- Bercaw, John; Berke, Heinz; et el. (2019) Hans
Herbert Brintzinger (1935–2019); Angewandte Chemie International
Edition; Vol. 58; No. 34; 11569; 10.1002/anie.201907530
- Panchenko, Valentina N.; Babushkin, Dmitrii E.; et el. (2019) Catalyst
Speciation During ansa-Zirconocene-Catalyzed Polymerization of 1-Hexene
Studied by UV-vis Spectroscopy—Formation and Partial Re-Activation of
Zr-Allyl Intermediates; Polymers; Vol. 11; No. 6; Art. No. 936;
PMCID PMC6630943; 10.3390/polym11060936
- Bercaw, John E. and Labinger, Jay A. (2019) Malcolm
L. H. Green: Reminiscences and Appreciations; Inorganica Chimica
Acta; Vol. 487; 405-408; 10.1016/j.ica.2018.12.044
- Bercaw, John (2018) Mechanistic
studies inspired by Jack
- Bercaw, John E. (2018) Jack
Halpern (1925–2018): Pioneer of homogeneous catalysis; Proceedings
of the National Academy of Sciences of the United States of America;
Vol. 115; No. 20; 5049-5050; PMCID PMC5960341; 10.1073/pnas.1806116115
- Bercaw, John E. (2018) Olefin
trimerization and ethylene tandem conversion to linear low density
polyethylene
- Steelman, D. Keith; Aluthge, Dinesh C.; et el. (2017) Mechanistic
Studies on Selective Trimerization of Linear α-Olefins over a Supported
Titanium Catalyst; ACS Catalysis; Vol. 7; No. 8; 4922-4926; 10.1021/acscatal.7b00256
- Bercaw, John E. (2017) Award
Address (Gabor A. Somorjai Award for Creative Research in Catalysis
sponsored by the Gabor A. & Judith K. Somorjai Endowment Fund).
Mechanistic studies of 1-alkene trimerization and polymerization with
organotransition metal catalysts
- Aluthge, Dinesh; Sattler, Aaron; et el. (2017) Co-supported
tandem catalysts for production of linear low density
polyethylene
- Bercaw, John E.; Aluthge, Dinesh; et el. (2017) Olefin
trimerization with titanium catalysts: MAO/silica-supported variants
display higher productivities
- Aluthge, Dinesh C.; Sattler, Aaron; et el. (2016) Cosupported
Tandem Catalysts for Production of Linear Low-Density Polyethylene from
an Ethylene-Only Feed; ACS Catalysis; Vol. 6; No. 10; 6581-6584; 10.1021/acscatal.6b02370
- Bercaw, John; Do, Loi; et el. (2016) Ethylene
and alpha olefin trimerization and tandem trimerization/polymerization
of ethylene
- Bercaw, John E.; Labinger, Jay A.; et el. (2016) Homogeneous
Ta/Ir tandem catalytic alkane/alkene coupling
- Labinger, Jay; Bercaw, John; et el. (2016) Oligo
or poly? A mechanistic interpretation of a switchable catalyst
- Sattler, Aaron; Aluthge, Dinesh C.; et el. (2016) Enhanced
Productivity of a Supported Olefin Trimerization Catalyst; ACS
Catalysis; Vol. 6; No. 1; 19-22; 10.1021/acscatal.5b02604
- Mindiola, Daniel J.; Smith, Milton R.; et el. (2015) Gregory
L. Hillhouse: His Life, His Art, His Science, and the Rise of “Double
Nickel”; Organometallics; Vol. 34; No. 19; 4633-4636; 10.1021/acs.organomet.5b00527
- Despagnet-Ayoub, Emmanuelle; Takase, Michael K.; et el. (2015) Mechanistic
Insights on the Controlled Switch from Oligomerization to Polymerization
of 1-Hexene Catalyzed by an NHC-Zirconium Complex; Organometallics;
Vol. 34; No. 19; 4707-4716; 10.1021/acs.organomet.5b00472
- Labinger, Jay A. and Bercaw, John E. (2015) Mechanistic
studies on the Shilov system: A retrospective; Journal of
Organometallic Chemistry; Vol. 793; 47-53; 10.1016/j.jorganchem.2015.01.027
- Despagnet-Ayoub, Emmanuelle; Takase, Michael K.; et el. (2015) Reversible
1,2-Alkyl Migration to Carbene and Ammonia Activation in an
N-Heterocyclic Carbene–Zirconium Complex; Journal of the American
Chemical Society; Vol. 137; No. 33; 10500-10503; 10.1021/jacs.5b06695
- Bercaw, John E.; Labinger, Jay A.; et el. (2015) Linear
low density polyethylenes using well defined tandem catalysts and a
single monomer feed
- Bercaw, John E.; Leitch, David C.; et el. (2015) Tandem
catalytic processes for light alkane upgrading and ethylene
polymerization
- Labinger, Jay A.; Leitch, David C.; et el. (2015) Upgrading
Light Hydrocarbons: A Tandem Catalytic System for Alkane/Alkene
Coupling; Topics in Catalysis; Vol. 58; No. 7-9; 494-501; 10.1007/s11244-015-0380-2
- Winston, Matthew S. and Bercaw, John E. (2014) Palladium(II)
Complexes Supported by a Bidentate Bis(secondary)phosphine Linked by
Pyridine; Inorganica Chimica Acta; Vol. 422; 30-35; 10.1016/j.ica.2014.08.002
- Teets, Thomas S.; Labinger, Jay A.; et el. (2014) Guanidine-Functionalized
Rhenium Cyclopentadienyl Carbonyl Complexes: Synthesis and Cooperative
Activation of H–H and O–H Bonds; Organometallics; Vol. 33; No. 15;
4107-4117; 10.1021/om500650b
- Despagnet-Ayoub, Emmanuelle; Labinger, Jay A.; et el. (2014) N-Heterocyclic
carbene group 4 transition metal catalysts: Synthesis and reactivity
towards oligomerization/polymerization of α-olefins; Abstracts of
Papers of the American Chemical Society; Vol. 248; 527-INOR
- Sattler, Aaron; Winkler, Jay R.; et el. (2014) Upgrading
light olefins by trimerization catalysis
- Sattler, Aaron; VanderVelde, David G.; et el. (2014) Lewis
Acid Promoted Titanium Alkylidene Formation: Off-Cycle Intermediates
Relevant to Olefin Trimerization Catalysis; Journal of the American
Chemical Society; Vol. 136; No. 30; 10790-10800; 10.1021/ja5055687
- Leitch, David C.; Labinger, Jay A.; et el. (2014) Scope
and Mechanism of Homogeneous Tantalum/Iridium Tandem Catalytic
Alkane/Alkene Upgrading using Sacrificial Hydrogen Acceptors;
Organometallics; Vol. 33; No. 13; 3353-3365; 10.1021/om500231t
- Klet, Rachel C.; Theriault, Curt N.; et el. (2014) Investigations
into Asymmetric Post-Metallocene Group 4 Complexes for the Synthesis of
Highly Regioirregular Polypropylene; Macromolecules; Vol. 47;
No. 10; 3317-3324; 10.1021/ma500453t
- Min, Endy Y.-J; Bercaw, John E.; et el. (2014) Bis(η^5-Pentamethylcyclopentadienyl)
Complexes of Niobium and Tantalum; ISBN 9781118744871; 52-57; 10.1002/9781118744994.ch11
- Min, Endy Y.-J.; Bercaw, John E.; et el. (2014) Bis(η^5-Pentamethylcyclopentadienyl)
Complexes of Titanium, Zirconium, and Hafnium; ISBN 9781118744871;
47-51; 10.1002/9781118744994.ch10
- Shin, Jun Ho; Churchill, David G.; et el. (2014) Bis(η⁵-Pentamethylcyclopentadienyl)
Complexes of Molybdenum; ISBN 9781118744871; 58-62; 10.1002/9781118744994.ch12
- Min, Endy Y.-J; Bercaw, John E.; et el. (2014) Bis(η⁵-Pentamethylcyclopentadienyl)
Complexes of Scandium; ISBN 9781118744871; 42-47; 10.1002/9781118744994.ch09
- Labinger, Jay A.; Leitch, David C.; et el. (2014) Upgrading
light hydrocarbons: A tandem catalytic system for alkane/alkene
coupling
- Sattler, Aaron; Labinger, Jay A.; et el. (2013) Highly
Selective Olefin Trimerization Catalysis by a Borane-Activated Titanium
Trimethyl Complex; Organometallics; Vol. 32; No. 23; 6899-6902; 10.1021/om401098m
- Do, Loi H.; Labinger, Jay A.; et el. (2013) Spectral
Studies of a Cr(PNP)−MAO System for Selective Ethylene Trimerization
Catalysis: Searching for the Active Species; ACS Catalysis; Vol. 3;
No. 11; 2582-2585; PMCID PMC3855459; 10.1021/cs400778a
- Teets, Thomas S.; Labinger, Jay A.; et el. (2013) A
Thermodynamic Analysis of Rhenium(I)−Formyl C−H Bond Formation via
Base-Assisted Heterolytic H_2 Cleavage in the Secondary Coordination
Sphere; Organometallics; Vol. 32; No. 19; 5530-5545; 10.1021/om400810v
- Despagnet-Ayoub, Emmanuelle; Henling, Lawrence M.; et el. (2013) Addition
of a phosphine ligand switches an N-heterocyclic carbene-zirconium
catalyst from oligomerization to polymerization of 1-hexene; Dalton
Transactions; Vol. 42; No. 44; 15544-15547; 10.1039/C3DT52342J
- Kamal, Muhammad Shahzad; Bahuleyan, Bijal Kottukkal; et el. (2013)
Crystallization
analysis fractionation of poly(ethylene-co-styrene) produced by
metallocene catalysts; Polymer Bulletin; Vol. 70; No. 9; 2645-2656;
10.1007/s00289-013-0980-6
- Appel, Aaron M.; Bercaw, John E.; et el. (2013) Frontiers,
Opportunities, and Challenges in Biochemical and Chemical Catalysis of
CO_2 Fixation; Chemical Reviews; Vol. 113; No. 8; 6621-6658; PMCID
PMC3895110; 10.1021/cr300463y
- Lenton, Taylor N.; Bercaw, John E.; et el. (2013) Formation
of Trivalent Zirconocene Complexes from ansa-Zirconocene-Based
Olefin-Polymerization Precatalysts: An EPR- and NMR-Spectroscopic
Study; Journal of the American Chemical Society; Vol. 135; No. 29;
10710-10719; 10.1021/ja403170u
- Leitch, David C.; Lam, Yan Choi; et el. (2013) Upgrading
Light Hydrocarbons via Tandem Catalysis: A Dual Homogeneous Ta/Ir System
for Alkane/Alkene Coupling; Journal of the American Chemical
Society; Vol. 135; No. 28; 10302-10305; 10.1021/ja405191a
- Tonks, Ian A.; Meier, Josef C.; et el. (2013) Alkyne
Hydroamination and Trimerization with Titanium Bis(phenolate)pyridine
Complexes: Evidence for Low-Valent Titanium Intermediates and Synthesis
of an Ethylene Adduct of Titanium(II); Organometallics; Vol. 32;
No. 12; 3451-3457; 10.1021/om400080g
- Ahmed, Tonia S.; Tonks, Ian A.; et el. (2013) Kinetics
and Mechanism of Indene C–H Bond Activation by [(COD)Ir(μ_2-OH)]_2;
Organometallics; Vol. 32; No. 11; 3322-3326; 10.1021/om400230j
- Despagnet-Ayoub, Emmanuelle; Henling, Lawrence M.; et el. (2013) Group
4 Transition-Metal Complexes of an Aniline–Carbene–Phenol Ligand;
Organometallics; Vol. 32; No. 10; 2934-2938; 10.1021/om4001567
- Bercaw, John E.; Labinger, Jay A.; et el. (2013) New
precatalysts for olefin polymerization having LX2 pincer
ligands
- Bercaw, John E.; Labinger, Jay A.; et el. (2013) Reductive
coupling of carbon monoxide in carbonyl complexes with pendant Lewis
acids or bases
- Despagnet-Ayoub, Emmanuelle; Miqueu, Karinne; et el. (2013) Unexpected
rearrangements in the synthesis of an unsymmetrical tridentate dianionic
N-heterocyclic carbene; Chemical Science; Vol. 4; No. 5; 2117-2121;
10.1039/c3sc22171g
- Lenton, Taylor N.; VanderVelde, David G.; et el. (2012) Synthesis
of a Bis(thiophenolate)pyridine Ligand and Its Titanium, Zirconium, and
Tantalum Complexes; Organometallics; Vol. 31; No. 21; 7492-7499; 10.1021/om300789h
- Winston, Matthew S.; Oblad, Paul F.; et el. (2012) Activator-Free
Olefin Oligomerization and Isomerization Reactions Catalyzed by an Air-
and Water-Tolerant Wacker Oxidation Intermediate; Angewandte Chemie
International Edition; Vol. 51; No. 39; 9822-9824; 10.1002/anie.201206215
- Klet, Rachel C.; Labinger, Jay A.; et el. (2012) Diverse
C−C Bond-Forming Reactions of Bis(carbene)platinum(II) Complexes;
Organometallics; Vol. 31; No. 18; 6652-6657; 10.1021/om300733h
- Hazari, Amaruka; Labinger, Jay A.; et el. (2012) A
Versatile Ligand Platform that Supports Lewis Acid Promoted Migratory
Insertion; Angewandte Chemie International Edition; Vol. 51; No. 33;
8268-8271; 10.1002/anie.201203264
- Do, Loi H.; Labinger, Jay A.; et el. (2012) Mechanistic
Studies of Ethylene and α-Olefin Co-Oligomerization Catalyzed by
Chromium−PNP Complexes; Organometallics; Vol. 31; No. 14; 5143-5149;
10.1021/om300492r
- Klet, Rachel C.; VanderVelde, David G.; et el. (2012) Highly
regioirregular polypropylene from asymmetric group 4
anilide(pyridine)phenoxide complexes; Chemical Communications; Vol.
48; No. 53; 6657-6659; 10.1039/C2CC32806B
- Atiqullah, M.; Winston, M. S.; et el. (2012) Effects
of a vanadium post-metallocene catalyst-induced polymer backbone
inhomogeneity on UV oxidative degradation of the resulting polyethylene
film; Polymer Degradation and Stability; Vol. 97; No. 7; 1164-1177;
10.1016/j.polymdegradstab.2012.03.042
- Tonks, Ian A.; Durrell, Alec C.; et el. (2012) Groups
5 and 6 Terminal Hydrazido(2−) Complexes: N_β Substituent Effects on
Ligand-to-Metal Charge-Transfer Energies and Oxidation States;
Journal of the American Chemical Society; Vol. 134; No. 17; 7301-7304;
10.1021/ja302275j
- Tonks, Ian A.; Tofan, Daniel; et el. (2012) Zirconium
and Titanium Propylene Polymerization Precatalysts Supported by a
Fluxional C_2-Symmetric Bis(anilide)pyridine Ligand;
Organometallics; Vol. 31; No. 5; 1965-1974; 10.1021/om201262h
- Fu, Ross; Bercaw, John E.; et el. (2011) Intra-
and Intermolecular C−H Activation by Bis(phenolate)pyridineiridium(III)
Complexes; Organometallics; Vol. 30; No. 24; 6751-6765; 10.1021/om201069k
- Scott, Valerie J.; Labinger, Jay A.; et el. (2011) Large
Kinetic Isotope Effects for the Protonolysis of Metal-Methyl Complexes
Are Not Reliable Mechanistic Indicators; Organometallics; Vol. 30;
No. 16; 4374-4378; 10.1021/om200432b
- Miller, Alexander J. M.; Labinger, Jay A.; et el. (2011) Trialkylborane-Assisted
CO_2 Reduction by Late Transition Metal Hydrides; Organometallics;
Vol. 30; No. 16; 4308-4314; 10.1021/om200364w
- West, Nathan M.; Labinger, Jay A.; et el. (2011) Heterobimetallic
Complexes of Rhenium and Zinc: Potential Catalysts for Homogeneous
Syngas Conversion; Organometallics; Vol. 30; No. 10; 2690-2700; 10.1021/om200051u
- West, Nathan M.; Miller, Alexander J. M.; et el. (2011) Homogeneous
syngas conversion; Coordination Chemistry Reviews; Vol. 255;
No. 7-8; 881-898; 10.1016/j.ccr.2010.08.019
- Baldwin, Steven M.; Bercaw, John E.; et el. (2011) Cationic
Alkylaluminum-Complexed Zirconocene Hydrides: NMR-Spectroscopic
Identification, Crystallographic Structure Determination, and
Interconversion with Other Zirconocene Cations; Journal of the
American Chemical Society; Vol. 133; No. 6; 1805-1813; 10.1021/ja1050428
- Labinger, Jay A. and Bercaw, John E. (2011) The
Role of Higher Oxidation State Species in Platinum-Mediated C–H Bond
Activation and Functionalization; ISBN 978-3-642-17428-5; 29-59; 10.1007/978-3-642-17429-2_2
- Winston, Matthew S. and Bercaw, John E. (2010) A
Novel Bis(phosphido)pyridine [PNP]^(2−) Pincer Ligand and Its Potassium
and Bis(dimethylamido)zirconium(IV) Complexes; Organometallics; Vol.
29; No. 23; 6408-6416; 10.1021/om100775g
- Golisz, Suzanne R.; Labinger, Jay A.; et el. (2010) Intramolecular
C−H Activation of a Bisphenolate(benzene)-Ligated Titanium Dibenzyl
Complex. Competing Pathways Involving α-Hydrogen Abstraction and σ-Bond
Metathesis; Organometallics; Vol. 29; No. 21; 5026-5032; 10.1021/om100253u
- Miller, Alexander J. M.; Labinger, Jay A.; et el. (2010) Homogeneous
CO Hydrogenation: Ligand Effects on the Lewis Acid-Assisted Reductive
Coupling of Carbon Monoxide; Organometallics; Vol. 29; No. 20;
4499-4516; 10.1021/om100638d
- Baldwin, Steven M.; Bercaw, John E.; et el. (2010) Cationic
Alkylaluminum-Complexed Zirconocene Hydrides as Participants in Olefin
Polymerization Catalysis; Journal of the American Chemical Society;
Vol. 132; No. 40; 13969-13971; 10.1021/ja105040r
- Bercaw, John E.; Chen, George S.; et el. (2010) Protonolysis
of Platinum(II) and Palladium(II) Methyl Complexes: A Combined
Experimental and Theoretical Investigation; Organometallics; Vol.
29; No. 19; 4354-4359; 10.1021/om100655w
- Scott, Valerie J.; Labinger, Jay A.; et el. (2010) Mechanism
of Reductive Elimination of Methyl Iodide from a Novel
Gold(III)−Monomethyl Complex; Organometallics; Vol. 29; No. 18;
4090-4096; 10.1021/om1006566
- Tonks, Ian A. and Bercaw, John E. (2010) (dme)MCl_3(NNPh_2)
(dme= dimethoxyethane; M= Nb, Ta): A Versatile Synthon for [Ta═NNPh_2]
Hydrazido(2-) Complexes; Inorganic Chemistry; Vol. 49; No. 10;
4648-4656; 10.1021/ic1004193
- Fulmer, Gregory R.; Miller, Alexander J. M.; et el. (2010) NMR
Chemical Shifts of Trace Impurities: Common Laboratory Solvents,
Organics, and Gases in Deuterated Solvents Relevant to the
Organometallic Chemist; Organometallics; Vol. 29; No. 9; 2176-2179;
10.1021/om100106e
- Wilson, Aaron D.; Miller, Alexander J. M.; et el. (2010) Thermodynamic
Studies of [H_(2)Rh(diphosphine)_2]^+ and
[HRh(diphosphine)(2)(CH(3)CN)]^(2+) Complexes in
Acetonitrile; Inorganic Chemistry; Vol. 49; No. 8; 3918-3926; 10.1021/ic100117y
- Miller, Alexander J. M.; Labinger, Jay A.; et el. (2010) Homogeneous
CO Hydrogenation: Dihydrogen Activation Involves a Frustrated Lewis Pair
Instead of a Platinum Complex; Journal of the American Chemical
Society; Vol. 132; No. 10; 3301-3303; 10.1021/ja100574n
- Oblad, Paul F.; Bercaw, John E.; et el. (2010) Oxidation
of Organometallic Platinum and Palladium Complexes Obtained from C−H
Activation; Organometallics; Vol. 29; No. 4; 789-794; 10.1021/om900678z
- Bercaw, John E.; Durrell, Alec C.; et el. (2010) Electronic
Structures of Pd^(II) Dimers; Inorganic Chemistry; Vol. 49; No. 4;
1801-1810; 10.1021/ic902189g
- Weinberg, David R.; Hazari, Nilay; et el. (2010) Iridium(I)
and Iridium(III) Complexes Supported by a Diphenolate Imidazolyl-Carbene
Ligand; Organometallics; Vol. 29; No. 1; 89-100; 10.1021/om900803r
- Miller, Alexander J. M. and Bercaw, John E. (2010) Dehydrogenation
of amine–boranes with a frustrated Lewis pair; Chemical
Communications; Vol. 46; No. 10; 1709-1711; 10.1039/b925659h
- Golisz, Suzanne R. and Bercaw, John E. (2009) Synthesis
of Early Transition Metal Bisphenolate Complexes and Their Use as Olefin
Polymerization Catalysts; Macromolecules; Vol. 42; No. 22;
8751-8762; 10.1021/ma901659q
- Golisz, Suzanne R.; Hazari, Nilay; et el. (2009) Activation
of the C−N Bond in Nitromethane by Palladium α-Diimine Complexes;
Journal of Organic Chemistry; Vol. 74; No. 21; 8441-8443; 10.1021/jo901635g
- Elowe, Paul R.; West, Nathan M.; et el. (2009) Transformations
of Group 7 Carbonyl Complexes: Possible Intermediates in a Homogeneous
Syngas Conversion Scheme; Organometallics; Vol. 28; No. 21;
6218-6227; 10.1021/om900804j
- Bercaw, John E.; Hazari, Nilay; et el. (2009) Activation
of a C−H Bond in Indene by [(COD)Rh(μ_2-OH)]_2; Organometallics;
Vol. 28; No. 18; 5489-5492; 10.1021/om9004498
- Bercaw, John E.; Day, Michael W.; et el. (2009) Robotic
Lepidoptery: Structural Characterization of (mostly) Unexpected
Palladium Complexes Obtained from High-Throughput Catalyst
Screening; Organometallics; Vol. 28; No. 17; 5017-5024; 10.1021/om900240a
- Chen, George S.; Labinger, Jay A.; et el. (2009) Selective
Oxidation of sp^3 C-H Bonds in Water Catalyzed by a
Glycinate-Platinum(II) Complex; Organometallics; Vol. 28; No. 17;
4899-4901; 10.1021/om900267w
- Lin, Bo-Lin; Bhattacharyya, Koyel X.; et el. (2009) Competitive
Benzene C−H Bond Activation versus Olefin Insertion in a
(Monomethyl)palladium(II) β-Diketiminate Complex; Organometallics;
Vol. 28; No. 15; 4400-4405; 10.1021/om900171d
- Scott, Valerie J.; Henling, Lawrence M.; et el. (2009) Competitive
Activation of a Methyl C−H Bond of Dimethylformamide at an Iridium
Center; Organometallics; Vol. 28; No. 14; 4229-4230; 10.1021/om9002413
- Tonks, Ian A.; Henling, Larry M.; et el. (2009) Amine,
Amido, and Imido Complexes of Tantalum Supported by a Pyridine-Linked
Bis(phenolate) Pincer Ligand: Ta−N π-Bonding Influences Pincer Ligand
Geometry; Inorganic Chemistry; Vol. 48; No. 12; 5096-5105; 10.1021/ic802234x
- Weintrob, Edward C.; Tofan, Daniel; et el. (2009) Synthesis
and Characterization of Iron Derivatives Having a Pyridine-Linked
Bis(anilide) Pincer Ligand; Inorganic Chemistry; Vol. 48; No. 8;
3808-3813; 10.1021/ic900083s
- Lin, Bo-Lin; Labinger, Jay A.; et el. (2009) Mechanistic
investigations of bipyrimidine-promoted palladium-catalyzed allylic
acetoxylation of olefins; Canadian Journal of Chemistry; Vol. 87;
No. 1; 264-271; 10.1139/V08-133
- Bercaw, John E.; Hazari, Nilay; et el. (2008) C-H Bond
Activation by [{(Diimine)Pd(μ-OH)}2]2+ Dimers: Mechanism-Guided
Catalytic Improvement; Angewandte Chemie International Edition; Vol.
47; No. 51; 9941-9943; 10.1002/anie.200804455
- Agapie, Theodor; Day, Michael W.; et el. (2008) Synthesis and
reactivity of tantalum complexes supported by bidentate X2 and
tridentate LX2 ligands with two phenolates linked to pyridine,
thiophene, furan, and benzene connectors: mechanistic studies of the
formation of a tantalum benzylidene and insertion chemistry for
tantalum-carbon bonds; Organometallics; Vol. 27; No. 23; 6123-6142;
10.1021/om8002653
- Agapie, Theodor; Henling, Lawrence M.; et el. (2008) Zirconium and
titanium complexes supported by tridentate LX2 ligands having two
phenolates linked to furan, thiophene, and pyridine donors: precatalysts
for propylene polymerization and oligomerization; Organometallics;
Vol. 27; No. 23; 6245-6256; 10.1021/om800136y
- Bercaw, John E.; Chen, George S.; et el. (2008) Hydrogen
tunneling in protonolysis of platinum(II) and palladium(II) methyl
complexes: mechanistic implications; Journal of the American
Chemical Society; Vol. 130; No. 52; 17654-17655; 10.1021/ja807427d
- Baldwin, Steven M.; Bercaw, John E.; et el. (2008) Alkylaluminum-complexed
zirconocene hydrides: identification of hydride-bridged species by NMR
spectroscopy; Journal of the American Chemical Society; Vol. 130;
No. 51; 17423-17433; 10.1021/ja8054723
- Bercaw, John E.; Hazari, Nilay; et el. (2008) Oxidative
aromatization of olefins with dioxygen catalyzed by palladium
trifluoroacetate; Journal of Organic Chemistry; Vol. 73; No. 21;
8654-8657; 10.1021/jo8016296
- Miller, Alexander J. M.; Labinger, Jay A.; et el. (2008) Reductive
Coupling of Carbon Monoxide in a Rhenium Carbonyl Complex with Pendant
Lewis Acids; Journal of the American Chemical Society; Vol. 130;
No. 36; 11874-11875; 10.1021/ja805108z
- Bercaw, John E.; Hazari, Nilay; et el. (2008) Selective
Methylative Homologation: An Alternate Route to Alkane Upgrading;
Journal of the American Chemical Society; Vol. 130; No. 36; 11988-11995;
10.1021/ja803029s
- Min, Endy Y.-J.; Byers, Jeffery A.; et el. (2008) Catalyst
Site Epimerization during the Kinetic Resolution of Chiral α-Olefins by
Polymerization; Organometallics; Vol. 27; No. 10; 2179-2188; 10.1021/om700778e
- Williams, Travis J.; Caffyn, Andrew J. M.; et el. (2008) C−H
Bond Activation by Air-Stable [(Diimine)M^(II)(μ_2-OH)]_2^(2+)Dimers (M
= Pd, Pt); Journal of the American Chemical Society; Vol. 130;
No. 8; 2418-2419; 10.1021/ja076740q
- Bercaw, John E.; Diaconescu, Paula L.; et el. (2007) Conversion
of Methanol to 2,2,3-Trimethylbutane (Triptane) over Indium(III)
Iodide; Inorganic Chemistry; Vol. 46; No. 26; 11371-11380; 10.1021/ic7014447
- Agapie, Theodor; Labinger, Jay A.; et el. (2007) Mechanistic
Studies of Olefin and Alkyne Trimerization with Chromium Catalysts:
Deuterium Labeling and Studies of Regiochemistry Using a Model
Chromacyclopentane Complex; Journal of the American Chemical
Society; Vol. 129; No. 46; 14281-14295; 10.1021/ja073493h
- Bercaw, John E.; Grubbs, Robert H.; et el. (2007) Enhanced
selectivity in the conversion of methanol to 2,2,3-trimethylbutane
(triptane) over zinc iodide by added phosphorous or hypophosphorous
acid; Chemical Communications; Vol. 2007; No. 28; 2974-2976; 10.1039/b705470j
- Agapie, Theodor and Bercaw, John E. (2007) Cyclometalated
Tantalum Diphenolate Pincer Complexes: Intramolecular C−H/M−CH_3σ-Bond
Metathesis May Be Faster than O−H/M−CH_3 Protonolysis;
Organometallics; Vol. 26; No. 12; 2957-2959; 10.1021/om700284c
- Klamo, Sara B.; Wendt, Ola F.; et el. (2007) Dialkyl
and Methyl-Alkyl Zirconocenes: Synthesis and Characterization of
Zirconocene-Alkyls That Model the Polymeryl Chain in Alkene
Polymerizations; Organometallics; Vol. 26; No. 12; 3018-3030; 10.1021/om0601302
- Bercaw, John E. and Labinger, Jay A. (2007) The
coordination chemistry of saturated molecules; Proceedings of the
National Academy of Sciences of the United States of America; Vol. 104;
No. 17; 6899-6900; PMCID PMC1855396; 10.1073/pnas.0700902104
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of alkane coordination in C–H bond cleavage at a Pt(II) center;
Proceedings of the National Academy of Sciences of the United States of
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Monoanionic Ligands: Synthesis and Reactivity; Organometallics; Vol.
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Bond Activation by Dicationic Platinum(II) Complexes;
Organometallics; Vol. 26; No. 2; 294-301; 10.1021/om060792r
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of Indene and Indoles with Platinum Methyl Cations: Indene C−H
Activation, Indole π versus Nitrogen Lone-Pair Coordination;
Organometallics; Vol. 26; No. 2; 281-287; PMCID PMC4833004; 10.1021/om0606643
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Oxidation and Protonation of Aqueous Monomethylplatinum(II) Complexes: A
Comparison of Oxidants; Organometallics; Vol. 26; No. 1; 167-172; 10.1021/om060763g
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the Mechanism of the Conversion of Methanol to 2,2,3-Trimethylbutane
(Triptane) over Zinc Iodide; Journal of Organic Chemistry; Vol. 71;
No. 23; 8907-8917; 10.1021/jo0617823
- Elowe, Paul R.; McCann, Cassandra; et el. (2006) Nitrogen-Linked
Diphosphine Ligands with Ethers Attached to Nitrogen for
Chromium-Catalyzed Ethylene Tri- and Tetramerizations;
Organometallics; Vol. 25; No. 22; 5255-5260; 10.1021/om0601596
- Byers, Jeffery A. and Bercaw, John E. (2006) Kinetic
resolution of racemic {alpha}-olefins with ansa-zirconocene
polymerization catalysts: Enantiomorphic site vs. chain end control;
Proceedings of the National Academy of Sciences of the United States of
America; Vol. 103; No. 42; 15303-15308; PMCID PMC1622822; 10.1073/pnas.0603071103
- Miller, Stephen A. and Bercaw, John E. (2006) Mechanism
of Isotactic Polypropylene Formation with C_1-Symmetric Metallocene
Catalysts; Organometallics; Vol. 25; No. 15; 3576-3592; 10.1021/om050841k
- Agapie, Theodor; Day, Michael W.; et el. (2006) A
Chromium-Diphosphine System for Catalytic Ethylene Trimerization:
Synthetic and Structural Studies of Chromium Complexes with a
Nitrogen-Bridged Diphosphine Ligand with ortho-Methoxyaryl
Substituents; Organometallics; Vol. 25; No. 11; 2733-2742; 10.1021/om050605+
- Schofer, Susan J.; Day, Michael W.; et el. (2006) Ethylene
Trimerization Catalysts Based on Chromium Complexes with a
Nitrogen-Bridged Diphosphine Ligand Having ortho-Methoxyaryl or
ortho-Thiomethoxy Substituents: Well-Defined Catalyst Precursors and
Investigations of the Mechanism; Organometallics; Vol. 25; No. 11;
2743-2749; 10.1021/om0506062
- Owen, Jonathan S.; Labinger, Jay A.; et el. (2006) Kinetics
and Mechanism of Methane, Methanol, and Dimethyl Ether C−H Activation
with Electrophilic Platinum Complexes; Journal of the American
Chemical Society; Vol. 128; No. 6; 2005-2016; 10.1021/ja056387t
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One-Pot Synthesis of Mixed Methyl−Aryl Platinum(II) Diimine
Complexes; Organometallics; Vol. 25; No. 4; 1055-1058; 10.1021/om050899z
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and Olefin Substituent Effects on Insertion and β-Hydrogen Elimination
with Group 4 Metallocenes. Kinetics, Mechanism, and Thermodynamics for
Zirconocene and Hafnocene Alkyl Hydride Derivatives;
Organometallics; Vol. 24; No. 22; 5407-5423; 10.1021/om0580351
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of C−H Bond Activation of Alkyl-Substituted Benzenes by Cationic
Platinum(II) Complexes; Organometallics; Vol. 24; No. 15; 3644-3654;
10.1021/om050251m
- Chirik, Paul J.; Dalleska, Nathan F.; et el. (2005) Experimental
Evidence for γ-Agostic Assistance in β-Methyl Elimination, the
Microscopic Reverse of α-Agostic Assistance in the Chain Propagation
Step of Olefin Polymerization; Organometallics; Vol. 24; No. 11;
2789-2794; 10.1021/om058002l
- Heyduk, Alan F.; Driver, Tom G.; et el. (2004) Kinetic
and Thermodynamic Preferences in Aryl vs Benzylic C−H Bond Activation
with Cationic Pt(II) Complexes; Journal of the American Chemical
Society; Vol. 126; No. 46; 15034-15035; 10.1021/ja045078k
- Iverson, Carl N.; Carter, Charles A. G.; et el. (2004) C-H
Bond Activation with Neutral Platinum Methyl Complexes; ISBN
9780841238497; 319-333; 10.1021/bk-2004-0885.ch019
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Bond Activation at Pt(II): A Route to Selective Alkane Oxidation?;
ISBN 9780841238497; 250-263; 10.1021/bk-2004-0885.ch015
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Resolution of Chiral α-Olefins Using Optically Active ansa-Zirconocene
Polymerization Catalysts; Journal of the American Chemical Society;
Vol. 126; No. 26; 8216-8231; 10.1021/ja040021j
- Owen, Jonathan S.; Labinger, Jay A.; et el. (2004) Pyridinium-Derived
N-Heterocyclic Carbene Complexes of Platinum: Synthesis, Structure and
Ligand Substitution Kinetics; Journal of the American Chemical
Society; Vol. 126; No. 26; 8247-8255; 10.1021/ja040075t
- Miller, Stephen A. and Bercaw, John E. (2004) Highly
Stereoregular Syndiotactic Polypropylene Formation with Metallocene
Catalysts via Influence of Distal Ligand Substituents;
Organometallics; Vol. 23; No. 8; 1777-1789; 10.1021/om030333f
- Agapie, Theodor; Schofer, Susan J.; et el. (2004) Mechanistic
Studies of the Ethylene Trimerization Reaction with Chromium−Diphosphine
Catalysts: Experimental Evidence for a Mechanism Involving Metallacyclic
Intermediates; Journal of the American Chemical Society; Vol. 126;
No. 5; 1304-1305; 10.1021/ja038968t
- Iverson, Carl N.; Carter, Charles A. G.; et el. (2003) C−H
Bond Activation by Unsymmetrical 2-(N-Arylimino)pyrrolide Pt Complexes:
Geometric Effects on Reactivity; Journal of the American Chemical
Society; Vol. 125; No. 42; 12674-12675; 10.1021/ja036511d
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C−H Bond Activation and Arene Oxidative Coupling by Cationic
Palladium(II) Complexes; Organometallics; Vol. 22; No. 19;
3884-3890; 10.1021/om0303294
- Heyduk, Alan F.; Labinger, Jay A.; et el. (2003) Catalytic
Alcoholysis of Tetramethylsilane via Pt-Mediated C−H Bond
Activation; Journal of the American Chemical Society; Vol. 125;
No. 21; 6366-6367; 10.1021/ja029099v
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and Theoretical Studies of Olefin Insertion foransa-Niobocene
andansa-Tantalocene Ethylene Hydride Complexes; Organometallics;
Vol. 22; No. 1; 188-194; 10.1021/om0206296
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of ansa-Niobocene and ansa-Tantalocene Olefin Hydride Complexes as
Transition State Analogues in Metallocene-Catalyzed Olefin
Polymerization; Organometallics; Vol. 22; No. 1; 172-187; 10.1021/om020628d
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Electronic Influence of Ring Substituents and Ansa Bridges in
Zirconocene Complexes as Probed by Infrared Spectroscopic,
Electrochemical, and Computational Studies; Journal of the American
Chemical Society; Vol. 124; No. 32; 9525-9546; 10.1021/ja020236y
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and Mechanistic Investigations of the Oxidation of Dimethylplatinum(II)
Complexes by Dioxygen; Inorganic Chemistry; Vol. 41; No. 14;
3608-3619; 10.1021/ic0112903
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and exploiting C–H bond activation; Nature; Vol. 417; No. 6888;
507-514; 10.1038/417507a
- Yoder, Jeffrey C. and Bercaw, John E. (2002) Chain
Epimerization during Propylene Polymerization with Metallocene
Catalysts: Mechanistic Studies Using a Doubly Labeled Propylene;
Journal of the American Chemical Society; Vol. 124; No. 11; 2548-2555;
10.1021/ja0123296
- Miller, Stephen A. and Bercaw, John
- Isotactic−Hemiisotactic
Polypropylene from C_1-Symmetric ansa-Metallocene Catalysts: A New
Strategy for the Synthesis of Elastomeric Polypropylene;
Organometallics; Vol. 21; No. 5; 934-945; 10.1021/om010788+
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Bond Activation by Cationic Platinum(II) Complexes: Ligand Electronic
and Steric Effects; Journal of the American Chemical Society; Vol.
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Ligand and Olefin Substituent Effects on Olefin Dissociation for
Cationic Zirconocene Complexes Bearing a Coordinated Pendant Olefin;
Organometallics; Vol. 20; No. 20; 4253-4261; 10.1021/om010363n
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Stable Dialkylzirconocenes with β-Hydrogens. Synthesis and
Diastereoselectivity; Organometallics; Vol. 20; No. 18; 3891-3895;
10.1021/om0102910
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bond activation mediated by cationic platinum(II) complexes;
Abstracts of Papers of the American Chemical Society; Vol. 221; INOR
83
- Balzarek, Christoph; Labinger, Jay A.; et el. (2001) Chemistry
of water-soluble Pt-diimine complexes relevant to C-H bond
activation; Abstracts of Papers of the American Chemical Society;
Vol. 221; INOR 201
- Scollard, John D.; Labinger, Jay A.; et el. (2001) Studies
towards the functionalization of light alkanes: Facile C-H bond
activation by a neutral Pt(II) alkyl complex; Abstracts of Papers of
the American Chemical Society; Vol. 221; INOR 85
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Research of Relevance to Carbon Management: Progress, Challenges, and
Opportunities; Chemical Reviews; Vol. 101; No. 4; 953-996; 10.1021/cr000018s
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of Singly and Doubly Bridgedansa-Zirconocene Hydrides. Formation of an
Unusual Mixed Valence Trimeric Hydride by Reaction of H_2 with
{(Me_2Si)_2(η^5-C_5H_3)_2}Zr(CH_3)_2and Generation of a Dinitrogen
Complex by Reaction of N_2 with a Zirconocene Dihydride;
Organometallics; Vol. 20; No. 3; 534-544; 10.1021/om000739h
- Miller, Stephen A. and Bercaw, John
- Aminofluorenyl−Pentamethylcyclopentadienyl
and Bis(aminofluorenyl) Derivatives of Group 4 Metals;
Organometallics; Vol. 19; No. 26; 5608-5613; 10.1021/om000723r
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and Mechanistic Studies of Stereocontrol for Ziegler—Natta
Polymerization Utilizing Doubly-Silylene Bridged Group 3 and Group 4
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Rearrangement Processes in Organozirconium Complexes. Observation of
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η^3-Allyl Derivatives of ansa-Scandocenes and an ansa-Yttrocene.
Measurements of the Barriers for the η^3 to η^1 Process as an Indicator
of Olefin Binding Energy to d^0 Metallocenes; Organometallics; Vol.
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Organometallics; Vol. 17; No. 25; 5528-5533; 10.1021/om980505m
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Interconversion for ansa-Scandocene and ansa-Yttrocene Derivatives.
Molecular Structures of
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[meso-{Me_2Si[η^5-C_5H_2-2,4-(CHMe_2)_2]_2}Y(μ_2-Cl)]_2, and
meso-{Me_2Si[η^5-C_5H_2-2,4-(CHMe_2)_2]_2}Zr(NMe_2)_2;
Organometallics; Vol. 17; No. 23; 4946-4958; 10.1021/om980349j
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10.1021/om9709345
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Cationic Imido Complex of Permethyltantalocene: H_2 and Carbon−Hydrogen
Bond Activation, [2 + 2] Cycloaddition Reactions, and an Unusual
Reaction with Carbon Dioxide That Affords Coordinated Isocyanate;
Organometallics; Vol. 17; No. 4; 718-725; 10.1021/om970815p
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[{(η5-C_5Me_4)SiMe_2(η1-NCMe_3)}(PMe_3)Sc(µ_2-H)]_2 and
[{(η5-C_5Me_4)SiMe_2(η1-NCMe_3)}Sc(µ_2-CH_2CH_2CH_3)]_2.
Synthesis, Structures, and Kinetic and Equilibrium Investigations of the
Catalytically Active Species in Solution; Journal of the American
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10.1021/ja00089a053
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Chain Transfer by β-Hydrogen and β-Methyl Elimination for a Model
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alkyls: model reactions for hydrocarbon oxidation with aqueous platinum
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No. 7; 3004-3005; 10.1021/ja00060a070
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1771-1773; 10.1107/S0108270192002038
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platinum chloro (fluoroaryl)phosphine complex; Acta
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permethylcyclopentadienyl carbollide scandium complex,
Sc_2Si_4O_3C_(50)B_(18)Li_2H_(114); Acta Crystallographica Section
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of permethyltantalocenephenylmethanecarbothialdehyde hydride,
(η^5-C_5Me_5)_2Ta(η^2-SCHCH_2C_6H_5)H; Acta Crystallographica
Section C; Vol. 48; No. 6; 1023-1025; 10.1107/S0108270191011927
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and characterization of thioaldehyde hydride derivatives of
permethyltantalocene. Investigations of their equilibration with
thiolates and the stereochemistry of alkyl migrations from sulfur to
tantalum; Organometallics; Vol. 11; No. 6; 2181-2189; 10.1021/om00042a036
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Hydroxylation of Hydrocarbons by Platinum Salts in Aqueous Media Direct
Conversion of Ethanol to Ethylene Glycol; ISBN 9780841220072;
221-232; 10.1021/ba-1992-0230.ch015
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trifluoromethanesulfonate (triflate) and
dihydroxobis(pentamethylcyclopentadienyl)tantalum(V) triflate; Acta
Crystallographica Section C; Vol. 47; No. 10; 2057-2060; 10.1107/S0108270191003323
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of permethylscandocene derivatives with acetylene. Structure of
acetylenediylbis(permethylscandocene),
(η^5-C_5Me_5)_2Sc-C≡C-Sc(η^5-C_5Me_5)_2; Organometallics; Vol. 10;
No. 3; 525-527; 10.1021/om00049a001
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and carbon-carbon bond activation with highly electrophilic transition
metal complexes; Pure and Applied Chemistry; Vol. 62; No. 6;
1151-1154; 10.1351/pac199062061151
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insertion and β-hydrogen elimination for permethylscandocene alkyl
complexes. A study of the chain propagation and termination steps in
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- Bercaw, John E.; Burger, Barbara J.; et el. (1989) A
new mechanism for exchange processes observed in the compounds
[M(η-C_5H_5)_2(exo-η-RCH = CH_2)H], M = Nb and Ta; Journal of the
Chemical Society. Chemical Communications; Vol. 1989; No. 11; 734-736;
10.1039/c39890000734
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protonation of the W–H bonds of Bis(pentamethylcyclopentadienyl)tungsten
dihydride; Journal of the Chemical Society. Chemical Communications;
Vol. 1989; No. 4; 255-257; 10.1039/c39890000255
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Line Techniques for Handling Air-Sensitive Organometallic Compounds;
ISBN 9780841214385; 79-115; 10.1021/bk-1987-0357.ch004
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^(13)C, and ^(15)N Nuclear Magnetic Resonance Studies of a Dinitrogen
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Journal of the Chemical Society D: Chemical Communications; Vol. 1971;
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