[
    {
        "id": "authors:q0zsn-en450",
        "collection": "authors",
        "collection_id": "q0zsn-en450",
        "cite_using_url": "https://resolver.caltech.edu/CaltechAUTHORS:20110826-140851864",
        "type": "book_section",
        "title": "The Role of Higher Oxidation State Species in Platinum-Mediated C\u2013H Bond Activation and Functionalization",
        "book_title": "Higher Oxidation State Organopalladium and Platinum Chemistry",
        "author": [
            {
                "family_name": "Labinger",
                "given_name": "Jay A.",
                "orcid": "0000-0002-1942-9232",
                "clpid": "Labinger-J-A"
            },
            {
                "family_name": "Bercaw",
                "given_name": "John E.",
                "clpid": "Bercaw-J-E"
            }
        ],
        "contributor": [
            {
                "family_name": "Canty",
                "given_name": "Allan J.",
                "clpid": "Canty-A-J"
            },
            {
                "family_name": "Bercaw",
                "given_name": "John E.",
                "clpid": "Bercaw-J-E"
            }
        ],
        "abstract": "The Shilov system, a mixture of di- and tetravalent chloroplatinate salts in aqueous solution, provided the first indication of the potential of organotransition\nmetal complexes for activating and functionalizing alkanes under mild conditions; the participation of higher-valent species plays a crucial role. In this chapter, we discuss the experimental and computational studies that have led to detailed mechanistic understanding of C\u2013H activation and functionalization by both the original Shilov system and the many subsequent modifications that have been developed, and assess the prospects for practical, selective catalytic oxidation of alkanes using this chemistry.",
        "doi": "10.1007/978-3-642-17429-2_2",
        "isbn": "978-3-642-17428-5",
        "publisher": "Springer",
        "place_of_publication": "Berlin",
        "publication_date": "2011",
        "pages": "29-59"
    }
]