Agapie, Theodor

Article from CaltechAUTHORS

• He, Tianyi and Bruening, Meaghan A., el al. (2025) Novel Silicate Platform as Weakly‐Coordinating Anions for Diverse Organometallic and Electrochemical Applications; Angewandte Chemie International Edition; Vol. 64; No. 4; e202417136; 10.1002/anie.202417136
• Ghana, Priyabrata and Xiong, Shuoyan, el al. (2024) Catalyst Editing via Post-Synthetic Functionalization by Phosphonium Generation and Anion Exchange for Nickel-Catalyzed Ethylene/Acrylate Copolymerization; Journal of the American Chemical Society; 10.1021/jacs.4c03416
• Heim, Gavin P. and Hirahara, Masanari, el al. (2024) Synthesis and Electronic Properties of Nitrogen-Rich Nanographene; Chemical Communications; 10.1039/d4cc01189a
• Heim, Gavin P. and Bruening, Meaghan A., el al. (2024) Potassium ion modulation of the Cu electrode-electrolyte interface with ionomers enhances CO₂ reduction to C₂₊ products; Joule; Vol. 8; No. 5; 1312-1321; 10.1016/j.joule.2024.03.019
• Watkins, Nicholas B. and Lai, Yungchieh, el al. (2024) Electrode Surface Heating with Organic Films Improves CO₂ Reduction Kinetics on Copper; ACS Energy Letters; Vol. 9; No. 4; 1440-1445; PMCID PMC11019637; 10.1021/acsenergylett.4c00204
• Xiong, Shuoyan and Spinney, Heather A., el al. (2024) Switchable Synthesis of Ethylene/Acrylate Copolymers by a Dinickel Catalyst: Evidence for Chain Growth on Both Nickel Centers and Concepts of Cation Exchange Polymerization; ACS Catalysis; Vol. 14; No. 7; 5260-5268; 10.1021/acscatal.4c00156
• Le, Linh N. V. and Joyce, Justin P., el al. (2024) Highly Activated Terminal Carbon Monoxide Ligand in an Iron–Sulfur Cluster Model of FeMco with Intermediate Local Spin State at Fe; Journal of the American Chemical Society; Vol. 146; No. 8; 5045-5050; PMCID PMC10910499; 10.1021/jacs.3c12025
• Lionetti, Davide and Suseno, Sandy, el al. (2024) Redox Processes Involving Oxygen: The Surprising Influence of Redox-Inactive Lewis Acids; JACS Au; Vol. 4; No. 2; 344-368; PMCID PMC10900226; 10.1021/jacsau.3c00675
• Aitbekova, Aisulu and Watkins, Nicholas, el al. (2024) Molecular Additives Improve the Selectivity of CO₂ Photoelectrochemical Reduction over Gold Nanoparticles on Gallium Nitride; Nano Letters; Vol. 24; No. 4; 1090-1095; 10.1021/acs.nanolett.3c03590
• Xiong, Shuoyan and Hong, Alexandria, el al. (2023) Acrylate-Induced β-H Elimination in Coordination Insertion Copolymerizaton Catalyzed by Nickel; Journal of the American Chemical Society; Vol. 145; No. 48; 26463-26471; PMCID PMC10704591; 10.1021/jacs.3c10800
• Scott, Anna G. and Alves Galico, Diogo, el al. (2023) High‐Spin and Reactive Fe₁₃ Cluster with Exposed Metal Sites; Angewandte Chemie International Edition; Vol. 62; No. 49; e202313880; PMCID PMC10962695; 10.1002/anie.202313880
• Xiong, Shuoyan and Shoshani, Manar M., el al. (2023) Nickel-Based Heterometallic Catalysts for Ethylene-Acrylate Copolymerization: Interrogating Effects of Secondary Metal Additives; Organometallics; 10.1021/acs.organomet.3c00307
• Shiau, Angela A. and Lee, Heui Beom, el al. (2023) Coordination Number in High-Spin–Low-Spin Equilibrium in Cluster Models of the S₂ State of the Oxygen Evolving Complex; Journal of the American Chemical Society; Vol. 145; No. 27; 14592-14598; PMCID PMC10575483; 10.1021/jacs.3c04464
• Bruening, Meaghan A. and Xiong, Shuoyan, el al. (2023) α,ω-Diene Generation from Ethylene and Butadiene by Copolymer Upcycling; ACS Sustainable Chemistry & Engineering; Vol. 11; No. 27; 9918-9923; 10.1021/acssuschemeng.3c02569
• Watkins, Nicholas B. and Schiffer, Zachary J., el al. (2023) Hydrodynamics Change Tafel Slopes in Electrochemical CO₂ Reduction on Copper; ACS Energy Letters; Vol. 8; No. 5; 2185-2192; 10.1021/acsenergylett.3c00442
• Xiong, Shuoyan and Ghana, Priyabrata, el al. (2023) Impact of Labile Ligands on Catalyst Initiation and Chain Propagation in Ni-Catalyzed Ethylene/Acrylate Copolymerization; ACS Catalysis; Vol. 13; No. 7; 5000-5006; 10.1021/acscatal.3c00627
• Nie, Weixuan and Heim, Gavin P., el al. (2023) Organic Additive-derived Films on Cu Electrodes Promote Electrochemical CO₂ Reduction to C₂₊ Products Under Strongly Acidic Conditions; Angewandte Chemie International Edition; Vol. 62; No. 12; Art. No. e202216102; 10.1002/anie.202216102
• Watkins, Nicholas B. and Wu, Yueshen, el al. (2023) In Situ Deposited Polyaromatic Layer Generates Robust Copper Catalyst for Selective Electrochemical CO₂ Reduction at Variable pH; ACS Energy Letters; Vol. 8; No. 1; 189-195; 10.1021/acsenergylett.2c02002
• Scott, Anna G. and Agapie, Theodor (2023) Synthesis of a Fe₃-Carbyne Motif by Oxidation of an Alkyl Ligated Iron-Sulfur (WFe₃S₃) Cluster; Journal of the American Chemical Society; Vol. 145; No. 1; 2-6; PMCID PMC10575540; 10.1021/jacs.2c04826
• Shoshani, Manar M. and Xiong, Shuoyan, el al. (2022) Phosphine-Phenoxide Nickel Catalysts for Ethylene/Acrylate Copolymerization: Olefin Coordination and Complex Isomerization Studies Relevant to the Mechanism of Catalysis; Organometallics; Vol. 41; No. 15; 2119-2131; 10.1021/acs.organomet.2c00241
• Xiong, Shuoyan and Hong, Alexandria, el al. (2022) Highly Active and Thermally Robust Nickel Enolate Catalysts for the Synthesis of Ethylene‐Acrylate Copolymers; Angewandte Chemie International Edition; 10.1002/anie.202206637
• Shiau, Angela A. and Lee, Heui Beom, el al. (2022) Mnᴵⱽ₄O₄ Model of the S₃ Intermediate of the Oxygen-Evolving Complex: Effect of the Dianionic Disiloxide Ligand; Inorganic Chemistry; 10.1021/acs.inorgchem.2c01612
• Low, Choon Heng and Buss, Joshua A., el al. (2022) Molybdenum-Mediated Coupling of Carbon Monoxide to a C₃ Product on a Single Metal Site; Inorganic Chemistry; Vol. 61; No. 20; 7710-7714; 10.1021/acs.inorgchem.2c00266
• Barluzzi, Luciano and Jori, Nadir, el al. (2022) Heterometallic uranium/molybdenum nitride synthesis via partial N-atom transfer; Chemical Communications; Vol. 58; No. 29; 4655-4658; 10.1039/d2cc00473a
• Lai, Yungchieh and Watkins, Nicholas B., el al. (2022) Molecular Coatings Improve the Selectivity and Durability of CO₂ Reduction Chalcogenide Photocathodes; ACS Energy Letters; Vol. 7; No. 3; 1195-1201; 10.1021/acsenergylett.1c02762
• Arnett, Charles H. and Oyala, Paul H., el al. (2021) Probing Redox Non-Innocence in Iron–Carbene Complexes {Fe=C(H)Ar}¹⁰⁻¹¹ by ^(1,2)H and ¹³C Pulse Electron Paramagnetic Resonance; Angewandte Chemie International Edition; Vol. 60; No. 52; 27220-27224; 10.1002/anie.202110704
• Le, Linh N. V. and Bailey, Gwendolyn A., el al. (2021) Partial synthetic models of FeMoco with sulfide and carbyne ligands: Effect of interstitial atom in nitrogenase active site; Proceedings of the National Academy of Sciences of the United States of America; Vol. 118; No. 49; Art. No. e2109241118; PMCID PMC8670491; 10.1073/pnas.2109241118
• Buss, Joshua A. and Shida, Naoki, el al. (2021) Carbon Dioxide Reduction with Dihydrogen and Silanes at Low-Valent Molybdenum Terphenyl Diphosphine Complexes: Reductant Identity Dictates Mechanism; ACS Catalysis; Vol. 11; No. 21; 13294-13302; 10.1021/acscatal.1c02922
• Lai, Yunchieh and Watkins, Nicholas B., el al. (2021) Breaking Scaling Relationships in CO₂ Reduction on Copper Alloys with Organic Additives; ACS Central Science; Vol. 7; No. 10; 1756-1762; PMCID PMC8554824; 10.1021/acscentsci.1c00860
• Yadegari, Hossein and Ozden, Adnan, el al. (2021) Glycerol Oxidation Pairs with Carbon Monoxide Reduction for Low-Voltage Generation of C₂ and C₃ Product Streams; ACS Energy Letters; Vol. 6; No. 10; 3538-3544; 10.1021/acsenergylett.1c01639
• Bailey, Gwendolyn A. and Buss, Joshua A., el al. (2021) Terminal, Open-Shell Mo Carbide and Carbyne Complexes: Spin Delocalization and Ligand Noninnocence; Journal of the American Chemical Society; Vol. 143; No. 33; 13091-13102; 10.1021/jacs.1c03806
• Bailey, Gwendolyn A. and Agapie, Theodor (2021) Terminal Mo Carbide and Carbyne Reactivity: H₂ Cleavage, B–C Bond Activation, and C–C Coupling; Organometallics; Vol. 40; No. 16; 2881-2887; 10.1021/acs.organomet.1c00336
• Lee, Heui Beom and Shiau, Angela A., el al. (2021) CaMn₃^(IV)O₄ Cubane Models of the Oxygen Evolving Complex: Spin Ground States S < 9/2 and the Effect of Oxo Protonation; Angewandte Chemie International Edition; Vol. 60; No. 32; 17671-17679; PMCID PMC8319083; 10.1002/anie.202105303
• Sampson, Jessica and Bruening, Meaghan, el al. (2021) Copolymerization of Ethylene and Long-Chain Functional α-Olefins by Dinuclear Zirconium Catalysts; Organometallics; Vol. 40; No. 12; 1854-1858; 10.1021/acs.organomet.1c00126
• Xiong, Shuoyan and Shoshani, Manar M., el al. (2021) Efficient Copolymerization of Acrylate and Ethylene with Neutral P, O-Chelated Nickel Catalysts: Mechanistic Investigations of Monomer Insertion and Chelate Formation; Journal of the American Chemical Society; Vol. 143; No. 17; 6516-6527; 10.1021/jacs.1c00566
• Thevenon, Arnaud and Rosas-Hernández, Alonso, el al. (2021) Dramatic HER Suppression on Ag Electrodes via Molecular Films for Highly Selective CO₂ to CO Reduction; ACS Catalysis; Vol. 11; No. 8; 4530-4537; 10.1021/acscatal.1c00338
• Ozden, Adnan and Wang, Yuhang, el al. (2021) Cascade CO₂ electroreduction enables efficient carbonate-free production of ethylene; Joule; Vol. 5; No. 3; 706-719; 10.1016/j.joule.2021.01.007
• Hirscher, Nathanael A. and Arnett, Charles H., el al. (2020) Characterization of Cr-Hydrocarbyl Species via Pulse EPR in the Study of Ethylene Tetramerization Catalysis; Organometallics; Vol. 39; No. 24; 4420-4429; 10.1021/acs.organomet.0c00521
• Ribson, Ryan D. and Choi, Gyeongshin, el al. (2020) Controlling Singlet Fission with Coordination Chemistry-Induced Assembly of Dipyridyl Pyrrole Bipentacenes; ACS Central Science; Vol. 6; No. 11; 2088-2096; PMCID PMC7706079; 10.1021/acscentsci.0c01044
• Arnett, Charles H. and Bogacz, Isabel, el al. (2020) Mixed-Valent Diiron µ-Carbyne, µ-Hydride Complexes: Implications for Nitrogenase; Journal of the American Chemical Society; Vol. 142; No. 44; 18795-18813; 10.1021/jacs.0c05920
• Shoshani, Manar M. and Agapie, Theodor (2020) Ligand architecture for triangular metal complexes: a high oxidation state Ni₃ cluster with proximal metal arrangement; Chemical Communications; Vol. 56; No. 76; 11279-11282; 10.1039/d0cc03816d
• Ozden, Adnan and Li, Fengwang, el al. (2020) High-Rate and Efficient Ethylene Electrosynthesis Using a Catalyst/Promoter/Transport Layer; ACS Energy Letters; Vol. 5; No. 9; 2811-2818; 10.1021/acsenergylett.0c01266
• Wan, Ruomeng and Buss, Joshua A., el al. (2020) A Hemilabile Diphosphine Pyridine Pincer Ligand: σ- and π-Binding in Molybdenum Coordination Complexes; Polyhedron; Vol. 187; Art. No. 114631; 10.1016/j.poly.2020.114631
• Arnett, Charles H. and Agapie, Theodor (2020) Activation of an Open Shell, Carbyne-Bridged Diiron Complex Toward Binding of Dinitrogen; Journal of the American Chemical Society; Vol. 142; No. 22; 10059-10068; 10.1021/jacs.0c01896
• Nam, Dae-Hyun and De Luna, Phil, el al. (2020) Molecular enhancement of heterogeneous CO₂ reduction; Nature Materials; Vol. 19; No. 3; 266-276; 10.1038/s41563-020-0610-2
• Lee, Heui Beom and Marchiori, David A., el al. (2020) S = 3 Ground State for a Tetranuclear Mn^(IV)₄O₄ Complex Mimicking the S₃ State of the Oxygen Evolving Complex; Journal of the American Chemical Society; Vol. 142; No. 8; 3753-3761; PMCID PMC7236085; 10.1021/jacs.9b10371
• Li, Fengwang and Thevenon, Arnaud, el al. (2020) Molecular tuning of CO₂-to-ethylene conversion; Nature; Vol. 577; No. 7791; 509-513; 10.1038/s41586-019-1782-2
• Arnett, Charles H. and Kaiser, Jens T., el al. (2019) Remote Ligand Modifications Tune Electronic Distribution and Reactivity in Site-Differentiated, High-Spin Iron Clusters: Flipping Scaling Relationships; Inorganic Chemistry; Vol. 58; No. 23; 15971-15982; 10.1021/acs.inorgchem.9b02470
• Mathe, Zachary and Pantazis, Dimitrios A., el al. (2019) Calcium Valence-to-Core X-ray Emission Spectroscopy: A Sensitive Probe of Oxo Protonation in Structural Models of the Oxygen-Evolving Complex; Inorganic Chemistry; Vol. 58; No. 23; 16292-16301; PMCID PMC6891804; 10.1021/acs.inorgchem.9b02866
• Thevenon, Arnaud and Rosas-Hernández, Alonso, el al. (2019) In-situ Nanostructuring and Stabilization of Polycrystalline Copper by an Organic Salt Additive Promotes Electrocatalytic CO₂ Reduction to Ethylene; Angewandte Chemie International Edition; Vol. 58; No. 47; 16952-16958; 10.1002/anie.201907935
• Lee, Heui Beom and Agapie, Theodor (2019) Redox Tuning via Ligand-Induced Geometric Distortions at a YMn₃O₄ Cubane Model of the Biological Oxygen Evolving Complex; Inorganic Chemistry; Vol. 58; No. 22; 14998-15003; PMCID PMC6876925; 10.1021/acs.inorgchem.9b00510
• Buss, Joshua A. and Bailey, Gwendolyn A., el al. (2019) CO Coupling Chemistry of a Terminal Mo Carbide: Sequential Addition of Proton, Hydride, and CO Releases Ethenone; Journal of the American Chemical Society; Vol. 141; No. 39; 15664-15674; 10.1021/jacs.9b07743
• Sampson, Jessica and Choi, Gyeongshin, el al. (2019) Early Metal Di(pyridyl) Pyrrolide Complexes with Second Coordination Sphere Arene−π Interactions: Ligand Binding and Ethylene Polymerization; ACS Omega; Vol. 4; No. 14; 15879-15892; PMCID PMC6776977; 10.1021/acsomega.9b01788
• Reed, Christopher J. and Agapie, Theodor (2019) A Terminal Fe^(III)-Oxo in a Tetranuclear Cluster: Effects of Distal Metal Centers on Structure and Reactivity; Journal of the American Chemical Society; Vol. 141; No. 24; 9479-9484; PMCID PMC7207158; 10.1021/jacs.9b03157
• Hirscher, Nathanael A. and Perez Sierra, Danny, el al. (2019) Robust Chromium Precursors for Catalysis: Isolation and Structure of a Single-Component Ethylene Tetramerization Precatalyst; Journal of the American Chemical Society; Vol. 141; No. 14; 6022-6029; PMCID PMC7025812; 10.1021/jacs.9b01387
• Lionetti, Davide and Suseno, Sandy, el al. (2019) Effects of Lewis Acidic Metal Ions (M) on Oxygen-Atom Transfer Reactivity of Heterometallic Mn₃MO₄ Cubane and Fe₃MO(OH) and Mn₃MO(OH) Clusters; Inorganic Chemistry; Vol. 58; No. 4; 2336-2345; PMCID PMC6574207; 10.1021/acs.inorgchem.8b02701
• Hirscher, Nathanael A. and Labinger, Jay A., el al. (2019) Isotopic labelling in ethylene oligomerization: addressing the issue of 1-octene vs. 1-hexene selectivity; Dalton Transactions; Vol. 48; No. 1; 40-44; 10.1039/c8dt04509g
• Lee, Heui Beom and Shiau, Angela A., el al. (2018) Tetranuclear [Mn^(III)Mn_3^(IV)O_4] Complexes as Spectroscopic Models of the S_2 State of the Oxygen Evolving Complex in Photosystem II; Journal of the American Chemical Society; Vol. 140; No. 49; 17175-17187; PMCID PMC6574184; 10.1021/jacs.8b09961
• Buss, Joshua A. and Hirahara, Masanari, el al. (2018) Molecular Mimics of Heterogeneous Metal Phosphides: Thermochemistry, Hydride‐Proton Isomerism, and HER Reactivity; Angewandte Chemie International Edition; Vol. 57; No. 50; 16329-16333; 10.1002/anie.201808307
• Low, Choon Heng and Rosenberg, Jeffrey N., el al. (2018) Oxidative Coupling with Zr(IV) Supported by a Noninnocent Anthracene-Based Ligand: Application to the Catalytic Cotrimerization of Alkynes and Nitriles to Pyrimidines; Journal of the American Chemical Society; Vol. 140; No. 38; 11906-11910; PMCID PMC7282345; 10.1021/jacs.8b07418
• Reed, Christopher J. and Agapie, Theodor (2018) Thermodynamics of Proton and Electron Transfer in Tetranuclear Clusters with Mn–OH₂/OH Motifs Relevant to H₂O Activation by the Oxygen Evolving Complex in Photosystem II; Journal of the American Chemical Society; Vol. 140; No. 34; 10900-10908; PMCID PMC6277146; 10.1021/jacs.8b06426
• Buss, Joshua A. and VanderVelde, David G., el al. (2018) Lewis Acid Enhancement of Proton Induced CO_2 Cleavage: Bond Weakening and Ligand Residence Time Effects; Journal of the American Chemical Society; Vol. 140; No. 32; 10121-10125; 10.1021/jacs.8b05874
• Buss, Joshua A. and Cheng, Christine, el al. (2018) A Low-Valent Molybdenum Nitride Complex: Reduction Promotes Carbonylation Chemistry; Angewandte Chemie International Edition; Vol. 57; No. 31; 9670-9674; 10.1002/anie.201803728
• Arnett, Charles H. and Chalkley, Matthew J., el al. (2018) A Thermodynamic Model for Redox-Dependent Binding of Carbon Monoxide at Site-Differentiated, High Spin Iron Clusters; Journal of the American Chemical Society; Vol. 140; No. 16; 5569-5578; PMCID PMC6452638; 10.1021/jacs.8b01825
• Shida, Naoki and Buss, Joshua A., el al. (2018) Mild electrochemical synthesis of metal phosphides with dibenzo-7-phosphanorbornadiene derivatives: mechanistic insights and application to proton reduction in water; Chemical Communications; Vol. 54; No. 7; 767-770; 10.1039/c7cc09003j
• Buss, Joshua A. and Oyala, Paul H., el al. (2017) Terminal Molybdenum Phosphides with d Electrons: Radical Character Promotes Coupling Chemistry; Angewandte Chemie International Edition; Vol. 56; No. 46; 14502-14506; 10.1002/anie.201707921
• Hirscher, Nathanael A. and Agapie, Theodor (2017) Stoichiometrically Activated Catalysts for Ethylene Tetramerization using Diphosphinoamine-Ligated Cr Tris(hydrocarbyl) Complexes; Organometallics; Vol. 36; No. 21; 4107-4110; 10.1021/acs.organomet.7b00706
• Reed, Christopher J. and Agapie, Theodor (2017) Tetranuclear Fe Clusters with a Varied Interstitial Ligand: Effects on the Structure, Redox Properties, and Nitric Oxide Activation; Inorganic Chemistry; Vol. 56; No. 21; 13360-13367; PMCID PMC6277142; 10.1021/acs.inorgchem.7b02114
• Kubin, Markus and Kanady, Jacob S., el al. (2017) Soft x-ray absorption spectroscopy of metalloproteins and high-valent metal-complexes at room temperature using free-electron lasers; Structural Dynamics; Vol. 4; No. 5; Art. No. 054307; PMCID PMC5586166; 10.1063/1.4986627
• Han, Zhiji and Kortlever, Ruud, el al. (2017) CO_2 Reduction Selective for C_(≥2) Products on Polycrystalline Copper with N-Substituted Pyridinium Additives; ACS Central Science; Vol. 3; No. 8; 853-859; PMCID PMC5571460; 10.1021/acscentsci.7b00180
• De Ruiter, Graham and Carsch, Kurtis M., el al. (2017) Selectivity of C−H vs. C−F Bond Oxygenation by Homo- and Heterometallic Fe_4, Fe_3Mn, and Mn_4 Clusters; Chemistry: a European Journal; Vol. 23; No. 45; 10744-10748; PMCID PMC5659184; 10.1002/chem.201702302
• Carsch, Kurtis M. and De Ruiter, Graham, el al. (2017) Intramolecular C–H and C–F Bond Oxygenation by Site-Differentiated Tetranuclear Manganese Models of the OEC; Inorganic Chemistry; Vol. 56; No. 15; 9044-9054; PMCID PMC5669799; 10.1021/acs.inorgchem.7b01022
• Han, Zhiji and Horak, Kyle T., el al. (2017) Tetranuclear Manganese Models of the OEC Displaying Hydrogen Bonding Interactions: Application to Electrocatalytic Water Oxidation to Hydrogen Peroxide; Journal of the American Chemical Society; Vol. 139; No. 27; 9108-9111; PMCID PMC5643074; 10.1021/jacs.7b03044
• Lee, Heui Beom and Tsui, Emily Y., el al. (2017) A CaMn₄O₂ model of the biological oxygen evolving complex: synthesis via cluster expansion on a low symmetry ligand; Chemical Communications; Vol. 53; No. 51; 6832-6835; PMCID PMC5508601; 10.1039/c7cc02313h
• Sampson, Jessica and Choi, Gyeongshin, el al. (2017) Olefin Polymerization by Dinuclear Zirconium Catalysts Based on Rigid Teraryl Frameworks: Effects on Tacticity and Copolymerization Behavior; Organometallics; Vol. 36; No. 10; 1915-1928; 10.1021/acs.organomet.7b00015
• Lifschitz, Alejo M. and Hirscher, Nathanael A., el al. (2017) Ethylene Tetramerization Catalysis: Effects of Aluminum-Induced Isomerization of PNP to PPN Ligands; Organometallics; Vol. 36; No. 8; 1640-1648; 10.1021/acs.organomet.7b00189
• De Ruiter, Graham and Carsch, Kurtis M., el al. (2017) Accelerated Oxygen Atom Transfer and C−H Bond Oxygenation by Remote Redox Changes in Fe_3Mn-Iodosobenzene Adducts; Angewandte Chemie International Edition; Vol. 56; No. 17; 4772-4776; PMCID PMC5505263; 10.1002/anie.201701319
• Jung, Suho and Kortlever, Ruud, el al. (2017) Gastight Hydrodynamic Electrochemistry: Design for a Hermetically Sealed Rotating Disk Electrode Cell; Analytical Chemistry; Vol. 89; No. 1; 581-585; 10.1021/acs.analchem.6b04228
• Buss, Joshua A. and Agapie, Theodor (2016) Mechanism of Molybdenum-Mediated Carbon Monoxide Deoxygenation and Coupling: Mono- and Dicarbyne Complexes Precede C–O Bond Cleavage and C–C Bond Formation; Journal of the American Chemical Society; Vol. 138; No. 50; 16466-16477; 10.1021/jacs.6b10535
• Kelley, Paul and Edouard, Guy A., el al. (2016) Lewis Acid Accelerated Aryl Ether Bond Cleavage with Nickel: Orders of Magnitude Rate Enhancement Using AlMe_3; Chemistry: a European Journal; Vol. 22; No. 48; 17173-17176; 10.1002/chem.201604160
• Lin, Po-Heng and Tsui, Emily Y., el al. (2016) Effect of the Mn Oxidation State on Single-Molecule-Magnet Properties: Mnᴵᴵᴵ vs Mnᴵⱽ in Biologically Inspired DyMn₃O₄ Cubanes; Inorganic Chemistry; Vol. 55; No. 12; 6095-6099; PMCID PMC5510600; 10.1021/acs.inorgchem.6b00630
• Henthorn, Justin T. and Agapie, Theodor (2016) Modulation of Proton-Coupled Electron Transfer through Molybdenum–Quinonoid Interactions; Inorganic Chemistry; Vol. 55; No. 11; 5337-5342; 10.1021/acs.inorgchem.6b00331
• Lionetti, Davide and De Ruiter, Graham, el al. (2016) A trans-Hyponitrite Intermediate in the Reductive Coupling and Deoxygenation of Nitric Oxide by a Tricopper–Lewis Acid Complex; Journal of the American Chemical Society; Vol. 138; No. 15; 5008-5011; 10.1021/jacs.6b01083
• Horak, Kyle T. and Agapie, Theodor (2016) Dioxygen Reduction by a Pd(0)–Hydroquinone Diphosphine Complex; Journal of the American Chemical Society; Vol. 138; No. 10; 3443-3452; 10.1021/jacs.5b12928
• De Ruiter, Graham and Thompson, Niklas B., el al. (2016) Intramolecular C–H and C–F Bond Oxygenation Mediated by a Putative Terminal Oxo Species in Tetranuclear Iron Complexes; Journal of the American Chemical Society; Vol. 138; No. 5; 1486-1489; PMCID PMC4871154; 10.1021/jacs.5b12214
• Buss, Joshua A. and Agapie, Theodor (2016) Four-electron deoxygenative reductive coupling of carbon monoxide at a single metal site; Nature; Vol. 592; No. 7584; 72-75; 10.1038/nature16154
• De Ruiter, Graham and Thompson, Niklas B., el al. (2015) Nitric Oxide Activation by Distal Redox Modulation in Tetranuclear Iron Nitrosyl Complexes; Journal of the American Chemical Society; Vol. 137; No. 44; 14094-14106; PMCID PMC4871614; 10.1021/jacs.5b07397
• Edouard, Guy A. and Kelley, Paul, el al. (2015) Aryl Ether Cleavage by Group 9 and 10 Transition Metals: Stoichiometric Studies of Selectivity and Mechanism; Organometallics; Vol. 34; No. 21; 5254-5277; 10.1021/acs.organomet.5b00710
• Horak, Kyle T. and VanderVelde, David G., el al. (2015) Tuning of Metal Complex Electronics and Reactivity by Remote Lewis Acid Binding to π-Coordinated Pyridine Diphosphine Ligands; Organometallics; Vol. 34; No. 19; 4753-4765; 10.1021/acs.organomet.5b00562
• Horak, Kyle T. and Lin, Sibo, el al. (2015) Heterometallic Effects in Trinuclear Complexes Supported by p-Terphenyl Diphosphine Ligands; Organometallics; Vol. 34; No. 18; 4429-4432; 10.1021/acs.organomet.5b00579
• Suseno, Sandy and McCrory, Charles C. L., el al. (2015) Molecular Mixed-Metal Manganese Oxido Cubanes as Precursors to Heterogeneous Oxygen Evolution Catalysts; Chemistry: a European Journal; Vol. 21; No. 38; 13420-13430; PMCID PMC4868073; 10.1002/chem.201501104
• Agapie, Theodor (2015) Synthetic cluster models of the biological oxygen evolving catalyst from photosystem II; Abstracts of Papers of the American Chemical Society; Vol. 249; INOR-423
• Henthorn, Justin T. and Lin, Sibo, el al. (2015) Combination of Redox-Active Ligand and Lewis Acid for Dioxygen Reduction with π-Bound Molybdenum−Quinonoid Complexes; Journal of the American Chemical Society; Vol. 137; No. 4; 1458-1464; 10.1021/ja5100405
• Lin, Po-Heng and Takase, Michael K., el al. (2015) Investigations of the Effect of the Non-Manganese Metal in Heterometallic-Oxido Cluster Models of the Oxygen Evolving Complex of Photosystem II: Lanthanides as Substitutes for Calcium; Inorganic Chemistry; Vol. 54; No. 1; 59-64; PMCID PMC4286168; 10.1021/ic5015219
• Tsui, Emily Y. and Agapie, Theodor (2014) Carbon dioxide cleavage by a Ni_2 complex supported by a binucleating bis(N-heterocyclic carbene) framework; Polyhedron; Vol. 84; 103-110; PMCID PMC6214461; 10.1016/j.poly.2014.06.041
• Martin-Diaconescu, Vlad and Gennari, Marcello, el al. (2014) Ca K‑Edge XAS as a Probe of Calcium Centers in Complex Systems; Inorganic Chemistry; Vol. 54; No. 4; 1283-1292; PMCID PMC4331723; 10.1021/ic501991e
• Henthorn, Justin T. and Agapie, Theodor (2014) Dioxygen Reactivity with a Ferrocene–Lewis Acid Pairing: Reduction to a Boron Peroxide in the Presence of Tris(pentafluorophenyl)borane; Angewandte Chemie International Edition; Vol. 53; No. 47; 12893-12896; 10.1002/anie.201408462
• Kanady, Jacob S. and Lin, Po-Heng, el al. (2014) Toward Models for the Full Oxygen-Evolving Complex of Photosystem II by Ligand Coordination To Lower the Symmetry of the Mn_3CaO_4 Cubane: Demonstration That Electronic Effects Facilitate Binding of a Fifth Metal; Journal of the American Chemical Society; Vol. 136; No. 41; 14373-14376; PMCID PMC4210109; 10.1021/ja508160x
• Lionetti, Davide and Agapie, Theodor (2014) How calcium affects oxygen formation; Nature; Vol. 513; No. 7519; 495-496; PMCID PMC4879831; 10.1038/nature13753
• Buss, Joshua A. and Edouard, Guy A., el al. (2014) Molybdenum Catalyzed Ammonia Borane Dehydrogenation: Oxidation State Specific Mechanisms; Journal of the American Chemical Society; Vol. 136; No. 32; 11272-11275; PMCID PMC4140452; 10.1021/ja5059923
• Kanady, Jacob S. and Lin, Po-Heng, el al. (2014) Synthetic strategies towards a Mn4CaOn model complex of the oxygen-evolving complex of photosystem II; Abstracts of Papers of the American Chemical Society; Vol. 248; 989-INOR
• Radlauer, Madalyn R. and Agapie, Theodor (2014) Bimetallic Zirconium Amine Bis(phenolate) Polymerization Catalysts: Enhanced Activity and Tacticity Control for Polyolefin Synthesis; Organometallics; Vol. 33; No. 13; 3247-3250; PMCID PMC4216186; 10.1021/om500608j
• Agapie, Theodor (2014) Synthesis and properties of heterometallic cluster models of biological and heterogeneous water oxidation catalysts; Abstracts of Papers of the American Chemical Society; Vol. 247; 519-INOR
• Horak, Kyle T. and Velian, Alexandra, el al. (2014) Arene non-innocence in dinuclear complexes of Fe, Co, and Ni supported by a para-terphenyl diphosphine; Chemical Communications; Vol. 50; No. 34; 4427-4429; 10.1039/C4CC00838C
• Martin-Diaconescu, V. and Serena, D., el al. (2014) Application of X-ray Absorption (XAS) and Emission (XES) Spectroscopies to the Calcium Centers of PSII Oxygen Evolving Complex Structural Analogs; Journal of Biological Inorganic Chemistry; Vol. 19; No. S1; S498; 10.1007/s00775-014-1095-8
• Herbert, David E. and Lionetti, Davide, el al. (2013) Heterometallic Triiron-Oxo/Hydroxo Clusters: Effect of Redox-Inactive Metals; Journal of the American Chemical Society; Vol. 135; No. 51; 19075-19078; PMCID PMC3953215; 10.1021/ja4104974
• Tsui, Emily Y. and Kanady, Jacob S., el al. (2013) Synthetic Cluster Models of Biological and Heterogeneous Manganese Catalysts for O_2 Evolution; Inorganic Chemistry; Vol. 52; No. 24; 13833-13848; PMCID PMC3917504; 10.1021/ic402236f
• Suseno, Sandy and Horak, Kyle T., el al. (2013) Trinuclear Nickel Complexes with Metal–Arene Interactions Supported by Tris- and Bis(phosphinoaryl)benzene Frameworks; Organometallics; Vol. 32; No. 23; 6883-6886; PMCID PMC3920585; 10.1021/om400976x
• Herbert, David E. and Lara, Nadia C., el al. (2013) Arene C-H Amination at Nickel in Terphenyl–Diphosphine Complexes with Labile Metal–Arene Interactions; Chemistry-A European Journal; Vol. 19; No. 48; 16453-16460; PMCID PMC3897266; 10.1002/chem.201302539
• Lin, Sibo and Herbert, David E., el al. (2013) Dipalladium(I) Terphenyl Diphosphine Complexes as Models for Two-Site Adsorption and Activation of Organic Molecules; Journal of the American Chemical Society; Vol. 135; No. 42; 15830-15840; PMCID PMC3851319; 10.1021/ja406696k
• Kanady, Jacob S. and Tran, Rosalie, el al. (2013) Role of oxido incorporation and ligand lability in expanding redox accessibility of structurally related Mn4 clusters; Chemical Science; Vol. 4; No. 10; 3986-3996; PMCID PMC3806640; 10.1039/C3SC51406D
• Kelley, Paul and Day, Michael W., el al. (2013) Hydrogen Evolution Catalyzed by Aluminum-Bridged Cobalt Diglyoximate Complexes; European Journal of Inorganic Chemistry; Vol. 2013; No. 22-23; 3840-3845; 10.1002/ejic.201300309
• Tsui, Emily Y. and Agapie, Theodor (2013) Reduction potentials of heterometallic manganese-oxido cubane complexes modulated by redox-inactive metals; Proceedings of the National Academy of Sciences of the United States of America; Vol. 110; No. 25; 10084-10088; PMCID PMC3690856; 10.1073/pnas.1302677110
• Suseno, Sandy and Agapie, Theodor (2013) Intramolecular Arene C−H to C−P Functionalization Mediated by Nickel(II) and Palladium(II); Organometallics; Vol. 32; No. 11; 3161-3164; PMCID PMC3811949; 10.1021/om400424a
• Tsui, Emily Y. and Tran, Rosalie, el al. (2013) Redox-inactive metals modulate the reduction potential in heterometallic manganese–oxido clusters; Nature Chemistry; Vol. 5; No. 4; 293-299; PMCID PMC3654670; 10.1038/NCHEM.1578
• Radlauer, Madalyn R. and Buckley, Aya K., el al. (2013) Bimetallic Coordination Insertion Polymerization of Unprotected Polar Monomers: Copolymerization of Amino Olefins and Ethylene by Dinickel Bisphenoxyiminato Catalysts; Journal of the American Chemical Society; Vol. 135; No. 10; 3784-3787; 10.1021/ja4004816
• Kanady, Jacob S. and Mendoza-Cortés, José L., el al. (2013) Oxygen Atom Transfer and Oxidative Water Incorporation in Cuboidal Mn_(3)MO_n Complexes Based on Synthetic, Isotopic Labeling, and Computational Studies; Journal of the American Chemical Society; Vol. 135; No. 3; 1073-1082; 10.1021/ja310022p
• Lionetti, Davide and Day, Michael W., el al. (2013) Metal-templated ligand architectures for trinuclear chemistry: tricopper complexes and their O_2 reactivity; Chemical Science; Vol. 4; No. 2; 785-790; PMCID PMC3607385; 10.1039/c2sc21758a
• Mindiola, Daniel J. and Arnold, John, el al. (2012) New talent: Americas; Dalton Transactions; Vol. 41; No. 26; 7781-7781; 10.1039/c2dt90087d
• Kelley, Paul and Radlauer, Madalyn R., el al. (2012) Metallomacrocycles as ligands: synthesis and characterisation of aluminium-bridged bisglyoximato complexes of palladium and iron; Dalton Transactions; Vol. 41; No. 26; 8086-8092; 10.1039/c2dt30285c
• Kelley, Paul and Lin, Sibo, el al. (2012) Nickel-Mediated Hydrogenolysis of C–O Bonds of Aryl Ethers: What Is the Source of the Hydrogen?; Journal of the American Chemical Society; Vol. 134; No. 12; 5480-5483; PMCID PMC3340012; 10.1021/ja300326t
• Radlauer, Madalyn R. and Day, Michael W., el al. (2012) Dinickel Bisphenoxyiminato Complexes for the Polymerization of Ethylene and α-Olefins; Organometallics; Vol. 31; No. 6; 2231-2243; PMCID PMC3375993; 10.1021/om2011694
• Tonks, Ian A. and Tofan, Daniel, el al. (2012) Zirconium and Titanium Propylene Polymerization Precatalysts Supported by a Fluxional C_2-Symmetric Bis(anilide)pyridine Ligand; Organometallics; Vol. 31; No. 5; 1965-1974; 10.1021/om201262h
• Radlauer, Madalyn R. and Day, Michael W., el al. (2012) Bimetallic Effects on Ethylene Polymerization in the Presence of Amines: Inhibition of the Deactivation by Lewis Bases; Journal of the American Chemical Society; Vol. 134; No. 3; 1478-1481; PMCID PMC3307529; 10.1021/ja210990t
• Whited, Charlotte A. and Warren, Jeffrey J., el al. (2012) Gating NO Release from Nitric Oxide Synthase; Journal of the American Chemical Society; Vol. 134; No. 1; 27-30; PMCID PMC3257399; 10.1021/ja2069533
• Chao, Steven T. and Lara, Nadia C., el al. (2011) Reversible Halide-Modulated Nickel–Nickel Bond Cleavage: Metal–Metal Bonds as Design Elements for Molecular Devices; Angewandte Chemie International Edition; Vol. 50; No. 33; 7529-7532; PMCID PMC3805114; 10.1002/anie.201102797
• Kanady, Jacob S. and Tsui, Emily Y., el al. (2011) A Synthetic Model of the Mn_3Ca Subsite of the Oxygen-Evolving Complex in Photosystem II; Science; Vol. 333; No. 6043; 733-736; 10.1126/science.1206036
• Agapie, Theodor (2011) Selective ethylene oligomerization: Recent advances in chromium catalysis and mechanistic investigations; Coordination Chemistry Reviews; Vol. 255; No. 7-8; 861-880; 10.1016/j.ccr.2010.11.035
• Lin, Sibo and Day, Michael W., el al. (2011) Nickel Hydrides Supported by a Non-Innocent Diphosphine Arene Pincer: Mechanistic Studies of Nickel−Arene H-Migration and Partial Arene Hydrogenation; Journal of the American Chemical Society; Vol. 133; No. 11; 3828-3831; PMCID PMC3060299; 10.1021/ja200368y
• Tsui, Emily Y. and Day, Michael W., el al. (2011) Trinucleating Copper: Synthesis and Magnetostructural Characterization of Complexes Supported by a Hexapyridyl 1,3,5-Triarylbenzene Ligand; Angewandte Chemie International Edition; Vol. 50; No. 7; 1668-1672; 10.1002/anie.201005232
• Lin, Sibo and Agapie, Theodor (2011) Cross-Coupling Chemistry at Mononuclear and Dinuclear Nickel Complexes; Synlett; Vol. 2011; No. 1; 1-5; 10.1055/s-0030-1259093
• Tsui, Emily Y. and Kanady, Jacob S., el al. (2011) Trinuclear first row transition metal complexes of a hexapyridyl, trialkoxy 1,3,5-triarylbenzene ligand; Chemical Communications; Vol. 47; No. 14; 4189-4191; 10.1039/c0cc05608a
• Velian, Alexandra and Lin, Sibo, el al. (2010) Synthesis and C−C Coupling Reactivity of a Dinuclear Ni^I−Ni^I Complex Supported by a Terphenyl Diphosphine; Journal of the American Chemical Society; Vol. 132; No. 18; 6296-6297; 10.1021/ja101699a
• Agapie, Theodor and Henling, Lawrence M., el al. (2008) Zirconium and titanium complexes supported by tridentate LX2 ligands having two phenolates linked to furan, thiophene, and pyridine donors: precatalysts for propylene polymerization and oligomerization; Organometallics; Vol. 27; No. 23; 6245-6256; 10.1021/om800136y
• Agapie, Theodor and Day, Michael W., el al. (2008) Synthesis and reactivity of tantalum complexes supported by bidentate X2 and tridentate LX2 ligands with two phenolates linked to pyridine, thiophene, furan, and benzene connectors: mechanistic studies of the formation of a tantalum benzylidene and insertion chemistry for tantalum-carbon bonds; Organometallics; Vol. 27; No. 23; 6123-6142; 10.1021/om8002653
• Agapie, Theodor and Labinger, Jay A., el al. (2007) Mechanistic Studies of Olefin and Alkyne Trimerization with Chromium Catalysts: Deuterium Labeling and Studies of Regiochemistry Using a Model Chromacyclopentane Complex; Journal of the American Chemical Society; Vol. 129; No. 46; 14281-14295; 10.1021/ja073493h
• Agapie, Theodor and Bercaw, John E. (2007) Cyclometalated Tantalum Diphenolate Pincer Complexes: Intramolecular C−H/M−CH_3σ-Bond Metathesis May Be Faster than O−H/M−CH_3 Protonolysis; Organometallics; Vol. 26; No. 12; 2957-2959; 10.1021/om700284c
• Marinescu, Smaranda C. and Agapie, Theodor, el al. (2007) Group 3 Dialkyl Complexes with Tetradentate (L, L, N, O; L = N, O, S) Monoanionic Ligands: Synthesis and Reactivity; Organometallics; Vol. 26; No. 5; 1178-1190; 10.1021/om0608612
• Agapie, Theodor and Day, Michael W., el al. (2006) A Chromium-Diphosphine System for Catalytic Ethylene Trimerization: Synthetic and Structural Studies of Chromium Complexes with a Nitrogen-Bridged Diphosphine Ligand with ortho-Methoxyaryl Substituents; Organometallics; Vol. 25; No. 11; 2733-2742; 10.1021/om050605+
• Agapie, Theodor and Schofer, Susan J., el al. (2004) Mechanistic Studies of the Ethylene Trimerization Reaction with Chromium−Diphosphine Catalysts: Experimental Evidence for a Mechanism Involving Metallacyclic Intermediates; Journal of the American Chemical Society; Vol. 126; No. 5; 1304-1305; 10.1021/ja038968t
• Agapie, Theodor and Diaconescu, Paula L., el al. (2002) Radical Scission of Symmetrical 1,4-Dicarbonyl Compounds:  C−C Bond Cleavage with Titanium(IV) Enolate Formation and Related Reactions; Organometallics; Vol. 21; No. 7; 1329-1340; 10.1021/om0107284
• Agapie, Theodor and Diaconescu, Paula L., el al. (2002) Methine (CH) Transfer via a Chlorine Atom Abstraction/Benzene-Elimination Strategy:  Molybdenum Methylidyne Synthesis and Elaboration to a Phosphaisocyanide Complex; Journal of the American Chemical Society; Vol. 124; No. 11; 2412-2413; 10.1021/ja017278r
• Diaconescu, Paula L. and Odom, Aaron L., el al. (2001) Uranium−Group 14 Element Single Bonds: Isolation and Characterization of a Uranium(IV) Silyl Species; Organometallics; Vol. 20; No. 24; 4993-4995; 10.1021/om010575k
• Agapie, Theodor and Odom, Aaron L., el al. (2000) In Pursuit of the Molybdenum(III) Tris(thiolate) Fragment:  Unusual Structure of a Dimolybdenum μ-Nitrido Complex; Inorganic Chemistry; Vol. 39; No. 2; 174-179; 10.1021/ic9904891