-ordination of an organic amide to Cr^III, the N-atom and carbonyl O-atom of two separate amide groups being co-ordinated to each Cr^III centre [Cr\u2013N 2.030(6) and Cr\u2013O 1.976(5)\u00c5]; the potentially tetra-anionic chelating ligand leads to a variety of co-ordination modes.", "date": "1983", "date_type": "published", "publication": "Journal of the Chemical Society. Chemical Communications", "volume": "1983", "number": "12", "publisher": "Royal Society of Chemistry", "pagerange": "681-682", "id_number": "CaltechAUTHORS:20120712-112655275", "issn": "0022-4936", "official_url": "https://resolver.caltech.edu/CaltechAUTHORS:20120712-112655275", "rights": "No commercial reproduction, distribution, display or performance rights in this work are provided.", "funders": { "items": [ { "agency": "American Chemical Society Petroleum Research Fund" }, { "agency": "Research Corporation" }, { "agency": "NSF" }, { "agency": "Caltech Myron A. Bantrell Research Fellowship" } ] }, "doi": "10.1039/C39830000681", "primary_object": { "basename": "COLjcscc83.pdf", "url": "https://authors.library.caltech.edu/records/96v1f-wr608/files/COLjcscc83.pdf" }, "resource_type": "article", "pub_year": "1983", "author_list": "Collins, Terrence J.; Santarsiero, Bernard D.; et el." } ]