Bercaw, John E.

• Bercaw, John; Berke, Heinz; et el. (2019) Hans Herbert Brintzinger (1935–2019); Angewandte Chemie International Edition; Vol. 58; No. 34; 11569; 10.1002/anie.201907530
• Panchenko, Valentina N.; Babushkin, Dmitrii E.; et el. (2019) Catalyst Speciation During ansa-Zirconocene-Catalyzed Polymerization of 1-Hexene Studied by UV-vis Spectroscopy—Formation and Partial Re-Activation of Zr-Allyl Intermediates; Polymers; Vol. 11; No. 6; Art. No. 936; PMCID PMC6630943; 10.3390/polym11060936
• Bercaw, John E. and Labinger, Jay A. (2019) Malcolm L. H. Green: Reminiscences and Appreciations; Inorganica Chimica Acta; Vol. 487; 405-408; 10.1016/j.ica.2018.12.044
• Bercaw, John (2018) Mechanistic studies inspired by Jack
• Bercaw, John E. (2018) Jack Halpern (1925–2018): Pioneer of homogeneous catalysis; Proceedings of the National Academy of Sciences of the United States of America; Vol. 115; No. 20; 5049-5050; PMCID PMC5960341; 10.1073/pnas.1806116115
• Bercaw, John E. (2018) Olefin trimerization and ethylene tandem conversion to linear low density polyethylene
• Steelman, D. Keith; Aluthge, Dinesh C.; et el. (2017) Mechanistic Studies on Selective Trimerization of Linear α-Olefins over a Supported Titanium Catalyst; ACS Catalysis; Vol. 7; No. 8; 4922-4926; 10.1021/acscatal.7b00256
• Bercaw, John E. (2017) Award Address (Gabor A. Somorjai Award for Creative Research in Catalysis sponsored by the Gabor A. & Judith K. Somorjai Endowment Fund). Mechanistic studies of 1-alkene trimerization and polymerization with organotransition metal catalysts
• Aluthge, Dinesh; Sattler, Aaron; et el. (2017) Co-supported tandem catalysts for production of linear low density polyethylene
• Bercaw, John E.; Aluthge, Dinesh; et el. (2017) Olefin trimerization with titanium catalysts: MAO/silica-supported variants display higher productivities
• Aluthge, Dinesh C.; Sattler, Aaron; et el. (2016) Cosupported Tandem Catalysts for Production of Linear Low-Density Polyethylene from an Ethylene-Only Feed; ACS Catalysis; Vol. 6; No. 10; 6581-6584; 10.1021/acscatal.6b02370
• Bercaw, John; Do, Loi; et el. (2016) Ethylene and alpha olefin trimerization and tandem trimerization/polymerization of ethylene
• Bercaw, John E.; Labinger, Jay A.; et el. (2016) Homogeneous Ta/Ir tandem catalytic alkane/alkene coupling
• Labinger, Jay; Bercaw, John; et el. (2016) Oligo or poly? A mechanistic interpretation of a switchable catalyst
• Sattler, Aaron; Aluthge, Dinesh C.; et el. (2016) Enhanced Productivity of a Supported Olefin Trimerization Catalyst; ACS Catalysis; Vol. 6; No. 1; 19-22; 10.1021/acscatal.5b02604
• Mindiola, Daniel J.; Smith, Milton R.; et el. (2015) Gregory L. Hillhouse: His Life, His Art, His Science, and the Rise of “Double Nickel”; Organometallics; Vol. 34; No. 19; 4633-4636; 10.1021/acs.organomet.5b00527
• Despagnet-Ayoub, Emmanuelle; Takase, Michael K.; et el. (2015) Mechanistic Insights on the Controlled Switch from Oligomerization to Polymerization of 1-Hexene Catalyzed by an NHC-Zirconium Complex; Organometallics; Vol. 34; No. 19; 4707-4716; 10.1021/acs.organomet.5b00472
• Labinger, Jay A. and Bercaw, John E. (2015) Mechanistic studies on the Shilov system: A retrospective; Journal of Organometallic Chemistry; Vol. 793; 47-53; 10.1016/j.jorganchem.2015.01.027
• Despagnet-Ayoub, Emmanuelle; Takase, Michael K.; et el. (2015) Reversible 1,2-Alkyl Migration to Carbene and Ammonia Activation in an N-Heterocyclic Carbene–Zirconium Complex; Journal of the American Chemical Society; Vol. 137; No. 33; 10500-10503; 10.1021/jacs.5b06695
• Bercaw, John E.; Labinger, Jay A.; et el. (2015) Linear low density polyethylenes using well defined tandem catalysts and a single monomer feed
• Bercaw, John E.; Leitch, David C.; et el. (2015) Tandem catalytic processes for light alkane upgrading and ethylene polymerization
• Labinger, Jay A.; Leitch, David C.; et el. (2015) Upgrading Light Hydrocarbons: A Tandem Catalytic System for Alkane/Alkene Coupling; Topics in Catalysis; Vol. 58; No. 7-9; 494-501; 10.1007/s11244-015-0380-2
• Winston, Matthew S. and Bercaw, John E. (2014) Palladium(II) Complexes Supported by a Bidentate Bis(secondary)phosphine Linked by Pyridine; Inorganica Chimica Acta; Vol. 422; 30-35; 10.1016/j.ica.2014.08.002
• Teets, Thomas S.; Labinger, Jay A.; et el. (2014) Guanidine-Functionalized Rhenium Cyclopentadienyl Carbonyl Complexes: Synthesis and Cooperative Activation of H–H and O–H Bonds; Organometallics; Vol. 33; No. 15; 4107-4117; 10.1021/om500650b
• Despagnet-Ayoub, Emmanuelle; Labinger, Jay A.; et el. (2014) N-Heterocyclic carbene group 4 transition metal catalysts: Synthesis and reactivity towards oligomerization/polymerization of α-olefins; Abstracts of Papers of the American Chemical Society; Vol. 248; 527-INOR
• Sattler, Aaron; Winkler, Jay R.; et el. (2014) Upgrading light olefins by trimerization catalysis
• Sattler, Aaron; VanderVelde, David G.; et el. (2014) Lewis Acid Promoted Titanium Alkylidene Formation: Off-Cycle Intermediates Relevant to Olefin Trimerization Catalysis; Journal of the American Chemical Society; Vol. 136; No. 30; 10790-10800; 10.1021/ja5055687
• Leitch, David C.; Labinger, Jay A.; et el. (2014) Scope and Mechanism of Homogeneous Tantalum/Iridium Tandem Catalytic Alkane/Alkene Upgrading using Sacrificial Hydrogen Acceptors; Organometallics; Vol. 33; No. 13; 3353-3365; 10.1021/om500231t
• Klet, Rachel C.; Theriault, Curt N.; et el. (2014) Investigations into Asymmetric Post-Metallocene Group 4 Complexes for the Synthesis of Highly Regioirregular Polypropylene; Macromolecules; Vol. 47; No. 10; 3317-3324; 10.1021/ma500453t
• Min, Endy Y.-J; Bercaw, John E.; et el. (2014) Bis(η^5-Pentamethylcyclopentadienyl) Complexes of Niobium and Tantalum; ISBN 9781118744871; 52-57; 10.1002/9781118744994.ch11
• Min, Endy Y.-J.; Bercaw, John E.; et el. (2014) Bis(η^5-Pentamethylcyclopentadienyl) Complexes of Titanium, Zirconium, and Hafnium; ISBN 9781118744871; 47-51; 10.1002/9781118744994.ch10
• Shin, Jun Ho; Churchill, David G.; et el. (2014) Bis(η⁵-Pentamethylcyclopentadienyl) Complexes of Molybdenum; ISBN 9781118744871; 58-62; 10.1002/9781118744994.ch12
• Min, Endy Y.-J; Bercaw, John E.; et el. (2014) Bis(η⁵-Pentamethylcyclopentadienyl) Complexes of Scandium; ISBN 9781118744871; 42-47; 10.1002/9781118744994.ch09
• Labinger, Jay A.; Leitch, David C.; et el. (2014) Upgrading light hydrocarbons: A tandem catalytic system for alkane/alkene coupling
• Sattler, Aaron; Labinger, Jay A.; et el. (2013) Highly Selective Olefin Trimerization Catalysis by a Borane-Activated Titanium Trimethyl Complex; Organometallics; Vol. 32; No. 23; 6899-6902; 10.1021/om401098m
• Do, Loi H.; Labinger, Jay A.; et el. (2013) Spectral Studies of a Cr(PNP)−MAO System for Selective Ethylene Trimerization Catalysis: Searching for the Active Species; ACS Catalysis; Vol. 3; No. 11; 2582-2585; PMCID PMC3855459; 10.1021/cs400778a
• Teets, Thomas S.; Labinger, Jay A.; et el. (2013) A Thermodynamic Analysis of Rhenium(I)−Formyl C−H Bond Formation via Base-Assisted Heterolytic H_2 Cleavage in the Secondary Coordination Sphere; Organometallics; Vol. 32; No. 19; 5530-5545; 10.1021/om400810v
• Despagnet-Ayoub, Emmanuelle; Henling, Lawrence M.; et el. (2013) Addition of a phosphine ligand switches an N-heterocyclic carbene-zirconium catalyst from oligomerization to polymerization of 1-hexene; Dalton Transactions; Vol. 42; No. 44; 15544-15547; 10.1039/C3DT52342J
• Kamal, Muhammad Shahzad; Bahuleyan, Bijal Kottukkal; et el. (2013) Crystallization analysis fractionation of poly(ethylene-co-styrene) produced by metallocene catalysts; Polymer Bulletin; Vol. 70; No. 9; 2645-2656; 10.1007/s00289-013-0980-6
• Appel, Aaron M.; Bercaw, John E.; et el. (2013) Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO_2 Fixation; Chemical Reviews; Vol. 113; No. 8; 6621-6658; PMCID PMC3895110; 10.1021/cr300463y
• Lenton, Taylor N.; Bercaw, John E.; et el. (2013) Formation of Trivalent Zirconocene Complexes from ansa-Zirconocene-Based Olefin-Polymerization Precatalysts: An EPR- and NMR-Spectroscopic Study; Journal of the American Chemical Society; Vol. 135; No. 29; 10710-10719; 10.1021/ja403170u
• Leitch, David C.; Lam, Yan Choi; et el. (2013) Upgrading Light Hydrocarbons via Tandem Catalysis: A Dual Homogeneous Ta/Ir System for Alkane/Alkene Coupling; Journal of the American Chemical Society; Vol. 135; No. 28; 10302-10305; 10.1021/ja405191a
• Tonks, Ian A.; Meier, Josef C.; et el. (2013) Alkyne Hydroamination and Trimerization with Titanium Bis(phenolate)pyridine Complexes: Evidence for Low-Valent Titanium Intermediates and Synthesis of an Ethylene Adduct of Titanium(II); Organometallics; Vol. 32; No. 12; 3451-3457; 10.1021/om400080g
• Ahmed, Tonia S.; Tonks, Ian A.; et el. (2013) Kinetics and Mechanism of Indene C–H Bond Activation by [(COD)Ir(μ_2-OH)]_2; Organometallics; Vol. 32; No. 11; 3322-3326; 10.1021/om400230j
• Despagnet-Ayoub, Emmanuelle; Henling, Lawrence M.; et el. (2013) Group 4 Transition-Metal Complexes of an Aniline–Carbene–Phenol Ligand; Organometallics; Vol. 32; No. 10; 2934-2938; 10.1021/om4001567
• Bercaw, John E.; Labinger, Jay A.; et el. (2013) New precatalysts for olefin polymerization having LX2 pincer ligands
• Bercaw, John E.; Labinger, Jay A.; et el. (2013) Reductive coupling of carbon monoxide in carbonyl complexes with pendant Lewis acids or bases
• Despagnet-Ayoub, Emmanuelle; Miqueu, Karinne; et el. (2013) Unexpected rearrangements in the synthesis of an unsymmetrical tridentate dianionic N-heterocyclic carbene; Chemical Science; Vol. 4; No. 5; 2117-2121; 10.1039/c3sc22171g
• Lenton, Taylor N.; VanderVelde, David G.; et el. (2012) Synthesis of a Bis(thiophenolate)pyridine Ligand and Its Titanium, Zirconium, and Tantalum Complexes; Organometallics; Vol. 31; No. 21; 7492-7499; 10.1021/om300789h
• Winston, Matthew S.; Oblad, Paul F.; et el. (2012) Activator-Free Olefin Oligomerization and Isomerization Reactions Catalyzed by an Air- and Water-Tolerant Wacker Oxidation Intermediate; Angewandte Chemie International Edition; Vol. 51; No. 39; 9822-9824; 10.1002/anie.201206215
• Klet, Rachel C.; Labinger, Jay A.; et el. (2012) Diverse C−C Bond-Forming Reactions of Bis(carbene)platinum(II) Complexes; Organometallics; Vol. 31; No. 18; 6652-6657; 10.1021/om300733h
• Hazari, Amaruka; Labinger, Jay A.; et el. (2012) A Versatile Ligand Platform that Supports Lewis Acid Promoted Migratory Insertion; Angewandte Chemie International Edition; Vol. 51; No. 33; 8268-8271; 10.1002/anie.201203264
• Do, Loi H.; Labinger, Jay A.; et el. (2012) Mechanistic Studies of Ethylene and α-Olefin Co-Oligomerization Catalyzed by Chromium−PNP Complexes; Organometallics; Vol. 31; No. 14; 5143-5149; 10.1021/om300492r
• Klet, Rachel C.; VanderVelde, David G.; et el. (2012) Highly regioirregular polypropylene from asymmetric group 4 anilide(pyridine)phenoxide complexes; Chemical Communications; Vol. 48; No. 53; 6657-6659; 10.1039/C2CC32806B
• Atiqullah, M.; Winston, M. S.; et el. (2012) Effects of a vanadium post-metallocene catalyst-induced polymer backbone inhomogeneity on UV oxidative degradation of the resulting polyethylene film; Polymer Degradation and Stability; Vol. 97; No. 7; 1164-1177; 10.1016/j.polymdegradstab.2012.03.042
• Tonks, Ian A.; Durrell, Alec C.; et el. (2012) Groups 5 and 6 Terminal Hydrazido(2−) Complexes: N_β Substituent Effects on Ligand-to-Metal Charge-Transfer Energies and Oxidation States; Journal of the American Chemical Society; Vol. 134; No. 17; 7301-7304; 10.1021/ja302275j
• Tonks, Ian A.; Tofan, Daniel; et el. (2012) Zirconium and Titanium Propylene Polymerization Precatalysts Supported by a Fluxional C_2-Symmetric Bis(anilide)pyridine Ligand; Organometallics; Vol. 31; No. 5; 1965-1974; 10.1021/om201262h
• Fu, Ross; Bercaw, John E.; et el. (2011) Intra- and Intermolecular C−H Activation by Bis(phenolate)pyridineiridium(III) Complexes; Organometallics; Vol. 30; No. 24; 6751-6765; 10.1021/om201069k
• Scott, Valerie J.; Labinger, Jay A.; et el. (2011) Large Kinetic Isotope Effects for the Protonolysis of Metal-Methyl Complexes Are Not Reliable Mechanistic Indicators; Organometallics; Vol. 30; No. 16; 4374-4378; 10.1021/om200432b
• Miller, Alexander J. M.; Labinger, Jay A.; et el. (2011) Trialkylborane-Assisted CO_2 Reduction by Late Transition Metal Hydrides; Organometallics; Vol. 30; No. 16; 4308-4314; 10.1021/om200364w
• West, Nathan M.; Labinger, Jay A.; et el. (2011) Heterobimetallic Complexes of Rhenium and Zinc: Potential Catalysts for Homogeneous Syngas Conversion; Organometallics; Vol. 30; No. 10; 2690-2700; 10.1021/om200051u
• West, Nathan M.; Miller, Alexander J. M.; et el. (2011) Homogeneous syngas conversion; Coordination Chemistry Reviews; Vol. 255; No. 7-8; 881-898; 10.1016/j.ccr.2010.08.019
• Baldwin, Steven M.; Bercaw, John E.; et el. (2011) Cationic Alkylaluminum-Complexed Zirconocene Hydrides: NMR-Spectroscopic Identification, Crystallographic Structure Determination, and Interconversion with Other Zirconocene Cations; Journal of the American Chemical Society; Vol. 133; No. 6; 1805-1813; 10.1021/ja1050428
• Labinger, Jay A. and Bercaw, John E. (2011) The Role of Higher Oxidation State Species in Platinum-Mediated C–H Bond Activation and Functionalization; ISBN 978-3-642-17428-5; 29-59; 10.1007/978-3-642-17429-2_2
• Winston, Matthew S. and Bercaw, John E. (2010) A Novel Bis(phosphido)pyridine [PNP]^(2−) Pincer Ligand and Its Potassium and Bis(dimethylamido)zirconium(IV) Complexes; Organometallics; Vol. 29; No. 23; 6408-6416; 10.1021/om100775g
• Golisz, Suzanne R.; Labinger, Jay A.; et el. (2010) Intramolecular C−H Activation of a Bisphenolate(benzene)-Ligated Titanium Dibenzyl Complex. Competing Pathways Involving α-Hydrogen Abstraction and σ-Bond Metathesis; Organometallics; Vol. 29; No. 21; 5026-5032; 10.1021/om100253u
• Miller, Alexander J. M.; Labinger, Jay A.; et el. (2010) Homogeneous CO Hydrogenation: Ligand Effects on the Lewis Acid-Assisted Reductive Coupling of Carbon Monoxide; Organometallics; Vol. 29; No. 20; 4499-4516; 10.1021/om100638d
• Baldwin, Steven M.; Bercaw, John E.; et el. (2010) Cationic Alkylaluminum-Complexed Zirconocene Hydrides as Participants in Olefin Polymerization Catalysis; Journal of the American Chemical Society; Vol. 132; No. 40; 13969-13971; 10.1021/ja105040r
• Bercaw, John E.; Chen, George S.; et el. (2010) Protonolysis of Platinum(II) and Palladium(II) Methyl Complexes: A Combined Experimental and Theoretical Investigation; Organometallics; Vol. 29; No. 19; 4354-4359; 10.1021/om100655w
• Scott, Valerie J.; Labinger, Jay A.; et el. (2010) Mechanism of Reductive Elimination of Methyl Iodide from a Novel Gold(III)−Monomethyl Complex; Organometallics; Vol. 29; No. 18; 4090-4096; 10.1021/om1006566
• Tonks, Ian A. and Bercaw, John E. (2010) (dme)MCl_3(NNPh_2) (dme= dimethoxyethane; M= Nb, Ta): A Versatile Synthon for [Ta═NNPh_2] Hydrazido(2-) Complexes; Inorganic Chemistry; Vol. 49; No. 10; 4648-4656; 10.1021/ic1004193
• Fulmer, Gregory R.; Miller, Alexander J. M.; et el. (2010) NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist; Organometallics; Vol. 29; No. 9; 2176-2179; 10.1021/om100106e
• Wilson, Aaron D.; Miller, Alexander J. M.; et el. (2010) Thermodynamic Studies of [H_(2)Rh(diphosphine)_2]^+ and [HRh(diphosphine)(2)(CH(3)CN)]^(2+) Complexes in Acetonitrile; Inorganic Chemistry; Vol. 49; No. 8; 3918-3926; 10.1021/ic100117y
• Miller, Alexander J. M.; Labinger, Jay A.; et el. (2010) Homogeneous CO Hydrogenation: Dihydrogen Activation Involves a Frustrated Lewis Pair Instead of a Platinum Complex; Journal of the American Chemical Society; Vol. 132; No. 10; 3301-3303; 10.1021/ja100574n
• Oblad, Paul F.; Bercaw, John E.; et el. (2010) Oxidation of Organometallic Platinum and Palladium Complexes Obtained from C−H Activation; Organometallics; Vol. 29; No. 4; 789-794; 10.1021/om900678z
• Bercaw, John E.; Durrell, Alec C.; et el. (2010) Electronic Structures of Pd^(II) Dimers; Inorganic Chemistry; Vol. 49; No. 4; 1801-1810; 10.1021/ic902189g
• Weinberg, David R.; Hazari, Nilay; et el. (2010) Iridium(I) and Iridium(III) Complexes Supported by a Diphenolate Imidazolyl-Carbene Ligand; Organometallics; Vol. 29; No. 1; 89-100; 10.1021/om900803r
• Miller, Alexander J. M. and Bercaw, John E. (2010) Dehydrogenation of amine–boranes with a frustrated Lewis pair; Chemical Communications; Vol. 46; No. 10; 1709-1711; 10.1039/b925659h
• Golisz, Suzanne R. and Bercaw, John E. (2009) Synthesis of Early Transition Metal Bisphenolate Complexes and Their Use as Olefin Polymerization Catalysts; Macromolecules; Vol. 42; No. 22; 8751-8762; 10.1021/ma901659q
• Golisz, Suzanne R.; Hazari, Nilay; et el. (2009) Activation of the C−N Bond in Nitromethane by Palladium α-Diimine Complexes; Journal of Organic Chemistry; Vol. 74; No. 21; 8441-8443; 10.1021/jo901635g
• Elowe, Paul R.; West, Nathan M.; et el. (2009) Transformations of Group 7 Carbonyl Complexes: Possible Intermediates in a Homogeneous Syngas Conversion Scheme; Organometallics; Vol. 28; No. 21; 6218-6227; 10.1021/om900804j
• Bercaw, John E.; Hazari, Nilay; et el. (2009) Activation of a C−H Bond in Indene by [(COD)Rh(μ_2-OH)]_2; Organometallics; Vol. 28; No. 18; 5489-5492; 10.1021/om9004498
• Bercaw, John E.; Day, Michael W.; et el. (2009) Robotic Lepidoptery: Structural Characterization of (mostly) Unexpected Palladium Complexes Obtained from High-Throughput Catalyst Screening; Organometallics; Vol. 28; No. 17; 5017-5024; 10.1021/om900240a
• Chen, George S.; Labinger, Jay A.; et el. (2009) Selective Oxidation of sp^3 C-H Bonds in Water Catalyzed by a Glycinate-Platinum(II) Complex; Organometallics; Vol. 28; No. 17; 4899-4901; 10.1021/om900267w
• Lin, Bo-Lin; Bhattacharyya, Koyel X.; et el. (2009) Competitive Benzene C−H Bond Activation versus Olefin Insertion in a (Monomethyl)palladium(II) β-Diketiminate Complex; Organometallics; Vol. 28; No. 15; 4400-4405; 10.1021/om900171d
• Scott, Valerie J.; Henling, Lawrence M.; et el. (2009) Competitive Activation of a Methyl C−H Bond of Dimethylformamide at an Iridium Center; Organometallics; Vol. 28; No. 14; 4229-4230; 10.1021/om9002413
• Tonks, Ian A.; Henling, Larry M.; et el. (2009) Amine, Amido, and Imido Complexes of Tantalum Supported by a Pyridine-Linked Bis(phenolate) Pincer Ligand: Ta−N π-Bonding Influences Pincer Ligand Geometry; Inorganic Chemistry; Vol. 48; No. 12; 5096-5105; 10.1021/ic802234x
• Weintrob, Edward C.; Tofan, Daniel; et el. (2009) Synthesis and Characterization of Iron Derivatives Having a Pyridine-Linked Bis(anilide) Pincer Ligand; Inorganic Chemistry; Vol. 48; No. 8; 3808-3813; 10.1021/ic900083s
• Lin, Bo-Lin; Labinger, Jay A.; et el. (2009) Mechanistic investigations of bipyrimidine-promoted palladium-catalyzed allylic acetoxylation of olefins; Canadian Journal of Chemistry; Vol. 87; No. 1; 264-271; 10.1139/V08-133
• Bercaw, John E.; Hazari, Nilay; et el. (2008) C-H Bond Activation by [{(Diimine)Pd(μ-OH)}2]2+ Dimers: Mechanism-Guided Catalytic Improvement; Angewandte Chemie International Edition; Vol. 47; No. 51; 9941-9943; 10.1002/anie.200804455
• Agapie, Theodor; Day, Michael W.; et el. (2008) Synthesis and reactivity of tantalum complexes supported by bidentate X2 and tridentate LX2 ligands with two phenolates linked to pyridine, thiophene, furan, and benzene connectors: mechanistic studies of the formation of a tantalum benzylidene and insertion chemistry for tantalum-carbon bonds; Organometallics; Vol. 27; No. 23; 6123-6142; 10.1021/om8002653
• Agapie, Theodor; Henling, Lawrence M.; et el. (2008) Zirconium and titanium complexes supported by tridentate LX2 ligands having two phenolates linked to furan, thiophene, and pyridine donors: precatalysts for propylene polymerization and oligomerization; Organometallics; Vol. 27; No. 23; 6245-6256; 10.1021/om800136y
• Bercaw, John E.; Chen, George S.; et el. (2008) Hydrogen tunneling in protonolysis of platinum(II) and palladium(II) methyl complexes: mechanistic implications; Journal of the American Chemical Society; Vol. 130; No. 52; 17654-17655; 10.1021/ja807427d
• Baldwin, Steven M.; Bercaw, John E.; et el. (2008) Alkylaluminum-complexed zirconocene hydrides: identification of hydride-bridged species by NMR spectroscopy; Journal of the American Chemical Society; Vol. 130; No. 51; 17423-17433; 10.1021/ja8054723
• Bercaw, John E.; Hazari, Nilay; et el. (2008) Oxidative aromatization of olefins with dioxygen catalyzed by palladium trifluoroacetate; Journal of Organic Chemistry; Vol. 73; No. 21; 8654-8657; 10.1021/jo8016296
• Miller, Alexander J. M.; Labinger, Jay A.; et el. (2008) Reductive Coupling of Carbon Monoxide in a Rhenium Carbonyl Complex with Pendant Lewis Acids; Journal of the American Chemical Society; Vol. 130; No. 36; 11874-11875; 10.1021/ja805108z
• Bercaw, John E.; Hazari, Nilay; et el. (2008) Selective Methylative Homologation: An Alternate Route to Alkane Upgrading; Journal of the American Chemical Society; Vol. 130; No. 36; 11988-11995; 10.1021/ja803029s
• Min, Endy Y.-J.; Byers, Jeffery A.; et el. (2008) Catalyst Site Epimerization during the Kinetic Resolution of Chiral α-Olefins by Polymerization; Organometallics; Vol. 27; No. 10; 2179-2188; 10.1021/om700778e
• Williams, Travis J.; Caffyn, Andrew J. M.; et el. (2008) C−H Bond Activation by Air-Stable [(Diimine)M^(II)(μ_2-OH)]_2^(2+)Dimers (M = Pd, Pt); Journal of the American Chemical Society; Vol. 130; No. 8; 2418-2419; 10.1021/ja076740q
• Bercaw, John E.; Diaconescu, Paula L.; et el. (2007) Conversion of Methanol to 2,2,3-Trimethylbutane (Triptane) over Indium(III) Iodide; Inorganic Chemistry; Vol. 46; No. 26; 11371-11380; 10.1021/ic7014447
• Agapie, Theodor; Labinger, Jay A.; et el. (2007) Mechanistic Studies of Olefin and Alkyne Trimerization with Chromium Catalysts: Deuterium Labeling and Studies of Regiochemistry Using a Model Chromacyclopentane Complex; Journal of the American Chemical Society; Vol. 129; No. 46; 14281-14295; 10.1021/ja073493h
• Bercaw, John E.; Grubbs, Robert H.; et el. (2007) Enhanced selectivity in the conversion of methanol to 2,2,3-trimethylbutane (triptane) over zinc iodide by added phosphorous or hypophosphorous acid; Chemical Communications; Vol. 2007; No. 28; 2974-2976; 10.1039/b705470j
• Agapie, Theodor and Bercaw, John E. (2007) Cyclometalated Tantalum Diphenolate Pincer Complexes: Intramolecular C−H/M−CH_3σ-Bond Metathesis May Be Faster than O−H/M−CH_3 Protonolysis; Organometallics; Vol. 26; No. 12; 2957-2959; 10.1021/om700284c
• Klamo, Sara B.; Wendt, Ola F.; et el. (2007) Dialkyl and Methyl-Alkyl Zirconocenes: Synthesis and Characterization of Zirconocene-Alkyls That Model the Polymeryl Chain in Alkene Polymerizations; Organometallics; Vol. 26; No. 12; 3018-3030; 10.1021/om0601302
• Bercaw, John E. and Labinger, Jay A. (2007) The coordination chemistry of saturated molecules; Proceedings of the National Academy of Sciences of the United States of America; Vol. 104; No. 17; 6899-6900; PMCID PMC1855396; 10.1073/pnas.0700902104
• Chen, George S.; Labinger, Jay A.; et el. (2007) The role of alkane coordination in C–H bond cleavage at a Pt(II) center; Proceedings of the National Academy of Sciences of the United States of America; Vol. 104; No. 17; 6915-6920; PMCID PMC1855376; 10.1073/pnas.0610981104
• Marinescu, Smaranda C.; Agapie, Theodor; et el. (2007) Group 3 Dialkyl Complexes with Tetradentate (L, L, N, O; L = N, O, S) Monoanionic Ligands: Synthesis and Reactivity; Organometallics; Vol. 26; No. 5; 1178-1190; 10.1021/om0608612
• Driver, Tom G.; Williams, Travis J.; et el. (2007) C−H Bond Activation by Dicationic Platinum(II) Complexes; Organometallics; Vol. 26; No. 2; 294-301; 10.1021/om060792r
• Williams, Travis J.; Labinger, Jay A.; et el. (2007) Reactions of Indene and Indoles with Platinum Methyl Cations: Indene C−H Activation, Indole π versus Nitrogen Lone-Pair Coordination; Organometallics; Vol. 26; No. 2; 281-287; PMCID PMC4833004; 10.1021/om0606643
• Weinberg, David R.; Labinger, Jay A.; et el. (2007) Competitive Oxidation and Protonation of Aqueous Monomethylplatinum(II) Complexes: A Comparison of Oxidants; Organometallics; Vol. 26; No. 1; 167-172; 10.1021/om060763g
• Bercaw, John E.; Diaconescu, Paula L.; et el. (2006) On the Mechanism of the Conversion of Methanol to 2,2,3-Trimethylbutane (Triptane) over Zinc Iodide; Journal of Organic Chemistry; Vol. 71; No. 23; 8907-8917; 10.1021/jo0617823
• Elowe, Paul R.; McCann, Cassandra; et el. (2006) Nitrogen-Linked Diphosphine Ligands with Ethers Attached to Nitrogen for Chromium-Catalyzed Ethylene Tri- and Tetramerizations; Organometallics; Vol. 25; No. 22; 5255-5260; 10.1021/om0601596
• Byers, Jeffery A. and Bercaw, John E. (2006) Kinetic resolution of racemic {alpha}-olefins with ansa-zirconocene polymerization catalysts: Enantiomorphic site vs. chain end control; Proceedings of the National Academy of Sciences of the United States of America; Vol. 103; No. 42; 15303-15308; PMCID PMC1622822; 10.1073/pnas.0603071103
• Miller, Stephen A. and Bercaw, John E. (2006) Mechanism of Isotactic Polypropylene Formation with C_1-Symmetric Metallocene Catalysts; Organometallics; Vol. 25; No. 15; 3576-3592; 10.1021/om050841k
• Agapie, Theodor; Day, Michael W.; et el. (2006) A Chromium-Diphosphine System for Catalytic Ethylene Trimerization: Synthetic and Structural Studies of Chromium Complexes with a Nitrogen-Bridged Diphosphine Ligand with ortho-Methoxyaryl Substituents; Organometallics; Vol. 25; No. 11; 2733-2742; 10.1021/om050605+
• Schofer, Susan J.; Day, Michael W.; et el. (2006) Ethylene Trimerization Catalysts Based on Chromium Complexes with a Nitrogen-Bridged Diphosphine Ligand Having ortho-Methoxyaryl or ortho-Thiomethoxy Substituents: Well-Defined Catalyst Precursors and Investigations of the Mechanism; Organometallics; Vol. 25; No. 11; 2743-2749; 10.1021/om0506062
• Owen, Jonathan S.; Labinger, Jay A.; et el. (2006) Kinetics and Mechanism of Methane, Methanol, and Dimethyl Ether C−H Activation with Electrophilic Platinum Complexes; Journal of the American Chemical Society; Vol. 128; No. 6; 2005-2016; 10.1021/ja056387t
• Lersch, Martin; Dalhus, Bjørn; et el. (2006) Improved One-Pot Synthesis of Mixed Methyl−Aryl Platinum(II) Diimine Complexes; Organometallics; Vol. 25; No. 4; 1055-1058; 10.1021/om050899z
• Chirik, Paul J. and Bercaw, John E. (2005) Cyclopentadienyl and Olefin Substituent Effects on Insertion and β-Hydrogen Elimination with Group 4 Metallocenes. Kinetics, Mechanism, and Thermodynamics for Zirconocene and Hafnocene Alkyl Hydride Derivatives; Organometallics; Vol. 24; No. 22; 5407-5423; 10.1021/om0580351
• Driver, Tom G.; Day, Michael W.; et el. (2005) Mechanism of C−H Bond Activation of Alkyl-Substituted Benzenes by Cationic Platinum(II) Complexes; Organometallics; Vol. 24; No. 15; 3644-3654; 10.1021/om050251m
• Chirik, Paul J.; Dalleska, Nathan F.; et el. (2005) Experimental Evidence for γ-Agostic Assistance in β-Methyl Elimination, the Microscopic Reverse of α-Agostic Assistance in the Chain Propagation Step of Olefin Polymerization; Organometallics; Vol. 24; No. 11; 2789-2794; 10.1021/om058002l
• Heyduk, Alan F.; Driver, Tom G.; et el. (2004) Kinetic and Thermodynamic Preferences in Aryl vs Benzylic C−H Bond Activation with Cationic Pt(II) Complexes; Journal of the American Chemical Society; Vol. 126; No. 46; 15034-15035; 10.1021/ja045078k
• Iverson, Carl N.; Carter, Charles A. G.; et el. (2004) C-H Bond Activation with Neutral Platinum Methyl Complexes; ISBN 9780841238497; 319-333; 10.1021/bk-2004-0885.ch019
• Heyduk, Alan F.; Zhong, H. Annita; et el. (2004) C—H Bond Activation at Pt(II): A Route to Selective Alkane Oxidation?; ISBN 9780841238497; 250-263; 10.1021/bk-2004-0885.ch015
• Baar, Cliff R.; Levy, Christopher J.; et el. (2004) Kinetic Resolution of Chiral α-Olefins Using Optically Active ansa-Zirconocene Polymerization Catalysts; Journal of the American Chemical Society; Vol. 126; No. 26; 8216-8231; 10.1021/ja040021j
• Owen, Jonathan S.; Labinger, Jay A.; et el. (2004) Pyridinium-Derived N-Heterocyclic Carbene Complexes of Platinum: Synthesis, Structure and Ligand Substitution Kinetics; Journal of the American Chemical Society; Vol. 126; No. 26; 8247-8255; 10.1021/ja040075t
• Miller, Stephen A. and Bercaw, John E. (2004) Highly Stereoregular Syndiotactic Polypropylene Formation with Metallocene Catalysts via Influence of Distal Ligand Substituents; Organometallics; Vol. 23; No. 8; 1777-1789; 10.1021/om030333f
• Agapie, Theodor; Schofer, Susan J.; et el. (2004) Mechanistic Studies of the Ethylene Trimerization Reaction with Chromium−Diphosphine Catalysts: Experimental Evidence for a Mechanism Involving Metallacyclic Intermediates; Journal of the American Chemical Society; Vol. 126; No. 5; 1304-1305; 10.1021/ja038968t
• Iverson, Carl N.; Carter, Charles A. G.; et el. (2003) C−H Bond Activation by Unsymmetrical 2-(N-Arylimino)pyrrolide Pt Complexes: Geometric Effects on Reactivity; Journal of the American Chemical Society; Vol. 125; No. 42; 12674-12675; 10.1021/ja036511d
• Ackerman, Lily J.; Sadighi, Joseph P.; et el. (2003) Arene C−H Bond Activation and Arene Oxidative Coupling by Cationic Palladium(II) Complexes; Organometallics; Vol. 22; No. 19; 3884-3890; 10.1021/om0303294
• Heyduk, Alan F.; Labinger, Jay A.; et el. (2003) Catalytic Alcoholysis of Tetramethylsilane via Pt-Mediated C−H Bond Activation; Journal of the American Chemical Society; Vol. 125; No. 21; 6366-6367; 10.1021/ja029099v
• Ackerman, Lily J.; Green, Malcolm L. H.; et el. (2003) Experimental and Theoretical Studies of Olefin Insertion foransa-Niobocene andansa-Tantalocene Ethylene Hydride Complexes; Organometallics; Vol. 22; No. 1; 188-194; 10.1021/om0206296
• Chirik, Paul J.; Zubris, Deanna L.; et el. (2003) Preparation of ansa-Niobocene and ansa-Tantalocene Olefin Hydride Complexes as Transition State Analogues in Metallocene-Catalyzed Olefin Polymerization; Organometallics; Vol. 22; No. 1; 172-187; 10.1021/om020628d
• Zachmanoglou, Cary E.; Docrat, Arefa; et el. (2002) The Electronic Influence of Ring Substituents and Ansa Bridges in Zirconocene Complexes as Probed by Infrared Spectroscopic, Electrochemical, and Computational Studies; Journal of the American Chemical Society; Vol. 124; No. 32; 9525-9546; 10.1021/ja020236y
• Rostovtsev, Vsevolod V.; Henling, Lawrence M.; et el. (2002) Structural and Mechanistic Investigations of the Oxidation of Dimethylplatinum(II) Complexes by Dioxygen; Inorganic Chemistry; Vol. 41; No. 14; 3608-3619; 10.1021/ic0112903
• Labinger, Jay A. and Bercaw, John E. (2002) Understanding and exploiting C–H bond activation; Nature; Vol. 417; No. 6888; 507-514; 10.1038/417507a
• Yoder, Jeffrey C. and Bercaw, John E. (2002) Chain Epimerization during Propylene Polymerization with Metallocene Catalysts: Mechanistic Studies Using a Doubly Labeled Propylene; Journal of the American Chemical Society; Vol. 124; No. 11; 2548-2555; 10.1021/ja0123296
• Miller, Stephen A. and Bercaw, John

5. 2002. Isotactic−Hemiisotactic Polypropylene from C_1-Symmetric ansa-Metallocene Catalysts: A New Strategy for the Synthesis of Elastomeric Polypropylene; Organometallics; Vol. 21; No. 5; 934-945; 10.1021/om010788+

• Zhong, H. Annita; Labinger, Jay A.; et el. (2002) C−H Bond Activation by Cationic Platinum(II) Complexes: Ligand Electronic and Steric Effects; Journal of the American Chemical Society; Vol. 124; No. 7; 1378-1399; 10.1021/ja011189x
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• Wendt, Ola F. and Bercaw, John E. (2001) Thermally Stable Dialkylzirconocenes with β-Hydrogens. Synthesis and Diastereoselectivity; Organometallics; Vol. 20; No. 18; 3891-3895; 10.1021/om0102910
• Zhong, Hong Annita; Labinger, Jay A.; et el. (2001) Carbon-hydrogen bond activation mediated by cationic platinum(II) complexes; Abstracts of Papers of the American Chemical Society; Vol. 221; INOR 83
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• Scollard, John D.; Labinger, Jay A.; et el. (2001) Studies towards the functionalization of light alkanes: Facile C-H bond activation by a neutral Pt(II) alkyl complex; Abstracts of Papers of the American Chemical Society; Vol. 221; INOR 85
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• Chirik, Paul J.; Henling, Lawrence M.; et el. (2001) Synthesis of Singly and Doubly Bridgedansa-Zirconocene Hydrides. Formation of an Unusual Mixed Valence Trimeric Hydride by Reaction of H_2 with {(Me_2Si)_2(η^5-C_5H_3)_2}Zr(CH_3)_2and Generation of a Dinitrogen Complex by Reaction of N_2 with a Zirconocene Dihydride; Organometallics; Vol. 20; No. 3; 534-544; 10.1021/om000739h
• Miller, Stephen A. and Bercaw, John

5. 2000. Aminofluorenyl−Pentamethylcyclopentadienyl and Bis(aminofluorenyl) Derivatives of Group 4 Metals; Organometallics; Vol. 19; No. 26; 5608-5613; 10.1021/om000723r

• Zubris, D. L.; Veghini, D.; et el. (1999) Reactivity and Mechanistic Studies of Stereocontrol for Ziegler—Natta Polymerization Utilizing Doubly-Silylene Bridged Group 3 and Group 4 Metalocenes; ISBN 9780841236141; 2-14; 10.1021/bk-2000-0749.ch001
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